Microwave enhanced greener synthesis of indazoles via nitrenes

Non-traditional methods (grinding, water-based biphasic reactions, microwave chemistry) were used for the preparation of Schiff bases from several amines and 2-nitrobenzaldehydes. These nitro compounds were allowed to react with triethyl phosphite under microwave irradiation for the generation of nitrenes that underwent insertion reactions to form indazoles. This procedure constitutes an energy-efficient, greener chemistry version of the Cadogan reaction for nitrene-based formation of nitrogen heterocycles.     

Minimum distance estimation in linear regression with unknown error distributions

This paper discusses minimum distance (m.d.) estimators of the paramter vector in the multiple linear regression model when the distributions of errors are unknown. These estimators are defined in terms of L₂-distances involving certain weighted empirical processes. Their finite sample properties and asymptotic behavior under heteroscedastic, symmetric and asymmetric errors are discussed. Some robustness properties of these estimators are also studied.     

Some test statistics based on the martingale term of the empirical distribution function

Summary It is proved that the martingale term of the empirical distribution function converges weakly to a Gaussian process inD[0, 1]. Some statistics for goodness-of-fit tests based on the martingale term of the empirical distribution function are proposed. Asymptotic distributions of these statistics under the null hypothesis are given. The approximate Bahadur efficiencies of the statistics to the Kolmogorov-Smirnov statistic and to the Cramér-von Mises statistic are also calculated. The Institute of Statistical Mathematics     

我国企业融资制约与宏观经济发展的关系研究

本通过对我国不同所有制企业的生产效率及其融资制约的分析，认为建立公平、合理、有效的融资体制，有利于宏观经济的快速健康发展。政策性贷款与中央银行贷款对国有企业的扩张发生在国有企业生产已经饱和而民营企业存在剩余生产能力的情形下，将会引发通货膨胀。而由于民营企业生产效率较高，其获得商业贷款能力的增强，会有效的拉动经济增长并降低通货膨胀，因而采取合理的向民营经济倾斜的融资政策，有利于缓解经济“滞胀”的压力。     

Er3+-Yb3+共掺磷酸盐玻璃放大器的大信号增益与量子效率理论分析

研究大信号工作状态下的Er^3 -Yb^3 共掺磷酸盐玻璃波导放大器的增益与量子转换效率。从量子转换效率的定义出发，得出了增益、抽运光功率以及量子转换效率三者之间关系的解析表达式。通过数值求解大信号工作状态下的Er^3 -Yb^3 共掺系统的速率方程与光功率传输方程，讨论了Er^3 浓度、Yb^3 浓度、Yb^3 与Er^3 浓度比率、抽运光功率以及放大器长度等因素对量子转换效率的影响。结果表明提高Er^3 浓度与增加放大器长度均有助于提高量子转换效率，高Er^3 浓度掺杂需要相应的高Yb^3 浓度与之相匹配以减小由于高浓度Er^3 掺杂引起的上转换效应，Yb^3 浓度的提高将降低器件的量子转换效率，Yb^3 -Er^3 浓度之比取1～2较好。     

Hybrid model analysis of the excitation function for alpha induced reaction on121Sb and123Sb

Excitation functions for the reactions¹²¹Sb(α, xn)^125−x I,¹²³Sb(α, xn)^127−x I and¹²¹Sb(α, p3n)¹²¹Te were obtained from the measurements of the residual activity of stacked foils of antimony trioxide evaporated on Al backings from threshold to 60 MeV. The excitation functions for the production of¹²¹I,¹²³I,¹²⁴I,¹²⁶I and¹²¹Te are presented. The experimental data are compared with calculations considering equilibrium as well as pre-equilibrium reaction mechanism according to the hybrid model of Blann. The high energy part of the excitation functions are dominated by the pre-equilibrium reaction mechanism. Calculations were done using a priori calculational method of Overlaid Alice Code of Blann. Most of the excitation functions in the energy range mentioned above could very well be fitted with the hybrid model calculation for exciton numbern=4 withn _n=2 andn _p=2. The overall agreement with the theory is good. Certain discrepancies for example¹²¹Sb(α, p3n)¹²¹Te excitation function, indicate that the production mechanism is different from the one presumed for the calculation.     

Polyethylenimine (PEI)g-comb-poly(ethylene glycol)-transferrin(I): Tumor-targeted Vector for Gene Delivery In-vitro

A new vector, PEG as a core, low Mw PEI was grafted to PEG, and transferrin was conjugated the co-polymer to form PEI-g-PEG-transferrin1,2. NMR, FT-IR and TGA spectroscopy confirmed the structures of activated PEG and the final products. The MW of PEI-g-P…     

Local powers of two-sample and multi-sample rank tests for Lehmann's contaminated alternative

Summary Local powers of two- andk-sample rank tests under alternatives of contaminated distributions are investigated. It is shown that the rank tests based on normal scores and Wilcoxon scores are superior to thet-test or theF-test for many choices of alternatives of contaminated distributions and that the values of the asymptotic relative efficiency of the rank test based on Wilcoxon scores with respect to the normal scores are about one in all the investigated cases.