Synthesis and crystal structures of extremely crowded oligophenylenes as model precursors to ‘cubic graphite’

By using drastic conditions for a Diels-Alder cycloaddition reaction, it was possible to synthesize an oligophenylene with an extremely dense packing of the benzene rings. Crystallographic data could be obtained and a projection of the structure on the plane of the central phenyl ring reveals that the molecule retained its theoretical threefold symmetry with only minor deviations. Due to its dense packing of interlocked benzene rings, this oligophenylene could be furthermore used as a suitable precursor for constructing a subunit of ‘cubic graphite’.     

Rational approximation to trigonometric operators

We consider the approximation of trigonometric operator functions that arise in the numerical solution of wave equations by trigonometric integrators. It is well known that Krylov subspace methods for matrix functions without exponential decay show superlinear convergence behavior if the number of steps is larger than the norm of the operator. Thus, Krylov approximations may fail to converge for unbounded operators. In this paper, we propose and analyze a rational Krylov subspace method which converges not only for finite element or finite difference approximations to differential operators but even for abstract, unbounded operators. In contrast to standard Krylov methods, the convergence will be independent of the norm of the operator and thus of its spatial discretization. We will discuss efficient implementations for finite element discretizations and illustrate our analysis with numerical experiments. AMS subject classification (2000)  65F10, 65L60, 65M60, 65N22     

On hyperinvariant subspaces of contraction operators on a Banach space whose spectrum contains the unit circle

In this paper, we prove that every operator in a class of contraction operators on a Banach space whose spectrum contains the unit circle has a nontrivial hyperinvariant subspace. This research is supported by the Natural Science Foundation of P. R. China (No. 10771039)     

Restrictions of an invertible chaotic operator to its invariant subspaces

Let M$M$ be a closed subspace of a separable, infinite dimensional Hilbert space H$H$ with dim(H/M)=∞$dim(H/M)=\infty$. We show that a bounded linear operator A:M→M$A:M\to M$ has an invertible chaotic extension T:H→H$T:H\to H$ if and only if A$A$ is bounded below. Motivated by our result, we further show that A:M→M$A:M\to M$ has a chaotic Fredholm extension T:H→H$T:H\to H$ if and only if A$A$ is left semi-Fredholm.     

计及气动和隐身约束结构综合优化的并行子空间优化方法

通过分析基于响应面的并行子空间优化算法的特点指出并行子空间优化算法学科级优化的作用在于向系统级优化响应面提供性能优良的设计点.在此基础上,建立了不要求学科级优化的改进的并行子空间优化算法,进一步降低了设计优化的计算量,解决了分析模块与优化模块间的接口困难.依据该算法建立了结构、气动和隐身一体化设计优化框架,实现了某无人机机翼计及气动和隐身约束的结构综合优化.     

Interaction of a shock wave with a loose dusty bulk layer

The interaction of a planar shock wave with a loose dusty bulk layer has been investigated both experimentally and numerically. Experiments were conducted in a shock tube. The incident shock wave velocity and particle diameters were measured with the use of pressure transducers and a Malvern particle sizer, respectively. The flow fields, induced by shock waves, of both gas and granular phase were visualized by means of shadowgraphs and pulsed X-ray radiography with trace particles added. In addition, a two-phase model for granular flow presented by Gidaspow is introduced and is extended to describe such a complex phenomenon. Based on the kinetic theory, such a two-phase model has the advantage of being able to clarify many physical concepts, like particulate viscosity, granular conductivity and solid pressure, and deduce the correlative constitutive equations of the solid phase. The AUSM scheme was employed for the numerical calculation. The flow field behind the shock wave was displayed numerically and agrees well with our corresponding experimental results.      

Predicting the mode of flow in pneumatic conveying systems-- A review

An initial prediction of the particulate mode of flow in pneumatic conveying systems is beneficial as this knowledge can provide clearer direction to the pneumatic conveying design process. There are three general categories of modes of flow, two dense flows： fluidised dense phase and plug flow, and dilute phase oniy. Detailed in this paper is a review of the commonly used and available techniques for predicting mode of flow. Two types of predictive charts were defined： basic particle parameter based （e.g. particle size and density） and air-particle parameter based （e.g. permeability and de-aeration）. The basic particle techniques were found to have strong and weak areas of predictive ability, on the basis of a comparison with data from materials with known mode of flow capability. It was found that there was only slight improvement in predictive ability when the particle density was replaced by loose-poured bulk density in the basic parameter techniques. The air-particle-parameter-based techniques also showed well-defined regions for mode of flow prediction though the data set used was smaller than that for the basic techniques. Also, it was found to be difficult to utilise de-aeration values from different researchers and subsequently, an air-particle-based technique was developed which does not require any de-aeration parameter in its assessment.     

Characterization of the gas pulse frequency, amplitude and velocity in non-steady dense phase pneumatic conveying of powders

Current modelling techniques for the prediction of conveying line pressure drop in low velocity dense phase pneumatic conveying are largely based on steady state analyses.Work in this area has been on-going for many years with only marginal improvements in the accuracy of prediction being achieved.Experimental and theoretical investigations undertaken by the authors suggest that the flow mechanisms involved in dense phase conveying are dominated by transient effects rather than those of steady state and are possibly the principal reasons for the limited improvement in accuracy.This paper reports on investigations on the pressure fluctuation behaviour in dense phase pneumatic conveying of powders.The pressure behaviour of the gas flow in the top section of the pipeline was found to exhibit pulsatile oscillations.In particular,the pulse velocity showed variation in magnitude while the frequency of the oscillations rarely exceeded 5 Hz.A wavelet analysis using the Daubechie 4 wavelet found that the amplitude of the oscillations increased along the pipeline.Furthermore,there was significant variation in gas pulse amplitude for different types of particulate material.     

A VORTICITY–STREAMFUNCTION FORMULATION FOR STEADY INCOMPRESSIBLE TWO-DIMENSIONAL FLOWS

A vorticity–streamfunction formulation for incompressible planar viscous flows is presented. The standard kinematic field equations are discretized using centred finite difference schemes and solved in a coupled way via a Newton-like linearization scheme. The linearized system of partial differential equations is handled through the restarting linear GMRES algorithm, preconditioned by means of an incomplete LU approximate factorization. The proposed solution technique constitutes a fast and robust algorithm for treating laminar flows at high Reynolds numbers. The pressure field is obtained at a subsequent step by solving a convection– diffusion equation in terms of the stagnation pressure, which presents certain advantages compared with the widely used static pressure Poisson equation. Results are shown for a wide variety of applications including internal and external flows.