全文获取类型
收费全文 | 10886篇 |
免费 | 1834篇 |
国内免费 | 1367篇 |
专业分类
化学 | 6506篇 |
晶体学 | 381篇 |
力学 | 973篇 |
综合类 | 136篇 |
数学 | 244篇 |
物理学 | 5847篇 |
出版年
2024年 | 23篇 |
2023年 | 88篇 |
2022年 | 288篇 |
2021年 | 324篇 |
2020年 | 287篇 |
2019年 | 278篇 |
2018年 | 305篇 |
2017年 | 422篇 |
2016年 | 501篇 |
2015年 | 406篇 |
2014年 | 530篇 |
2013年 | 950篇 |
2012年 | 739篇 |
2011年 | 726篇 |
2010年 | 622篇 |
2009年 | 691篇 |
2008年 | 609篇 |
2007年 | 721篇 |
2006年 | 660篇 |
2005年 | 573篇 |
2004年 | 554篇 |
2003年 | 471篇 |
2002年 | 400篇 |
2001年 | 330篇 |
2000年 | 341篇 |
1999年 | 318篇 |
1998年 | 249篇 |
1997年 | 230篇 |
1996年 | 222篇 |
1995年 | 165篇 |
1994年 | 139篇 |
1993年 | 166篇 |
1992年 | 128篇 |
1991年 | 77篇 |
1990年 | 76篇 |
1989年 | 67篇 |
1988年 | 89篇 |
1987年 | 52篇 |
1986年 | 43篇 |
1985年 | 27篇 |
1984年 | 18篇 |
1983年 | 12篇 |
1982年 | 33篇 |
1981年 | 27篇 |
1980年 | 17篇 |
1979年 | 27篇 |
1978年 | 15篇 |
1977年 | 14篇 |
1976年 | 16篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
51.
The effect of the temperature factor, that is, the ratio of the body temperature to the freestream stagnation temperature, on the structure of the separated flow formed in the presence of a concave corner in a supersonic stream is studied. The strong influence of the temperature factor on the separation zone length and the flow-generated aerodynamic characteristics is established. It is shown that for fairly large deflection angles this flow cannot be described by free interaction, or triple deck, theory. 相似文献
52.
Most adhesives and binders, including bitumen for asphalt mixture production, are presently produced from petrochemicals after
the refining of crude oil. The fact that crude oil reserves are a finite resource means that in the future, it may become
necessary to produce these materials from alternative and probably renewable sources. Suitable resources of this kind may
include polysaccharides, plant oils and proteins. This paper deals with the synthesis of polymer binders from monomers that
could, in future, be derived from renewable resources. These binders consist of polyethyl acrylate (PEA) of different molecular
weight, polymethyl acrylate (PMA) and polybutyl acrylate (PBA), which were synthesised from ethyl acrylate, methyl acrylate
and butyl acrylate, respectively, by atom transfer radical polymerisation. The rheological properties of these binders were
determined by means of oscillatory testing using a dynamic shear rheometer and combinations of stress/strain, temperature
and frequency sweeps. The results indicate that PEA can be produced to have rheological properties similar to that of ‘soft’
100/150 penetration grade bitumen, PMA with similar rheological properties to that of ‘hard’ 10/20 penetration grade bitumen,
while PBA, due to its highly viscous nature and low dynamic moduli, cannot be used on its own as a binder. The synthetic polymers
were found to be thermo-rheologically simple, and the shift factors, used to produce the dynamic moduli master curves, were
found to fit an Arrhenius function. 相似文献
53.
后退火温度对溅射沉积Pb(Zr0.52Ti0.48)O3铁电薄膜结构和性能的影响 总被引:2,自引:0,他引:2
在具有Ti缓冲层的Pt(111)底电极上,用射频溅射工艺在较低的衬底温度(370℃)和纯Ar气氛中沉积Pb(Zr0.52Ti0.48)O3(PZT)薄膜,沉积过程中基片架作15°摇摆以提高膜厚的均匀性。然后将样品在大气中进行5min快速热退火处理,退火温度550-680℃。用XRD、SEM分析薄膜的微结构,RT66A标准铁电测试系统测量样品的铁电和介电性能。结果表明,所沉积的Pt为(111)取向,仅当后退火温度高于580℃,沉积在Pt(111)上的PZT薄膜才能形成钙钛矿结构的铁电相,退火温度在580-600℃时结晶为(110)择优取向,退火温度高于600℃时结晶为(111)择优取向。PZT薄膜的极化强度随退火温度的升高而增加,但退火温度超过650℃时漏电流急剧上升,因此退火处理的温度对PZT薄膜的结构和性能有决定性的影响。 相似文献
54.
本给出了三种提高YBCO块材在外磁场中悬浮力的方法.第一种方法是增强外磁场,对于此方法,本研究了一块直径为30mm的圆柱状YBCO块材分别在圆柱状NdFeB永磁体和NdFeB永磁导轨上的悬浮力.测量结果表明在77K温度下YBCO块在圆柱状NdFeB永磁体上的最大悬浮力为50N,在NdFeB永磁导轨上的最大悬浮力为103.ON.第二种方法是提高YBCO块材自身的性能,包括临界电流密度、俘获磁通和块材尺寸,对于此方法,本仅研究了块材尺寸对悬浮力的影响.三块直径分别为30mm、35mm、40mm的圆柱状YBC0块材在NdFeB永磁导轨上的悬浮力被测量,77K温度下5mm悬浮间距时的悬浮力分别为103.ON、134.5N、175.ON.第三方法是将YBCO块材变成准永久磁体,此种情况下,直径为40mm的圆柱状YBCO块材在77K温度下5mm悬浮间距时的悬浮力高达218.3N. 相似文献
55.
本文用超声相比较方法测定了高Tc超导体La1.85Sr0.15CuO4,La2CuO4和YBa2Cu3O7的纵波和横波声速,进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La1.85Sr0.15CuO4样品上,还进行了压力实验,发现所有弹性模量都是随压强增加而增加。定体比热cV和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。 相似文献
56.
Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007 相似文献
57.
A new flow electrical conductance instrument was constructed and tested on dilute NaCl solutions up to 458 K, and on more
concentrated solutions (maximum 0.436 mol⋅kg−1) at 373 K. The results of the new instrument agreed with those of previous authors within the estimated experimental errors.
The model of Bernard et al. (J. Phys. Chem. 96, 3833–3840 (1992), MSA) was found to represent the high-temperature results without introducing an ion-pairing equilibrium constant. The Fuoss–Hsia
conductance equation as given by Fernandez-Prini was found to represent the dilute concentrations with Λ° (NaCl) as the only adjustable parameter. It was found that Λ° (NaCl) could be expressed as a function of solvent viscosity and density by using three parameters found by regression of
literature results between 278.15 and 523 K. This equation along with the FHFP theory permits the equivalent conductivity
of dilute sodium chloride solutions to be calculated within the accuracy of the existing experimental measurements. 相似文献
58.
High temperature scanning tunneling spectroscopy (HT-STS) was used to investigate the electronic structure of Au(1 1 1) at different temperatures in the energy range 0-1 eV below the Fermi level. We concentrated on the influence of temperature on the Shockley surface state (SS) appearing on noble metals surface due to a surface projected bulk bang gap in [1 1 1] direction. The influence of temperature on the projected band gap edge (BE) was also investigated. The experiment was carried out in the temperature range 294-580 K. As the result of the experiment a delicate shift of the SS and the BE in direction of the Fermi level was reported. 相似文献
59.
Vlase T. Vlase G. Chiriac A. Doca N. 《Journal of Thermal Analysis and Calorimetry》2003,72(3):839-845
The thermal decomposition in non-isothermal conditions of formates, acetates, propionates and butyrates of Mn, Co, Zn, Cd,
Eu, Sm and Ni was studied. The observed compensation effect allows us to calculate the isokinetic temperature. A selective
activation mechanism was suggested. This leads to a good agreement between kinetic and spectroscopic data.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
60.
田兴 《新疆大学学报(理工版)》1991,8(1):53-55
本文分析计算了荧光光纤温度传感器的温敏元件——GsAlAs/GaAs双异质结半导体材料的荧光辐射效率与激励光波长的关系。讨论了温度测量范围及温敏元件GaAlAs层铝含量对激励光源的限制,在0~200℃测温范围内,若采用LED作激励光源,其峰值波长应在0.70~0.76μm之间选择。 相似文献