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991.
Three kinds of organic intercalation agent containing flame retardant groups, melamine (MA), triphenylphonium (TPP) chloride, and tetradecyl trihexyl phosphonium (TTP) bromide were intercalated into montmorillonite (MMT) via cation exchange reactions. These modified MMTs are combined with intumescent systems and compounded with PP. The flame retardant and thermal properties of the PP composites are studied. The organic intercalation agents in the layers of MMT play important roles in the char formation and flame retardant properties of PP composites. MA shows a better performance in limiting oxygen index (LOI) value and TPP helps to increase UL‐94 properties, whereas TTP maintains or deteriorates the flame retardancy of polypropylene/intumescent flame retardant (IFR) composites. The LOI and UL‐94 properties increase firstly and then decrease as the content of MMT increases. The MA acts as a blowing agent and emits an inert gas to provide migration impetus, which results in a better intumescent structured and stronger char to endure heat erosion. Although TPP and TTP emit combustible gas that burn, especially for TTP as it has a more flammable aliphatic chain. The synergistic effect between MA‐MMT and IFR is better than that for TPP‐MMT and TTP‐MMT. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
992.
《Comptes Rendus Chimie》2014,17(1):23-29
Sodium borohydride is stabilized on poly(n-butyl-4-vinylpyridinium) chloride, and it is used as an efficient and regenerable polymer-supported borohydride reagent for the reduction of a variety of carbonyl compounds, such as aldehydes, ketones, α,β-unsaturated carbonyl compounds, α-diketones, and acyloins. 相似文献
993.
ShiFa Wang ChuanFei Zhang GuangAi Sun Bo Chen Xia Xiang QingPing Ding XiaoTao Zu 《中国科学:化学(英文版)》2014,57(3):402-408
YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tartaric acid is employed as the chelating agent.In the gel routes,oxalic acid was used as a carboxyl chelating agent,while citric acid or tartaric acid was a carboxyl and hydroxyl chelating agent.The as-prepared samples were characterized by means of techniques such as X-ray powder diffraction(XRD)measurement,thermogravimetric analysis(TG),differential scanning calorimetry analysis(DSC),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),thermal expansion measurement and field-emission scanning electron microscopy(SEM)investigations.It was found that oxalic acid is the best chelating agent with Y(NO3)3·6H2O and Mn(CH3COO)2·4H2O as precursors to prepare a single orthorhombic YMn2O5nanorods at 1000°C.Scanning electron microscope observation shows that the morphology of YMn2O5powders is significantly dependent on the chelating agent.The peaks(single orthorhombic YMn2O5nanorods)at 642,600,573,546,521,493,486,468,448 and 400cm?1were observed from FTIR spectra.The phase,surface morphology and chelation mechanisms of YMn2O5samples have been discussed on the basis of the experimental results. 相似文献
994.
In this paper, we implement a fully phase-encrypted memory system using cascaded extended fractional Fourier transform (FRT). We encrypt and decrypt a two-dimensional image obtained from an amplitude image. The full phase image to be encrypted is fractional Fourier transformed three times and random phase masks are placed in the two intermediate planes. Performing the FRT three times increases the key size, at an added complexity of one more lens. The encrypted image is holographically recorded in a photorefractive crystal and is then decrypted by generating through phase conjugation, the conjugate of the encrypted image. A lithium niobate crystal has been used as a phase contrast filter to reconstruct the decrypted phase image, alleviating the need of alignment in the Fourier plane making the system rugged. 相似文献
995.
996.
Reflectance spectroscopy of gold nanoshells: computational predictions and experimental measurements
Alex W. H. Lin Nastassja A. Lewinski Min-Ho Lee Rebekah A. Drezek 《Journal of nanoparticle research》2006,8(5):681-692
Gold nanoshells are concentric spherical constructs that possess highly desirable optical responses in the near infrared. Gold nanoshells consist of a thin outer gold shell and a silica core and can be used for both diagnostic and therapeutic purposes by tuning the optical response through changing the core–shell ratio as well as the overall size. Although optical properties of gold nanoshells have already been well documented, the reflectance characteristics are not well understood and have not yet been elucidated by experimental measurements. Yet, in order to use gold nanoshells as an optical contrast agent for scattering-based optical methods such as reflectance spectroscopy, it is critical to characterize the reflectance behavior. With this in mind, we used a fiber-optic-based spectrometer to measure diffuse reflectance of gold nanoshell suspensions from 500 nm to 900 nm. Experimental results show that gold nanoshells cause a significant increase in the measured reflectance. Spectral features associated with scattering from large angles (~180°) were observed at low nanoshell concentrations. Monte Carlo modeling of gold nanoshells reflectance demonstrated the efficacy of using such methods to predict diffuse reflectance. Our studies suggest that gold nanoshells are an excellent candidate as optical contrast agents and that Monte Carlo methods are a useful tool for optimizing nanoshells best suited for scattering-based optical methods. 相似文献
997.
Hiroji Fukui Mitsuo Sawamoto Toshinobu Higashimura 《Journal of polymer science. Part A, Polymer chemistry》1993,31(6):1531-1542
A series of multifunctional malonate anions, [Na⊕?C(COOEt)2CH2]mC6H6?m(I; m = 2–4), were examined as polymer coupling agents for the living cationic polymerization of vinyl ethers initiated with the hydrogen iodide/zinc iodide (HI/ZnI2) initiating system. The bifunctional anion ( 2 ;I, m = 2), 1,4-[Na⊕?C(COOEt)2CH2]2C6H4, terminated living polymers of isobutyl vinyl ether (IBVE) (DP n = 10) almost quantitatively in toluene at ?15°C to give coupled living polymers with doubled molecular weights in 96% yield; the dianion 2 was dissolved in tetrahydrofuran containing 18-crown-6 for maintaining the solution homogeneous. The yield of the coupled polymers was increased with shorter living chains or in less polar solvents. Also by coupling via 2 , ABA block copolymers were obtained from living AB block polymers of IBVE and an ester-functionalized vinyl ether (CH2?CHOCH2CH2OCOCH3). Coupling of living poly(IBVE) with the trifunctional anion ( 3 ; I, m = 3) led to tri-armed polymers in 56% yield, whereas with the tetrafunctional version ( 4 ; I, m = 4), only three out of the four anions reacted to give another tri-armed polymer in 85% yield. © 1993 John Wiley & Sons, Inc. 相似文献
998.
999.
Shinto Eguchi 《Annals of the Institute of Statistical Mathematics》1984,36(1):199-206
Summary The optimality of estimation method is investigated in a curved exponential family. A risk function, which is an extension
of a residual sum of squares in regression analysis, is introduced. It is shown that second order efficiency of an estimation
method is equivalent to attain the minimum among limiting risks of all estimation methods. 相似文献
1000.
The different intensities of reflecting and scattering ultrasound signal at the tissue interface of the body can help to deliver the inner information and have proven their tremendous usefulness in medicine. Because it has a lot of advantages such as safety, wide application, good repetition, effi-cient detection, flexibility and economy, ultrasound diagnostics becomes the primary technology of modern medical imaging diagnostics and plays a key role in the modern diagnostic technol-ogy[1]. Alt… 相似文献