Convergence results for obstacle problems on metric spaces

Let X be a complete metric space equipped with a doubling Borel measure supporting a p-Poincaré inequality. We obtain various convergence results for the single and double obstacle problems on open subsets of X. In particular, we consider single and double obstacle problems with fixed obstacles and boundary data on an increasing sequence of open sets.     

Comparison of Triple Quadrupole and Double Focusing Mass Spectrometers to Investigate Collision-Induced Dissociation and Metastable Ions of Glycoconjugates

Glycoconjugates, such as chromophore-labeled disaccharides and permethylated glycosphingolipids (GSL) were used for comparison of triple quadrupole and double focusing mass spectrometers in analysis of product ions. A profound effect of collision energy was observed in the product ion spectra of ceramide ions (fragment ions of permethylated GSL): more product ions were observed from a double focusing mass spectrometer. Besides collision energy, the structure of the analyte had a significant effect on the formation of product ions. Despite the fact that masses of protonated molecular ions (MH⁺) of permethylated GSL are significantly larger than their ceramide fragments, the low-energy and high-energy product ion spectra of MH⁺ are, in general, similar. In a double focusing mass spectrometer of reversed geometry, more metastable ions were observed in the first field free region (FFR) than in the second FFR. The metastable ions observed in the second FFR were similar to those observed in low-energy collision-induced dissociation (CID). Although a double focusing mass spectrometer is superior to triple quadrupole instrument for detection of product ions, the poor resolution in either the selection of precursor ion or in the product ion spectra can be a serious problem in analysis of a mixture with similar masses.     

基于Mach-Zehnder干涉仪的光纤气体传感器理论

提出了一种基于马赫-曾德尔(Mach-Zehnder)干涉仪的光纤气体传感器。由于Mach-Zehnder干涉仪具有抑制光源噪声和模式噪声的特点,在高精度测量中越来越受到重视。在干涉仪的传感臂上涂有对待测气体敏感的薄膜,由于气体与敏感层的作用,导致光纤纤芯折射率发生变化,两臂的相位差发生变化,并引起干涉仪输出光强的变化和干涉条纹的平移,平移量与气体浓度对应。根据杨氏双缝干涉的理论,利用MATLAB对该研究进行计算机仿真,绘制出单色光的杨氏干涉图样和光强分布曲线,及气室中通入一定浓度的待测气体使干涉图样产生平移。     

双间隙耦合腔中自激振荡问题的分析和模拟

 建立了双间隙耦合腔中高次模式小信号电子电导计算模型,使用该模型和ISFIEL3D电磁场软件模拟的高次模式电场分布图分析了双间隙耦合腔中高次模式的自激性质。由3维粒子模拟软件对双间隙耦合腔自激模拟显示实际结构中存在高次模式3.17 GHz和3.99 GHz自激,验证了使用该方法分析双间隙耦合腔中高次模式自激性质的合理性。并通过对热测数据的分析说明实际结构中确实存在相应的模式自激并伴随吸收腔和耦合环发热现象。     

On Compact Graphs

Let G be a finite simple graph with adjacency matrix A, and let P（A） be the convex closure of the set of all permutation matrices commuting with A. G is said to be compact if every doubly stochastic matrix which commutes with A is in P（A）. In this paper, we characterize 3-regular compact graphs and prove that if G is a connected regular compact graph, G - v is also compact, and give a family of almost regular compact connected graphs.     

铁硫和钴碳混合簇配合物μ-[(CO)_6Co_2PhC_2S](μ-RS)Fe_2(CO)_6的合成及表征

本文表明含炔键的单簇铁硫配合物(μ-PhC≡S)(μ-RS)Fe_2CO)_6 1,在乙醚和室温条件下与Co_2(CO)_8发生络合反应,生成铁硫和钴碳双簇配合物μ-[(OC)_5Co_2PhC_2S](μ-RS)Fe_2(CO)_5 2.本文还表征了双簇配合物2的结构并对R与硫桥原子所连的键型以及影响络合反应的空间位阻因素进行了讨论。     

Enhanced nonlinear current-voltage behavior in Au nanoparticle dispersed CaCu3Ti4O12 composite films

An enhanced nonlinear current-voltage behavior has been observed in Au nanoparticle dispersed CaCu₃Ti₄O₁₂ composite films. The double Schottky barrier model is used to explain the enhanced nonlinearity in I-V curves. According to the energy-band model and fitting result, the nonlinearity in Au: CCTO film is mainly governed by thermionic emission in the reverse-biased Schottky barrier. This result not only supports the mechanism of double Schottky barrier in CCTO, but also indicates that the nonlinearity of current-voltage behavior could be improved in nanometal composite films, which has great significance for the resistance switching devices.     

超滤/纳滤双膜工艺处理苦咸水过程中DOM三维荧光特征分析

为探明“超滤-纳滤”双膜深度处理工艺处理苦咸水过程中DOM组分三维荧光特征的变化规律,采用三维荧光光谱研究了双膜工艺净水过程中DOM组分变化,发现原水中主要含有两个强度较高的尖峰和两个强度较低的尖峰,随着净水的流程,水样中的荧光峰值逐渐减弱。采用平行因子分析的方法对净水过程中的水样进行了定量分析,在对各水样进行三线性分解的过程中发现水样中主要含有以高激发光类色氨酸和低激发光类色氨酸为代表的类蛋白物质,以紫外类富里酸和可见类富里酸为代表的类富里酸两类因子,并通过水样中各因子的最大荧光峰强度的变化分析了DOM组分的变化规律,其中原水的类蛋白物质因子和类富里酸因子的荧光峰强度分别为0.351 08和0.175 55,类蛋白物质荧光峰的荧光强度大于类富里酸荧光峰,说明原水受到了一定程度外源有机物的污染。在经过水厂原有“混凝-沉淀-过滤”的工艺处理后,DOM的去除效果不佳,类蛋白物质在经过常规工艺处理后仅下降了22.27%,而对于类富里酸具有一定的去除效果,下降了47.57%。“混凝-沉淀-过滤”的常规工艺中未完全去除的DOM将进入“超滤-纳滤”双膜法净水工艺,双膜法工艺中超滤单元对DOM没有很好的去除效果,主要起预处理作用,保障进入纳滤单元的水质;对DOM去除起主要作用的是纳滤单元,经纳滤单元处理后,水中DOM大幅下降,两类因子的荧光峰强度分别为0.013 67和0.002 56,与原水相比,类蛋白物质下降了96.11%,类富里酸物质下降了98.54%。因此,在使用“超滤-纳滤”双膜法工艺处理苦咸水的过程中,应该注意在前处理中选用合适的预氧化处理以加强常规工艺对DOM的去除,在保证除盐效果良好的情况下以减轻DOM对膜污染的影响,本研究将为双膜法的推广应用及其膜污染的控制提供进一步理论基础和科学依据。     

双毛细管气相色谱法测定果蔬中有机磷及氨基甲酸酯类农药残留

对果蔬样品中残留的有机磷及氨基甲酸酯农药,通过较为简便有效的提取方法,以双毛细管柱气相色谱法进行测定,排除了干扰影响,增加了试验结果的可靠性,取得了满意结果。     

F-P腔掺Yb3+双包层光纤激光器中的模式竞争

对连续波LD泵浦掺Yb³⁺双包层光纤激光器的模式竞争进行了实验研究.发现由二色镜和光纤端面构成的F-P谐振腔中存在激烈的模式竞争,对光纤激光器发射波长和输出功率的稳定性都产生不利影响.通过消除"空间烧孔"或减小光纤激光器的有效增益带宽,能够有效抑制模式竞争,提高激光器的输出稳定性.