Solid‐Phase Synthesis of a Seventh‐Generation Inverse Poly(amidoamine) Dendrimer: Importance of the Loading Ratio on the Resin

Here, this study overcomes the current barriers to efficient solid‐phase synthesis of high‐generation dendrimers by decreasing the loading ratio on the resin. G7 inverse poly(amidoamine) dendrimer is now prepared, for the first time, through a solid‐phase synthesis using only 50% of the available reactive sites and by choosing a large resin. This preparation takes only 15 d to afford highly pure product in 80% yield with precipitation being the only purification procedure used. The results clearly show the amount of the initial monomer loaded on the resin to be a vital factor for the ability to use solid‐phase synthesis to produce large dendrimers. This finding also sets stage for the applications of solid‐phase synthesis for the preparation of other macromolecules.

     

碳纳米管添加剂对质子交换膜燃料电池低铂载量膜电极性能的影响研究

以碳纳米管（CNT）作为低铂载量膜电极（CCM）催化层（0.1 mg_Pt·cm^-2）添加剂，研究了CNT的添加方式对催化层微观结构以及膜电极性能的影响.结果表明，与常规低铂载量催化层相比，在其表面喷涂一层CNT或将CNT均匀分散到Pt/C催化层中均有利于提升低铂载量膜电极的输出性能，在70℃和100%相对湿度条件下最高输出功率比常规低铂载量膜电极的0.522 W·cm^-2分别提升了22.4%和60.0%，并且均匀分散添加方式优于分层添加方式.其原因在于分层添加CNT后改善了低铂催化层和气体扩散层之间的接触界面，降低了催化层与扩散层间的接触电阻，而均匀分散添加方式除了可降低界面接触电阻外，还显著改善了低铂催化层中的气体传输，大幅提升了Pt催化剂的利用效率，使得膜电极电化学反应电阻明显降低.进一步对均匀分散添加方式中CNT的载量进行优化，表明CNT添加量为37.5 μg·cm^-2时电池输出性能最佳，70℃和100%相对湿度条件下的最大输出功率达到0.91 W·cm^-2.本研究工作表明，将CNT均匀分散添加到催化层中是一种有效提升低铂载量膜电极性能的方法.     

锡负载量对PtSn/Al2O3催化丙烷脱氢性能的影响

采用羰基合成-浸渍法制备了不同Pt/Sn摩尔比(3:1, 1:1, 1:2和1:3)的PtSn/Al₂O₃催化剂, 利用N₂吸附-脱附实验、 X射线衍射(XRD)、 透射电子显微镜(TEM)、 吡啶吸附红外光谱(Py-IR)和热重-差热分析(TG-DTA)等手段对其进行了表征, 研究了Sn负载量对PtSn/Al₂O₃的结构性质及催化丙烷脱氢性能的影响. 结果表明, 制备的PtSn/Al₂O₃具有较高的丙烯选择性和稳定性. 当Pt/Sn摩尔比为3:1和1:1时, 铂和锡在催化剂上主要以Pt₃Sn和PtSn合金形式存在, 合金的形成明显改善了催化剂的脱氢性能, 可抑制金属颗粒的高温烧结; 当Pt/Sn摩尔比为1:2和1:3时, 铂主要以金属形式存在. 随着Sn负载量的增加, 催化剂上L酸性位逐渐减少, 丙烷转化率降低, 丙烯选择性增加, 同时促使反应积炭从金属表面向载体迁移, 改善了催化剂的稳定性.     

核-隔层-壳结构Fe3O4@MoO3@mSiO2纳米载体的合成及其药物可控释放

利用加热均匀、迅速、热平稳性好和安全性高的微波热响应来实现药物的微波可控释放。引入具有微波热响应性质、热稳定性和化学稳定性好的Mo O3作为微波吸收物质,制备了核-隔层-壳结构Fe_3O_4@MoO_3@mSiO_2纳米药物载体。研究该纳米载体对药物布洛芬(IBU)的负载和微波响应可控释放过程。该纳米载体具有高的比表面积(222 cm2·g-1)和较大的孔隙体积(0.14 cm3·g-1)可用来负载药物。同时还具有较好的磁响应性,可实现药物的靶向给药,具有相对好的微波热响应性,可通过MoO_3中间层吸收微波辐射实现药物的可控释放。结果表明,在持续微波辐射360 min时IBU的释放率达到86%,远远高于仅搅拌时的释放率。     

水热法制备Cu-HMS催化剂及其催化草酸二甲酯加氢性能的研究

以十六胺为模板剂,采用水热合成法制备了一系列不同铜负载量的Cu-HMS催化剂,并考察了其对草酸二甲酯加氢制乙二醇反应的催化性能.同时,通过X射线粉末衍射(XRD)、N_2低温吸附脱附、红外光谱(FI-IR)、H_2程序升温还原(H_2-TPR)及透射电镜(TEM)等手段对催化剂进行了系统表征.结果表明,铜负载量对催化剂活性组分的分散性和载体之间的相互作用力影响很大.实验结果表明,以20%铜负载量制备的Cu-HMS催化剂催化性能优势明显.在反应温度为205℃、压力为2.0 MPa、氢酯比为80 mol/mol及液时空速为0.4 h-1的条件下,草酸二甲酯的转化率接近100%,乙二醇的选择性高达98.11%.     

A filtration of -Catalan numbers

The operator of F. Bergeron, Garsia, Haiman and Tesler [F. Bergeron, A. Garsia, M. Haiman, G. Tesler, Identities and positivity conjectures for some remarkable operators in the theory of symmetric functions, Methods Appl. Anal. 6 (1999) 363–420] acting on the k-Schur functions [L. Lapointe, A. Lascoux, J. Morse, Tableaux atoms and a new Macdonald positivity conjecture, Duke Math. J. 116 (2003) 103–146; L. Lapointe, J. Morse, Schur functions analogs for a filtration of the symmetric functions space, J. Combin. Theory Ser. A 101 (2003) 191–224; L. Lapointe, J. Morse, Tableaux on k+1-cores, reduced words for affine permutations and k-Schur expansion, J. Combin. Theory Ser. A 112 (2005) 44–81] indexed by a single column has a coefficient in the expansion which is an analogue of the (q,t)-Catalan number with a level k. When k divides n we conjecture a representation theoretical model in this case such that the graded dimensions of the module are the coefficients of the (q,t)-Catalan polynomials of level k. When the parameter t is set to 1, the Catalan numbers of level k are shown to count the number of Dyck paths that lie below a certain Dyck path with q counting the area of the path.     

Computing stable loads for pallets

This paper describes an Integer Programming model for generating stable loading patterns for the Pallet Loading Problem under several stability criteria. The results obtained during evaluation show great improvement in the number of stable patterns in comparison with results reported earlier. Moreover, most of the solved cases also ensure optimality in terms of utilization of a pallet.     

The approximation characteristic of diagonal matrix in probabilistic setting

In this paper, the approximation characteristic of a diagonal matrix in probabilistic and average case settings is investigated. And the asymptotic degree of the probabilistic linear (n,δ)$(n,\delta )$-width and p$p$-average linear n$n$-width of diagonal matrix M$M$ are determined.     

PP/PA共混高聚物在冲击载荷下的热粘弹性力学响应

采用Instron1342液压伺服试验机和改进的SHPB技术对2种不同相容剂和重量比的4种PP／PA共混高聚物进行了应变率在10^-4～10^3s^-1宽广范围,温度为25℃、40℃、60℃、80℃下的一维应力力学性能试验．结果表明这类共混高聚物的力学响应对温度和应变率都是敏感的．在准静态时,以PP-g-MAH作相容剂的PP／PA三元体系的应力幅值要高于用TPE-g作界面相容剂的PP／PA三元体系,而在承受冲击载荷下,TPE—g作相容剂的PP／PA三元体系比PP-g-MAH作相容剂的三元体系更有韧性,而在相容剂相同的条件下,随着相容剂质量比重的增加,使得尼龙粒子分布的更加均匀,虽然降低了一定的强度,但提高了韧性,以113材料为例,由其从10^-4～10^3s^-1宽广应变率范围内,20～80℃下的试验数据为依据,以“朱-王-唐”非线性粘弹性本构方程来描述这类PP／PA共混高聚物的力学响应,并拟合得到了其热粘弹性本构参数,理论预言与实验结果在应变小于7％时吻合良好．