全文获取类型
收费全文 | 3535篇 |
免费 | 78篇 |
国内免费 | 223篇 |
专业分类
化学 | 1242篇 |
晶体学 | 8篇 |
力学 | 608篇 |
综合类 | 3篇 |
数学 | 1070篇 |
物理学 | 905篇 |
出版年
2024年 | 7篇 |
2023年 | 91篇 |
2022年 | 38篇 |
2021年 | 47篇 |
2020年 | 92篇 |
2019年 | 59篇 |
2018年 | 50篇 |
2017年 | 106篇 |
2016年 | 113篇 |
2015年 | 88篇 |
2014年 | 201篇 |
2013年 | 259篇 |
2012年 | 171篇 |
2011年 | 219篇 |
2010年 | 169篇 |
2009年 | 283篇 |
2008年 | 285篇 |
2007年 | 258篇 |
2006年 | 188篇 |
2005年 | 163篇 |
2004年 | 141篇 |
2003年 | 117篇 |
2002年 | 108篇 |
2001年 | 78篇 |
2000年 | 82篇 |
1999年 | 58篇 |
1998年 | 49篇 |
1997年 | 43篇 |
1996年 | 31篇 |
1995年 | 32篇 |
1994年 | 36篇 |
1993年 | 20篇 |
1992年 | 26篇 |
1991年 | 17篇 |
1990年 | 6篇 |
1989年 | 14篇 |
1988年 | 19篇 |
1987年 | 7篇 |
1986年 | 11篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有3836条查询结果,搜索用时 0 毫秒
91.
92.
The effect of the dynamic pressure (non-equilibrium pressure) on stationary heat conduction in a rarefied polyatomic gas at rest is elucidated by the theory of extended thermodynamics. It is shown that this effect is observable in a non-polytropic gas. Numerical studies are presented for a para-hydrogen gas as a typical example. 相似文献
93.
This Trends article highlights the recent advances published between 2012 and 2015 in solid-state 17O NMR for organic and biological molecules. New developments in the following areas are described: (1) new oxygen-containing functional groups, (2) metal organic frameworks, (3) pharmaceuticals, (4) probing molecular motion in organic solids, (5) dynamic nuclear polarization, and (6) paramagnetic coordination compounds. For each of these areas, the author offers his personal views on important problems to be solved and possible future directions. 相似文献
94.
95.
Piotr Kozlowski Silvia D. Chang Ran Meng Burkhard Mädler Robert Bell Edward C. Jones S. Larry Goldenberg 《Magnetic resonance imaging》2010
The purpose of this work was to compare diagnostic accuracy of Diffusion Tensor Imaging (DTI), dynamic contrast-enhanced magnetic resonance imaging (DCE MRI) and their combination in diagnosing prostate cancer. Twenty-five patients with clinical suspicion of prostate cancer underwent MRI, prior to transrectal ultrasound-guided biopsies. MRI data were correlated to biopsy results. Logistic regression models were constructed for the DTI parameters, DCE MRI parameters, and their combination. The areas under the receiver operator characteristic curves (AUC) were compared between the models. The nonparametric Wilcoxon signed rank test was used for statistical analysis. The sensitivity and specificity values were respectively 81% (74–87%) and 85% (79–90%) for DTI and 63% (55–70%) and 90% (85–94%) for DCE. The combination “DTI or DCE MRI” had 100% (97–100%) sensitivity and 77% (69–83%) specificity, while “DTI and DCE MRI” had 44% (37–52%) sensitivity and 98% (94–100%) specificity. The AUC for DTI+DCE parameters was significantly higher than that for either DTI (0.96 vs. 0.92, P=.0143) or DCE MRI parameters (0.96 vs. 0.87, P=.00187) alone. In conclusion, the combination of DTI and DCE MRI has significantly better accuracy in prostate cancer diagnosis than either technique alone. 相似文献
96.
Abstract Blends of poly(pyridinium ethyl methacrylate perchloride) and poly[oligo(oxyethylene) methacrylate-co-acrylamide] were prepared, and the ionic conductivity and mobility of the blends were investigated. Results indicate that both the transference of perchlorate anion and the dissociation of the polymeric salt in the comblike polyether obey the thermoactivation mechanism, and that the perchlorate anion in the blends is free. 相似文献
97.
Rosa M. Claramunt Pilar Cornago M. Dolores Santa María Verónica Torres Elena Pinilla M. Rosario Torres 《Supramolecular chemistry》2013,25(4):349-356
The X-ray structure and the solid-state NMR measurements, mainly 15N CPMAS of the labelled compound, allow to determine the static and dynamic properties of 3(5)-ethyl-5(3)-phenyl-1H-pyrazole. The compound is a tetramer formed by three 5-ethyl-3-phenyl-1H-pyrazole and one 3-ethyl-5-phenyl-1H-pyrazole tautomers in dynamic equilibrium with the complementary situation. 相似文献
98.
Maria Carmen Florian Eric Condamine loïc Toupet Yvan Ramondenc Gérard Plé 《Supramolecular chemistry》2013,25(6):383-392
The synthesis and the structure of new macrocycles containing semiflexible dispiro-1,3-dioxane units is reported. The structural analysis of the compounds is performed by high field NMR spectra, mass spectrometry investigations (MALDI, ESI-MS) and the solid state molecular structure obtained for two compounds by single crystal X-ray diffractometry. The dynamics of the macrocycles promoted by the flipping of the middle cyclohexane ring of the dispirane units is investigated using low temperature NMR experiments. New macrocycles containing dispiro-1,3-dioxane units were investigated by NMR, X-ray diffractometry and mass spectrometry 相似文献
99.
100.
H. P. S. Abdul Khalil M. Jawaid P. Firoozian E. S. Zainudin M. T. Paridah 《International Journal of Polymer Analysis and Characterization》2013,18(4):247-256
Nano-activated carbons obtained from oil palm empty fiber bunch (AC-EFB), bamboo stem (AC-BS), and coconut shells (AC-CNS) were reinforced in epoxy matrix to fabricate epoxy nanocomposites. The dynamic mechanical analysis of epoxy nanocomposites was carried out, and 5% AC-CNS treated with KOH-filled epoxy composites displayed the highest storage modulus of all the activated carbon–filled epoxy composites. The incorporation of a small amount of AC-BS, AC-EFB, and AC-CNS to the epoxy matrix enhanced the damping characteristics of the epoxy nanocomposites. The 5% AC-EFB treated with H3PO4 filled epoxy composites showed the highest glass transition temperature (Tg) in all temperature ranges. 相似文献