碱土金属氟卤化物中的Eu3+的荧光光谱特征

本文系统研究了MFX体系中Eu³⁺荧光光谱特征,着重讨论了X^-,M²⁺及杂质缺陷(主要为O^2-)对Eu³⁺发光的影响.     

C60和C60／C70的激光脱附飞行时间质谱分析

采用激光脱附并直接测量离子的方法对实验室提取的C_(60)/C_(70)以及进一步分离得到的纯C_(60)进行了飞行时间质谱分析,并讨论了质谱分析过程中实验条件对结果的影响.     

Activation energy and hall-coefficient measurements in lightly dopedn-InP in the thermal freeze-out region

Summary The direct-current resistivity, β, and Hall coefficient,R _H, of lightly dopedn-type InP samples were measured at temperatures (T) down to 12K and magnetic fields up to 4.8 kG. A sharp exponential increase in β, asT was decreased, was observed for temperatures below 80 K. The Hall coefficient showed a similar trend,i.e. R _H increased sharply asT was reduced below 80 K. This is attributed to the freeze-out of conduction electrons onto their donor sites. The donor activation energy,E _d, calculated from the temperature dependence of the resistivity, was less than the theoretical prediction. An enhanced dielectric constant would be a possible candidate for such behaviour. The initial decrease in β (asT is reduced) recorded in the higher-temperature region is due to impurity scattering probably combined with lattice scattering. The authors of this paper have agreed to not receive the proofs for correction.     

同步辐射与GGG：Nd^3＋晶体的相互作用

用北京同步辐射489A-VUV束线作为连续光源测定了GGG:Nd~(3+)晶体的短波吸收光谱。用束线4B9A-WX作为光源激发GGG:Nd~(3+),测定了它的XEOL(X-ray excited optical luminescence)。     

维数连续可变康托尔集分层介质中波的反射透射特性

本文研究了波通过一类可连续控制分维的广义Cantor集合介质层的反射透射频谱特性。利用自相似性,给出了任意分维情况的一般计算方法,从而使我们能研究反射透射频谱随分维的变化特点,并认识到,在一般分维下,谱具有广义自相似性和“混沌”周期性,这是一种新的物理现象,必定蕴藏着一定的实用价值。     

奇异值分解在海洋回波多普勒信息提取中的应用

运用矩阵奇异值分解原理,分析了功率谱估计对探测海洋表面信息和硬目标信号的意义,对接收信号的自相关矩阵进行分解以提高谱估计的分辨率,并将处理后的方法对实测数据进行功率谱的估计,与处理前的回波谱图进行比较,实验证明,得出的奇异值分解方法可以改善多普勒回波功率谱的性能,满足高频地波雷达的目标探测要求。     

Effect of local structure on electron paramagnetic resonance spectra for trigonal [Cr(H2O)6]3+coordination complex in the sulfate alums series: a ligand field theory study

A simple theoretical method is introduced for studying the interrelation between electronic and molecular structures.By diagonalizing the 120 × 120 complete energy matrices,the relationships between zero-field splitting(ZFS) parameter D and local distortion parameter △θ for Cr 3+ ions doped,separately,in α-and β-alums are investigated.Our results indicate that there exists an approximately linear relationship between D and △θ in a temperature range 4.2-297 K and the signs of D and △θ are opposite to each other.Moreover,in order to understand the contribution of spin-orbit coupling coefficient ζ to ZFS parameter D,the relation between D and ζ is also discussed.     

Classification of Raman spectra using the correlation kernel

The classification of Raman spectra can be very useful in a wide range of diagnostic applications including bacterial identification. Before any form of classification can be carried out on the Raman spectra, some form of pre‐processing is commonly applied. This pre‐processing greatly affects the accuracy of the results and introduces user bias and over‐fitting effects. In this paper, we propose using support vector machines with the correlation kernel. The use of the correlation kernel on Raman spectra has not been presented before in any published work. Our results illustrate that the correlation kernel is ‘self‐normalizing’ and produces superior classification performance with minimal pre‐processing, even on highly noisy data obtained using inexpensive equipment. Such effective classification approaches can lead to clinically valuable diagnostic applications of Raman Spectroscopy. Copyright © 2010 John Wiley & Sons, Ltd.     

The closed-orbit and the photoabsorption spectra of lithium atom in varying＇magnetic fields

Using a simple analytic formula from closed orbit theory, we have calculated the photoabsorption spectra of Li atom in different magnetic fields. Closed orbits in the corresponding classical system have also been obtained for B=5.96T.We demonstrate schematically that the closed orbits disappear gradually with the decrease of the magnitude of the magnetic field. This gives us a good method to control the closed orbits in the corresponding system by changing the magnetic field, and thus changing the peaks in the photoabaorption spectra. By comparing the photoabsorption spectra of Li atom with those of hydrogen case, we find the core-scattered effects play an important role in multi-electron Rydberg atoms.     

Electronic structure of BaTiO3 using resonant X-ray emission spectroscopy at the Ba-L3 and Ti-K absorption edges

We have studied the electronic properties of the ferroelectric barium titanate BaTiO₃ using two complementary bulk-sensitive spectroscopic probes, resonant X-ray emission spectroscopy (RXES) and X-ray absorption spectroscopy in the partial fluorescence mode (PFY-XAS) at the Ba-L₃ and Ti-K absorption edges. Contrary to a previous study, we found no fine structure in the pre-edge area of the PFY-XAS spectrum at the Ba-L₃ edge, and no temperature-induced spectral change was observed between room temperature and 150 °C. This result is not supportive of the possible presence of the displacement around Ba²⁺ at the Curie temperature. RXES spectra were measured at the Ti-K edge for BaTiO₃, along with SrTiO₃ and La-doped metallic SrTiO₃. The photon energy of the emission peak is found to be nearly constant throughout the absorption edge for all three compounds. We deduce the Ti 3d states to have a delocalized character, in contrast with the Ba 5d states, a property which is consistent with the proposed scenario of the formation of electric dipoles in BaTiO₃.