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21.
A routine method for the determination of chloride, nitrate and sulfate anions in rainwater by capillary electrophoresis was developed. The system uses an end-column non-suppressed conductivity detector. Linear calibration plots were generated from 0.050 to 20 mg/l, which is the range generally found in wet depositions. Accuracy and precision were evaluated by analyzing certified standards of simulated rainwater and environmental samples, or by comparing CE results with those obtained by IC, the reference technique for anion analysis in wet deposition. The reproducibility of the method was satisfactory except at the lower and upper limits of the analytical range. Sensitivity lay in the range of few μg/l. 相似文献
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Capillary electrophoresis-mass spectrometry (CE-MS) with an electrospray ionization interface was applied for the quantitative analysis of imazamox pesticide in well water, potable water, and pond water. The detector response for imazamox was determined to be linear over the concentration range of 50-1 ng/ml. The limits of quantitation and detection of the method were determined to be 200 and 20 ng/l for imazamox compound in each type of water sample, respectively. The total sample preparation and CE-MS analysis time was under 2 h. 相似文献
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S. Yu. Troitskii A. L. Chuvilin D. I. Kochubei B. N. Novgorodov V. N. Kolomiichuk V. A. Likholobov 《Russian Chemical Bulletin》1995,44(10):1822-1826
The structure of polynuclear PdII hydroxocomplexes (PHC) formed as a result of alkaline hydrolysis of PdII chloride complexes was studied by EXAFS, SAXS, and TEM methods. It is established that in aqueous solutions a hydroxocomplex particle is a filament curled into a ball containing about 100 Pd atoms. The filament consists of planar coordination squares of PdO4 units linkedvia one or two oxygen bridges of different geometry. Aging of samples results in an increase in the number of single bridging ligands and a decrease in the diameter of particles. Interatomic distances around palladium atoms were determined.Translated fromIzvestiya Akademii Nauk. Seriya Khimlcheskaya, No. 10, pp. 1901–1905, October, 1995. 相似文献
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Certain contaminants at trace concentrations in surface waters can have dramatic effects on the hormonal system of organisms in the aquatic environment. Therefore, immunoanalytical methods at a very low limit of detection (LOD) and a low limit of quantification (LOQ) are becoming more and more important for environmental analysis and especially for monitoring drinking water quality. Environmental monitoring of antibiotics, hormones, endocrine disrupting chemicals, and pesticides in real water samples (e.g. surface, ground or drinking water) with difficult matrices places high demands on chemical analysis. Biosensors have suitable characteristics such as efficiency in allowing very fast, sensitive, and cost-effective detection. Here we describe an assay optimization process with a fully automated immunoassay for estrone which resulted in a LOD below 0.20 ng L−1 and a LOQ below 1.40 ng L−1. In contrast to common analytical methods such as GC-MS or HPLC-MS, the biosensor used requires no sample pre-treatment and pre-concentration. The very low validation parameters for estrone are the result of the continuous optimization of the immunoassay. The basis of our sensitive assay is the antibody with a high affinity constant towards estrone. During the optimization process, we reduced the amount of antibody per sample and improved the chip surface modification. Finally, this proceeding led to a calibration routine with an amount of antibody of only 3.0 ng per sample (sample volume: 1.0 mL). The reduction of the amount of antibody per sample results in better validation parameters (LOD, LOQ, and IC50), but this reduction leads to the current device-related limitation of the River Analyser (RIANA).For some endocrine disrupting compounds, no effect levels (NOELs) in the lower nanogram per liter range are reported. This defines the challenge, which analytical methods have to compete with and our RIANA instrument with its improved sensitivity for the detection of a single hormone in the lower nanogram per liter range is a powerful tool in aquatic analytics in addition to the common analytical methods. 相似文献
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I.K. Battisha 《Journal of Sol-Gel Science and Technology》2004,30(3):163-172
Visible up-conversion emissions at (435, 545, 580, 675 and 690 nm) and (437, 547 575 and 675 nm) have been observed from the sol-gel derived nano-crystalline Ho3+: BaTiO3 powders and thin films respectively, under 808 nm laser diode excitation emissions. Combined with the energy level structure of Ho3+ ions and the kinetics of the visible emissions, the up-conversion mechanism has been analyzed and explained. The blue, green and red emissions of both samples has been attributed to the ground state-directed transition from (5F1), (5S2) and (5F5), which are populated through excited state absorption (ESA) for 808 nm excitation. Nano-structure pure barium titanate and doped with different concentrations of Ho3+ ions in the from of powder and thin film have been prepared by sol-gel technique, using barium acetate (Ba(Ac)2), and titanium butoxide (Ti(C4H9O)4), as precursors. The thin films were prepared by sol-gel spin coating method. The as-grown thin films and powders were found to be amorphous, which crystallized to the tetragonal phase after heating at 750°C in air for 30 minutes. The crystallite sizes of the thin film and powder both doped with 4% Ho3+ ions was found to be equal to 11 and 16 nm, respectvely. 相似文献
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Poly(methyl methacrylate) (PMMA)/silica/titania ternary nanocomposites with covalent bonding interaction between polymer and inorganic phases have been prepared using a novel non-hydrolytic sol-gel method. Transmission electron microscope (TEM) image of silica/titania binary inorganic component indicates a core-shell-like structure. Scanning electron microscope (SEM) images suggest that the well dispersed silica/titania particles in the hybrid are on the nanometer-scale. The transparencies of nanocomposites are maintained in visible region while the absorption band in ultraviolet (UV) region is red shifted with increasing inorganic content. The thermogravimetric analysis (TGA) results show that the thermal stability of PMMA copolymer increases dramatically with the addition of silica/titania moieties both in nitrogen and in air. 相似文献