A microwave-assisted synthesis of phenanthroperylene quinones as exemplified with hypericin

The synthesis of hypericin, one of the most important phenanthoperylene quinones used in photodynamic therapy, could be highly improved by using either a microwave-assisted dimerization of emodinanthrone, or a mixed dimerization of emodinanthrone with emodin in the presence of potassium t-butoxide as the key-step.     

Gouy phase compensation in quasi-phase matching

In any focussed nonlinear interaction the focus induced phase shift, known as the Gouy phase shift, provides an imperfection in phase matching for any linearly invariant material. However, using an appropriately designed quasi-phase matched structure it is theoretically possible to compensate for the deleterious effects of the Gouy phase shift, allowing a symmetric frequency response and tighter optimal focussing than in a uniform material.     

Unstable plasma characteristics in mirror field electron cyclotron resonance microwave ion source

Electron cyclotron plasma reactor are prone to instabilities in specific input power [3–7] region (150–450 watts). In this region power absorption by gas molecules in the cavity is very poor and enhanced input power gets reflected substantially without increasing ion density. There are abrupt changes in plasma characteristics when input power was decreased from maximum to minimum, it was observed that reflected power changed from <2% to ∼50%. Minimum two jumps in reflected power were noticed in this specific power region and these appear to be highly sensitive to three stub tuner position in the waveguide for this particular input power zone. Unstable plasma region of this source is found to be dependent upon the magnetic field strength. Some changes in reflected power are also noticed with pressure, flow and bias and they are random in nature.     

Surface pattern recording in amorphous chalcogenide layers

Investigations of light-induced volume expansion and surface pattern recording in amorphous chalcogenide layers and nano-layered structures (NLS) were extended to direct electron-beam recording on Se/As₂S₃ and Sb/As₂S₃ NLS. Light as well as e-beam induced bleaching occurs in all NLS, while volume expansion occurs only in chalcogenide–chalcogenide NLS and in homogeneous Se or As₂S₃ layers. Comparison of these two phenomena revealed the possible role of purely electronic and thermal processes in the interdiffusion and relief formation. The latter is supposed to be connected with radiation-induced defect creation, free volume increase under the increased fluidity conditions as well as with the possible additional influence of electrostatic forces and stress.     

Undulator linear accelerator as a generator of ribbon high power ion beams

The characteristics of an undulator linear accelerator, based on the use of a plane electrostatic undulator (UNDULAC-E), is presented in this paper. It is shown that UNDULAC-E can be used as a high intensity ribbon ion beam source. The results of modeling of dynamics and construction are presented.     

What is the maximum stretching for C–C single bond?

The objective of this work is to determine the maximum stretch of the C–C bond before it misses the character of single bond, employing both the Atoms in Molecules (AIM) and Electron Localization Function (ELF) methods. It was concluded that C–C distances up to 2.0 Å could be considered single bonds.     

Global existence and exponential stability for a contact problem between two thermoelastic beams

In this paper we analyze a dynamic unilateral contact problem between two thermoelastic beams. We establish the existence of a weak global-in-time solution, by a penalization method. Moreover, we study the asymptotic behavior of such a solution proving that the energy associated to the system decays exponentially to zero, as time goes to infinity.     

Chemical Kinetics Database and Predictive Schemes for Humid Air Plasma Chemistry. Part I: Positive Ion–Molecule Reactions

Reliable kinetic and thermodynamic data are required to model the evolution of electric discharge or electron-beam decomposition chemistry of gases in humid air streams. In this first segment of a continuing series, we provide a core database describing the initially dominant ion-neutral molecule reactions in humid air plasmas. Recommended reaction rate data and extrapolation tools are presented in a manner to facilitate prediction of reactivities and reaction channels as a function of temperature, pressure, and applied electric field.     

基于最小加速度原理的刚塑性动力问题

应用有限变形的最小加速度原理，推导出了小变形或有限变形构件受到刚性飞射物撞击时的刚塑性运动方程，指出该方法具有直接、简捷和可靠的特点。