Bipyridine‐Modulated Palladium‐Catalyzed Oxidative Heck‐Type Reactions of Arylboronic Acids with Olefins

We have demonstrated that 4,4′‐dimethyl 2,2′‐bipyridine as ligand for Pd(II) catalysts was very efficient for oxidative Heck‐type coupling reaction of arylboronic acids with olefins in DMA or CH₃CN under atm air at 80 °C. The presence of chelated bipyridine ligand isindispensable to achieve high reaction yields and to suppress the formation of biphenyl as homocoupled byproduct.     

Distribution sensitivity in a highway flow model

We examine a model of traffic flow on a highway segment, where traffic can be impaired by random incidents (usually, collisions). Using analytical and numerical methods, we show the degree of sensitivity that the model exhibits to the distributions of service times (in the queueing model) and incident clearance times. Its sensitivity to the distribution of time until an incident is much less pronounced. Our analytical methods include an M/G_t/∞ analysis (G_t denotes a service process whose distribution changes with time) and a fluid approximation for an M/M/c queue with general distributions for the incident clearance times. Our numerical methods include M/PH₂/c/K models with many servers and with phase‐type distributions for the time until an incident occurs or is cleared. We also investigate different time scalings for the rate of incident occurrence and clearance. Copyright © 2009 John Wiley & Sons, Ltd.     

弹光调制光电转换放大电路设计

弹光调制干涉具调制的干涉光被探测器接收后输出高速变化的微弱电信号,能否将该电信号提取并放大输出对弹光调制-傅里叶变换光谱仪的研制至关重要。通过对调制干涉光进行理论分析,设计一种具有高信噪比和较高带宽的光电转换放大电路,主要由电源电路、光电转换电路、放大电路、理论通频带为100 kHz~3.5 MHz的带通滤波电路组成。实验结果表明:设计的电路能够将探测器输出的最大频率为1.6 MHz的信号放大至670 mV左右,实现了将探测器输出的微弱速变电信号从背景噪声中有效提取与放大,为后续傅里叶变换提供可靠数据。     

Measurement accuracy analysis of the free carrier absorption determination of the electronic transport properties of silicon wafers

By introducing the random and systematic errors in simulated data computed from conventional frequency-scan and laterally resolved modulated free carrier absorption theory models, we investigate the relative determination sensitivities of three electronic transport properties, namely, carrier lifetime, carrier diffusivity and front surface recombination velocity of silicon wafers determined by frequency-scan and laterally resolved techniques. The phase and amplitude data with random errors as functions of the modulation frequency at zero pump-probe-beam separation or of the two-beam separation at four different modulation frequencies are simultaneously fitted to an appreciated carrier diffusion model to extract three transport parameters. The statistical results and fitted accuracies of the transport parameter determined by both techniques are theoretically analysed. Corresponding experimental results are carried out to compare to the simulated results. The simulated and experimental results show that the determination of the transport properties of silicon wafers by the laterally resolved technique are more accurate, as compared with that by the frequency-scan technique.     

激光调频连续波测距的精度评定方法研究

基于双光纤光路等光频重采样原理,提出了一种距离精度的评定方法.通过推导噪声背景下等光频重采样信号中距离参量的克拉美-罗下边界,得到了影响系统测距精度的两个重要因素:信噪比和扫描带宽,并进行了实验验证.实验表明,该评价方法并不会受到任何距离估算方法的影响,根据此方法可以选择一个最优的距离估算方法.通过对两个影响精度的因素进行仿真分析可知,在扫描带宽为2.2 nm时,若将测量光路的信噪比提升至70 dB以上,系统可获得低于10μm的测距精度.该精度评定方法可为后续改善调频连续波测距系统性能提供理论参考.     

Stochastic resonance in an over-damped linear oscillator

For an over-damped linear system subjected to both parametric excitation of colored noise and external excitation of periodically modulated noise, and in the case that the cross-correlation intensity between noises is a time-periodic function,we study the stochastic resonance(SR) in this paper. Using the Shapiro–Loginov formula, we acquire the exact expressions of the first-order and the second-order moments. By the stochastic averaging method, we obtain the analytical expression of the output signal-to-noise ratio(SNR). Meanwhile, we discuss the evolutions of the SNR with the signal frequency, noise intensity, correlation rate of noise, time period, and modulation frequency. We find a new bona fide SR. The evolution of the SNR with the signal frequency presents periodic oscillation, which is not observed in a conventional linear system. We obtain the conventional SR of the SNR with the noise intensity and the correlation rate of noise. We also obtain the SR in a wide sense, in which the evolution of the SNR with time period modulation frequency presents periodic oscillation. We find that the time-periodic modulation of the cross-correlation intensity between noises diversifies the stochastic resonance phenomena and makes this system possess richer dynamic behaviors.     

高分辨率调频连续波激光绝对测距研究

大空间精密测量在重大装备制造、空间科技、国防工业等方面发挥着重要作用,激光高精度绝对长度测量是大空间精密测量领域的重要研究课题.调频连续波激光测距是近年来激光绝对测距研究的热点,它克服了脉冲法测量分辨率低和相位法激光测距存在2π缠绕模糊度问题的缺点,有着测量精度高、量程大的优点.本文研究了调频连续波激光测距的原理,分析了影响其测距分辨率的主要原因,证明了利用等光频间隔采样来抑制激光调制非线性对测距结果影响的可行性.该方法可以提高测距分辨率,且系统构成简单、实用性强.搭建了光纤调频连续波激光测距系统,并加入了辅助干涉光路对测量信号进行等光频间隔采样.利用该系统进行了测距分辨率实验,实验结果表明,本系统测量分辨率可以达到50μm,测量范围达到了10m.     

二维电磁感应光子带隙的动态生成与调控

研究了由两个垂直传播的强驻波激光场共同耦合的一个四能级Tripod型冷⁸⁷Rb原子介质的稳态光学响应特性. 结果发现, 当两驻波场满足双光失谐条件时, 可在这两驻波场的传播方向上同时获得反射率高达95%以上的电磁感应光子带隙结构; 通过适当调节强激光场, 还可实现一个方向为光子带隙而另一个方向为透明窗口或者两个方向均为透明窗口的结构. 并且光子带隙和透明窗口的频宽和位置是可调谐的. 这种全光控制的二维的信号光禁闭和导通机制可用于实现全光开关和全光路由, 有利于复杂的全光通讯网络的开发. 关键词： 相干诱导光子带隙 电磁感应透明 周期调制原子相干     

Interface modulated electron mobility enhancement in core-shell nanowires

The transport properties of core-shell nanowires (CSNWs) under interface modulation and confinement are investigated based on the atomic-bond-relaxation (ABR) correlation mechanism and Fermi's golden rule. An analytical expression for the relationship between carrier mobility and interface mismatch strain is derived and the influence of size, shell thickness and alloyed layer on effective mass, band structures, and deformation potential constant are studied. It is found that interface modulation can not only reduce the lattice mismatch to optimize the band alignment, but also participate in the carrier transport for enhancing mobility. Moreover, the underlying mechanism regarding the interface shape dependence of transport properties in CSNWs is clarified. The great enhancement of electron mobility suggests that the interface modulation may become a potential pathway to improving the performance of nanoelectronic devices.