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171.
    
In capillary systems with narrow pores the Helmholtz electrochemical double layer located at the pore wall extends over the entire cross section of the pores. It loses its character as the “charge on the wall”. It will be shown that not only the electrokinetic phenomena but also the electrical conductivity and the dialysis potential of membranes with narrow pores can be understood from the same point of view, namely: the electrolyte solution in the pores of a membrane with narrow pores is considered to be an approximately homogeneous solution in contact with immobilised charges located at the pore wall. In this case the electrochemical equations contain the fixed ion concentration as a parameter instead of the ζ potential. This makes it possible to describe quantitatively to a good approximation data on the electroosmosis, the electrical conductivity, the streaming potential and the dialysis potential taken from the literature, as well as results of our own measurements, by using a single membrane constant.  相似文献   
172.
    
N,N'-(2-Hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II) has been synthesized. The crystal structure has been determined by X-ray diffraction analysis, and linear optical characterization has been determined by UV-vis spectroscopy. It was found that the molecule under investigation has solvatochromic behaviour in the UV region, implying non-zero microscopic first hyperpolarizability. To reveal the microscopic nonlinear optical (NLO) properties, the static first hyperpolarizabilities (beta) and the electric dipole moments (mu) were evaluated by using the ab initio finite field (FF) method. According to the results of the FF calculations, the synthesized compound exhibits non-zero beta values, and it might have microscopic NLO behaviour.  相似文献   
173.
邱奥祥  桑为民  张桐  安博  李栋  张彬乾 《力学学报》2024,40(8):2448-2467
翼身融合布局是指机翼和机身高度融合的全升力面飞机外形, 在提升巡航效率和减排降噪等方面展现出明显的性能优势和发展潜力. 采用雷诺平均Navier-Stokes方法结合基于叶素理论的体积力模型, 针对翼身融合布局民机分布式推进边界层吸入(BLI)效应影响下的绕流流场进行了数值研究. 首先, 将翼身融合布局民机分布式BLI推进构型简化为涵道风扇-机翼段耦合构型, 计算涵道风扇质量流率小于1、等于1以及大于1的3个工况, 对比分析了滑移网格方法、冻结转子方法和基于叶素理论的体积力模型法的流场细节、计算精度以及计算效率. 其次, 建立分布式BLI推进-机翼耦合构型, 对此构型不同转速下的绕流流场进行对比分析, 探究并验证所建立的分布式BLI推进系统抑制分离的能力. 最后, 将分布式BLI推进安装于翼身融合布局飞机概念方案NPU-BWB-300机翼与机身的融合段, 探究其对NPU-BWB-300绕流流场的影响. 研究结果表明: 滑移网格方法、冻结转子方法和基于叶素理论的体积力模型方法均可以较好地刻画涵道风扇边界层吸入效应的流场细节; 所建立的分布式BLI推进系统具备抑制分离的能力, 将其应用于NPU-BWB-300也可以取得较为明显地改善分离流场的效果.  相似文献   
174.
通过绝热动力学方法,研究了共轭高聚物双分子结构中激子对外加电场的响应.当外电场强度超过某个临界值时,激子会被解离成一对自由的电子与空穴.对于双分子结构中的激子,其临界解离电场除了受电子与电子相互作用以及电声相互作用影响之外,还受分子间相互作用的影响.由动力学演化的计算得到,激子临界解离电场强度随分子间相互作用强度的增大而呈非线性降低;随电子与电子相互作用强度的增大呈非线性减小的变化;但是,随电声耦合强度的增大却呈现出线性增大的变化.  相似文献   
175.
J. Ross Macdonald   《Solid State Ionics》2002,150(3-4):263-279
Possible errors in the widely used 1972–1973 macroscopic original-electric-modulus formalism are identified, corrected, and their consequences considered. These errors include misidentification of the high-frequency-limiting dielectric constant arising entirely from mobile charges, εC1∞, and the failure to treat properly the high-frequency-limiting dielectric constant associated with bulk dipolar and vibrionic effects, εD∞. It is shown that the corrected modulus formalism, which describes dispersed mobile-charge effects, is isomorphic in form with the 1973 microscopic continuous-time random-walk hopping model of Scher and Lax after a minor but significant correction is made to the latter's response function. This firmly established correction, which nevertheless could not be determined by Kronig–Kramers transformation, involved inversion of synthetic frequency-response data to determine a distribution of relaxation times and led to extension of the real part of the Scher–Lax dielectric response to higher frequencies by the inclusion of a nonzero limiting value. This isomorphism, along with excellent data fitting using the corrected modulus formalism, suggests that since the Scher–Lax stochastic model involves no explicit Coulomb interactions, cation motion in glasses is dominated by short-range interactions. Finally, two very-high-frequency processes, which each lead to a limiting plateau value of the real part of the conductivity at sufficiently high frequencies, are discussed in detail.  相似文献   
176.
The influence of ABA-triblock copolymers on the temperature-induced infinite droplet cluster formation in water/oil-microemulsions is studied. The effects of the different blocks of the polymer can be well separated. With the help of an Ehrenfest relation the coupling between the elastically-induced shift of the infinite cluster formation temperature Tc and the plateau modulus of the resulting microemulsion networks is described.  相似文献   
177.
Summary The excitation of metastable states in an atomic beam apparatus by means of electron collision is a widespread technique. We have observed a large bistable behaviour in our apparatus designed to provide an intense and collimated beam of metastable helium by excitation with orthogonally impinging electrons. This bistable behaviour largely affects the efficiency of the apparatus and is therefore worth of being carefully investigated. The apparatus has an electrode configuration equivalent to that of a tetrode valve with large intergrid distances. The bistability consists in a hysteresis cycle in the curve of the anode currentvs. grid voltage. Experimental measurements, supported by a simple theoretical model and by numerical simulation, stress out the crucial role played by space charge effects for the onset of bistability. A comparison with previous observation of this phenomenon is given. Spontaneous current oscillations with various shapes have been recorded in one of the two curves of the hysteresis cycle.  相似文献   
178.
The dynamical behavior of spiral waves in a period-2 oscillatory medium is investigated under the influence of an external applied alternating current field. Open and closed transversal line defects which wiggle along the direction parallel to the wave fronts, are generated in the spiral-wave patterns when the stimulus frequency of the electric field is equal to one, three or five times of the local oscillatory frequency in the period-2 state. Their generations are directly related with the change in the spatial wavelength induced by the electric field. These wigglings proliferate along the transverse direction parallel to the wave fronts as the stimulus strength increases, and become denser when the stimulus frequency increases by multiples of the period-2 oscillatory frequency.  相似文献   
179.
In the present work, the time differential perturbed angular correlation (PAC) technique was used to study the temperature dependence of electric field gradient (efg) in GdCoO3 perovskite using 111Cd and 181Ta nuclear probes. The radioactive parent nuclei 111In and 181Hf were introduced in the oxide lattice through chemical process during sample preparation and were found to occupy only the Co sites in GdCoO3. The efg's at 111Cd and 181Ta show temperature dependence with two different fractions each that change with temperature. In the case of 111Cd the quadrupole frequency slowly decreases, with corresponding increase of the temperature and shows a peak like structure at around 200 K and a discontinuity at 700 K. These changes have been interpreted as thermally activated spin-state transitions from low-spin ground state configuration to the intermediate-spin state and from intermediate-spin to high-spin state of Co3+Co3+ ion similar to LaCoO3 compound. Indication of a Jahn–Teller distortion, which stabilizes the intermediate-spin state with orbital ordering, is also pointed out.  相似文献   
180.
We examine the time evolution of a quantized field in external backgrounds that violate the stability of vacuum (particle-creating backgrounds). Our purpose is to study the exact form of the final quantum state (the density operator at the final instant of time) that has emerged from a given arbitrary initial state (from a given arbitrary density operator at the initial time instant) in the course of evolution. We find a generating functional that allows one to obtain density operators for an arbitrary initial state. Averaging over states of the subsystem of antiparticles (particles), we obtain explicit forms of reduced density operators for the subsystem of particles (antiparticles). Analyzing one-particle correlation functions, we establish a one-to-one correspondence between these functions and the reduced density operators. It is shown that in the general case a presence of bosons (e.g., gluons) in the initial state increases the creation rate of the same type of bosons. We discuss the question (and its relation to the initial stage of quark–gluon plasma formation) whether a thermal form of one-particle distribution can appear even if the final state of the complete system is not in thermal equilibrium. In this respect, we discuss some cases when pair-creation by an electric-like field can mimic the one-particle thermal distribution. We apply our technics to some QFT problems in slowly varying electric-like backgrounds: electric, SU(3) chromoelectric, and metric. In particular, we analyze the time and temperature behavior of the mean numbers of created particles, provided that the effects of switching the external field on and off are negligible. It is demonstrated that at high temperatures and in slowly varying electric fields the rate of particle-creation is essentially time-dependent.  相似文献   
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