The effect of duration of diffusion on Ag diffusion coefficients in YBa2Cu3O7

The Ag diffusion in superconducting YBa₂Cu₃O₇ (YBaCuO) ceramic has been studied over the duration of the diffusion range 5-24 h in the temperature range 700-850 °C by the energy-dispersive X-ray fluorescence (EDXRF) technique. For the excitation of silver atoms, an annular Am-241 radioisotope source (50 mCi) emitting 59.543 keV photons was used. The temperature dependences of silver diffusion coefficients in grains (D₁) and over the grain boundaries in the range 700-850 °C (D₂) are described by the relations D₁=1.4×10⁻² exp[−(1.18±0.10)/kT] and D₂=3.1×10⁻⁴ exp[−(0.87±0.10)/kT].     

Combined experimental and computational study of laminar, axisymmetric hydrogen–air diffusion flames

We investigate the structure of two-dimensional, axisymmetric, laminar hydrogen–air flames in which a cylindrical fuel stream is surrounded by coflowing air, using laser-diagnostic and computational methods. Spontaneous Raman scattering and coherent anti-Stokes Raman scattering (CARS) are used to measure the distributions of major species and temperature. Computationally, we solve the governing conservation equations for mass, momentum, energy, and species, using detailed chemistry and transport. The fuel is diluted with nitrogen (1:1) to reduce heat transfer to the burner, to match the zero temperature gradient at the fuel exit. Three average fuel exit velocities are studied: 18, 27, and 50 cm/s. Comparisons of the measured and computed results are performed for radial profiles at a number of axial positions, and along the axial centerline. Peak major species mole fractions and temperatures are quantitatively predicted by the computations, and the axial species profiles are predicted to within the experimental uncertainty. In the radial profiles studied, base-case computations excluding thermal diffusion of light species were in excellent agreement with the measurements. While the addition of thermal diffusion led to some discrepancy with the measured results, the magnitude of the differences was no more than 25%. The computations predicted the axial centerline profiles from the burner exit to the maximum temperature well, though the experimental temperatures in the downstream mixing region decreased somewhat faster than the computed profiles. Radiative losses are seen to be negligible in these flames, and changes in transport properties and variations in initial flow velocities generally led to only modest changes in the axial profiles. The results also show that the detailed axial profiles of major species and temperature at different fuel jet velocities scale quantitatively with the jet velocity.     

Crystallization of Random Trigonometric Polynomials

We give a precise measure of the rate at which repeated differentiation of a random trigonometric polynomial causes the roots of the function to approach equal spacing. This can be viewed as a toy model of crystallization in one dimension. In particular we determine the asymptotics of the distribution of the roots around the crystalline configuration and find that the distribution is not Gaussian.     

Scaling of spatial correlations in cooperative sequential adsorption with clustering

We examine solvable cooperative sequential adsorption models on a linear lattice where adsorption rates produce strong clustering or island formation. We show that the spatial pair correlations in this regime assume a scaled form for separations comparable to a characteristic length (which diverges in the strong clustering limit). This scaled form is also determined directly from consideration of appropriate solvable continuum grain growth models.     

A lattice Boltzmann equation for diffusion

The formulation of lattice gas automata (LGA) for given partial differential equations is not straightforward and still requires some sort of magic. Lattice Boltzmann equation (LBE) models are much more flexible than LGA because of the freedom in choosing equilibrium distributions with free parameters which can be set after a multiscale expansion according to certain requirements. Here a LBE is presented for diffusion in an arbitrary number of dimensions. The model is probably the simplest LBE which can be formulated. It is shown that the resulting algorithm with relaxation parameter =1 is identical to an explicit finite-difference (EFD) formulation at its stability limit. Underrelaxation (0<<1) allows stable integration beyond the stability limit of EFD. The time step of the explicit LBE integration is limited by accuracy and not by stability requirements.     

Narcissistic aggregation of steroid compounds in diluted solution elucidated by CSI-MS, PFG NMR and X-ray analysis

Large-scale aggregated chain structures of progesterone, estrone, cortisone, hydrocortisone and cholic acid were observed in diluted solution by means of cold-spray ionization mass spectrometry (CSI-MS) and pulsed field gradient (PFG) NMR. The crystal structures were determined by X-ray crystallography, and the relationship between the crystal and solution structures is discussed. It is suggested that the intermolecular hydrogen bondings observed in the crystal might be partly retained in diluted solution.     

Background gradient suppression in pulsed gradient stimulated echo measurements

Pulsed gradient spin echo (PGSE) experiments can be used to measure the probability distribution of molecular displacements. In homogeneous samples this reports on the molecular diffusion coefficient, and in heterogeneous samples, such as porous media and biological tissue, such measurements provide information about the sample's morphology. In heterogeneous samples however background gradients are also present and prevent an accurate measurement of molecular displacements. The interference of time independent background gradients with the applied magnetic field gradients can be removed through the use of bipolar gradient pulses. However, when the background gradients are spatially non-uniform molecular diffusion introduces a temporal modulation of the background gradients. This defeats simple bipolar gradient suppression of background gradients in diffusion related measurements. Here we introduce a new method that requires the background gradients to be constant over coding intervals only. Since the coding intervals are typically at least an order of magnitude shorter than the storage time, this new method succeeds in suppressing cross-terms for a much wider range of heterogeneous samples.     

Solid-state NMR studies for the determination of 11B electric field-gradient tensor orientations in P/B Frustrated Lewis Pairs and related systems

A solid state NMR method is described for measuring the angle Θ specifying the orientation of the principal component of the ¹¹B electric field gradient tensor relative to the ¹¹B^…31P internuclear vector of ¹¹B–³¹P spin pairs. It is based on the anisotropic dephasing of ¹¹B spins in the dipolar field of ³¹P nuclei via ¹¹B{³¹P} Rotational Echo DOuble Resonance (REDOR) experiments. The method is applied to four solid borane–phosphane compounds related to Frustrated Lewis Pair (FLP) chemistry. Results determined by numerical line shape simulations are found in excellent agreement with theoretically calculated values using advanced DFT methods. The angle Θ, which can be measured with an estimated precision of ±5°, offers a clear spectroscopic distinction between classical Lewis-acid/base adducts and active Frustrated Lewis pairs (FLPs).     

Controlled Teleportation of Multi-qudit Quantum Information by Entanglement Swapping

In this paper, we present a scheme for teleporting multi-qudit quantum state, from the sender Alice to the receiver Charlie via many controllers Bobs, whose control parameters are obtained using entanglement swapping of maximally d-dimensional EPR pair. In our scheme, Yang＇s qutrit controlled teleportation protocol [Commun. Theor. Phys. 49 （2008） 338] based on Bell-state entanglement swapping is generalized to the qudit case. The scheme of multi-qudit owns the advantage of having higher code capacity and better security than that of multi-qutrit.