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21.
In this study, stoichiometric protonation constants of L-tyrosine, L-cysteine, L-tryptophane, L-lysine, and L-histidine, and their methyl and ethyl esters in water and ethanol–water mixtures of 30, 50, and 70% ethanol (v/v), were determined potentiometrically using a combined pH electrode system calibrated as the concentration of hydrogen ion. Titrations were performed at 25C and the ionic strength of the medium was maintained at 0.10 mol⋅L−1 using sodium chloride. Protonation constants were calculated by using the BEST computer program. The effect of solvent composition on the protonation constants is discussed. The log10 K2 values of esters generally decreased with increasing ethanol content. However, the log10 K1 values of the esters of L-tyrosine, L-cysteine, and L-tryptophane were found to increase with increasing ethanol content in contrast those of L-lysine and L-histidine esters.  相似文献   
22.
非线性互补问题的一种全局收敛的显式光滑Newton方法   总被引:2,自引:0,他引:2  
本针对Po函数非线性互补问题,给出了一种显式光滑Newton方法,该方法将光滑参数μ进行显式迭代而不依赖于Newton方向的搜索过程,并在适当的假设条件下,证明了算法的全局收敛性。  相似文献   
23.
电路过渡过程所列方程是微分方程,本文中采用的是方框图模型分析法,即将微分方程的复杂示解分解成最基本的加(减)、乘(除)、积分(微分)、增益等运算,采用VB设计用户界面产进行计算,并给出了一算例。  相似文献   
24.
It is proved that for any integerk≥ 54 000, there isN k >0 depending onk only such that every even integer ≥N k is a sum of two odd prime numbers andk powers of 2. Project partially supported by RGC Research Grant (No.HKU 7122/97P) and Post-Doctoral Fellowship of the University of Hong Kong.  相似文献   
25.
In this paper we study constant mean curvature compact surfaces with two Jordan curves in parallel planes as boundary and we investigate the point at which the surface inherits the symmetries of its boundary.  相似文献   
26.
We describe a semi-analytical numerical method for coherent isotropic scattering time-dependent radiative transfer problems in slab geometry. This numerical method is based on a combination of two classes of numerical methods: the spectral methods and the Laplace transform (LTSN) methods applied to the radiative transfer equation in the discrete ordinates (SN) formulation. The basic idea is to use the essence of the spectral methods and expand the intensity of radiation in a truncated series of Laguerre polynomials in the time variable and then solve recursively the resulting set of “time-independent” SN problems by using the LTSN method. We show some numerical experiments for a typical model problem.  相似文献   
27.
In circuit-switched networks call streams are characterized by their mean and peakedness (two-moment method). The GI/M/C/0 system is used to model a single link, where the GI-stream is determined by fitting moments appropriately. For the moments of the overflow traffic of a GI/M/C/0 system there are efficient numerical algorithms available. However, for the moments of the freed carried traffic, defined as the moments of a virtual link of infinite capacity to which the process of calls accepted by the link (carried arrival process) is virtually directed and where the virtual calls get fresh exponential i.i.d. holding times, only complex numerical algorithms are available. This is the reason why the concept of the freed carried traffic is not used. The main result of this paper is a numerically stable and efficient algorithm for computing the moments of freed carried traffic, in particular an explicit formula for its peakedness. This result offers a unified handling of both overflow and carried traffics in networks. Furthermore, some refined characteristics for the overflow and freed carried streams are derived.  相似文献   
28.
R S Nikam 《Pramana》1989,32(4):331-339
The Schwinger representation of the SO(8) fermion pair algebra in terms ofd and quasispin vector (u, s, v) bosons is used in deriving a microscopic boson coherent state having both particle-hole and pair excitations. The coherent state is the exact boson image of the HFB variational solution. We can study the shape phase transition and pairing behaviour of the nuclear ground states using the coherent states.  相似文献   
29.
Yb3+掺杂KY(WO4)2激光晶体生长、结构与光谱分析   总被引:1,自引:0,他引:1       下载免费PDF全文
采用顶部籽晶提拉法(TSSG)生长出Yb:KY(WO4)2(Yb:KYW)激光晶体.对预烧后的原料及晶体进行了XRD分析,结果表明,分别在920℃和600℃预烧8h后的熔质和助熔剂基本上形成一相,抑止了实验中的挥发问题;所生长的晶体为β-Yb:KYW,计算其晶格常数为a=1.063nm,b=1.034nm,c=0.755nm,β=130.75°.测得不同厚度样品的吸收光谱,结果表明样品在933nm和981nm有较强的吸收峰,计算出主峰981nm的吸收截面σ关键词: Yb:KYW TSSG法 晶体结构 光谱参数  相似文献   
30.
The Chang-Łoś-Suszko theorem of first-order model theory characterizes universal-existential classes of models as just those elementary classes that are closed under unions of chains. This theorem can then be used to equate two model-theoretic closure conditions for elementary classes; namely unions of chains and existential substructures. In the present paper we prove a topological analogue and indicate some applications.  相似文献   
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