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Modulated temperature techniques allow to separate the reversing and non‐reversing contributions of material transitions. To investigate reversible crystallization and melting of isotactic polypropylene (iPP) at microstructural level, in this research, modulated temperature Fourier transform infrared (MTFTIR) and quasi‐isothermal FTIR (QIFTIR) analyses are used. By following the intensity variation of iPP regularity bands, associated with 31 helix structures of different lengths (n repeating units), MTFTIR evidences that, independently from helix length, a reversing coil–helix transition takes place few degrees below the non‐reversing crystallization onset. By comparing spectroscopic and differential scanning calorimetry experiments performed in quasi‐isothermal conditions, the reversing transition was found to be associated with the reversible melting‐crystallization phenomenon. Moreover, QIFTIR evidences that helices of different lengths contribute differently to the reversible transition: the helices composed of n = 10 and n = 12 are active into all the explored temperature range (30–130 °C) whereas the shortest (n = 6) and the longest (n > 15) helices contribute to reversibility at T > 100 °C. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 922–931  相似文献   
134.
We present a coherent ultra-dense wavelength division multiplexing passive optical network (UDWDM-PON) with enhanced spectral efficiency. The benefit of using Gaussian or Nyquist pulse-shaping filters at the transmitter is evaluated through numerical simulations and experiments. The transmitters consist of directly phase modulated distributed feedback (DFB) lasers through beat signals whose duty-cycle and amplitude are digitally adjusted. The results show that transmitting a Nyquist-shaped signal achieves a 25% spectral saving allowing to place 2.5 Gb/s/user data in 6.25 GHz channels. Furthermore, the proposed transmitter tolerates differential link-losses of 15 dB at Rx sensitivity of ?44 dBm at BER=10?3 with intradyne detection.  相似文献   
135.
一种基于小波变换的故障诊断改进算法   总被引:2,自引:0,他引:2  
为提高多传感器组合导航系统对各导航传感器的在线故障检测能力,提出了一种基于调频高斯小波变换的导航传感器故障诊断改进算法。该算法在分析调频高斯小波特性的基础上,采用高斯小波变换计算出观测量的小波系数后,然后利用带遗忘因子的数据平滑算法对小波系数进行平滑,通过判断平滑值来诊断导航工作正常与否。其优点是仅利用传感器的观测量来直接检测导航传感器故障,适当选择小波变换的拉伸因子和数据的衰减因子可以对方差突变等软故障进行有效的在线检测,并解决了误检问题。仿真结果证明了该算法的有效性。  相似文献   
136.
本文提出了三种新的散斑照相孔径方法:一维调频孔径法,交叉孔径法和旋转孔径法。给出了理论分析和实验证明。这些方法简单实用,能有效地改变衍射晕的能量分布。适当选择孔径的参数,实验者能相当任意地控制散斑图的空间频率成份。新方法兼顾了突出某一频率成份、灵敏度连续可调、获得多个方向散斑场运动信息等各方面的特性。  相似文献   
137.
We demonstrate a wireless transmission link at 3.9 THz over a distance of 0.5 m by employing a terahertz (Hz) quantum-cascade laser (QCL) and a THz quantum-well photodetector (QWP). We make direct voltage modulation of the THz QCL and use a spectral-matched THz QWP to detect the modulated THz light from the laser. The small signal model and a direct voltage modulation scheme of the laser are presented. A square wave up to 30 MHz is added to the laser and detected by the THz detector. The bandwidth limit of the wireless link is also discussed.  相似文献   
138.
李冬  吴逢铁  谢晓霞 《物理学报》2014,63(15):152401-152401
提出了一种基于轴棱锥产生零阶近似无衍射Mathieu光束的新方法,利用轴棱锥聚焦具有椭圆高斯振幅调制的平面波,得到近似零阶无衍射Mathieu光束.根据椭圆高斯平面波经轴棱锥衍射的衍射积分公式,对光强分布进行了数值模拟,依据几何光学模型计算了近似无衍射Mathieu光束的最大无衍射距离,并设计了实验对理论模拟的结果进行了验证.实验采用柱透镜和准直扩束系统变换圆高斯光束产生具有椭圆高斯振幅调制的平面波,用轴棱锥聚焦该平面波后得到近似无衍射Mathieu光束,实验结果与理论模拟和计算相符.  相似文献   
139.
For the miniaturization of optical devices, surface plasmon polaritons (SPPs) have been widely utilized due to their outstanding confinement and field‐enhancement characteristics. Analyzing a spectrum of optical signals and splitting certain regions of the spectrum range within a submicrometer‐scale structure are demanded for optical integrated systems. In this paper, a novel type of dichroic surface plasmon launcher that can switch the launching direction according to incident polarization states is demonstrated. Compared to the previously reported plasmonic dichroic splitters, the proposed schemes do not use any asymmetric geometry for directional launching. Hence, the direction of guided SPPs can be interchanged according to the polarization state. Such characteristics will be helpful to design switchable plasmonic devices that can be applied to active plasmonic integrated circuits.  相似文献   
140.
Unconstrained multi-objective optimisation problems with pp positively homogeneous objective functions are considered. We prove that such problems reduce to multi-objective optimisation problems with p−1p1 objectives and a single equality constraint. Thus, problems with two objectives can be solved with standard single objective optimisation methods and, for problems with p>2p>2 objectives, we can compute infinitely many efficient solutions by solving a finite number of single objective problems. The proposed procedure is applied on radiotherapy for cancer treatment.  相似文献   
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