全文获取类型
收费全文 | 6855篇 |
免费 | 501篇 |
国内免费 | 661篇 |
专业分类
化学 | 3958篇 |
晶体学 | 194篇 |
力学 | 643篇 |
综合类 | 56篇 |
数学 | 918篇 |
物理学 | 2248篇 |
出版年
2024年 | 11篇 |
2023年 | 34篇 |
2022年 | 75篇 |
2021年 | 94篇 |
2020年 | 101篇 |
2019年 | 96篇 |
2018年 | 93篇 |
2017年 | 136篇 |
2016年 | 159篇 |
2015年 | 136篇 |
2014年 | 245篇 |
2013年 | 447篇 |
2012年 | 287篇 |
2011年 | 331篇 |
2010年 | 286篇 |
2009年 | 418篇 |
2008年 | 482篇 |
2007年 | 509篇 |
2006年 | 430篇 |
2005年 | 461篇 |
2004年 | 462篇 |
2003年 | 323篇 |
2002年 | 323篇 |
2001年 | 243篇 |
2000年 | 239篇 |
1999年 | 238篇 |
1998年 | 208篇 |
1997年 | 187篇 |
1996年 | 139篇 |
1995年 | 145篇 |
1994年 | 122篇 |
1993年 | 113篇 |
1992年 | 116篇 |
1991年 | 45篇 |
1990年 | 36篇 |
1989年 | 36篇 |
1988年 | 33篇 |
1987年 | 36篇 |
1986年 | 25篇 |
1985年 | 13篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 12篇 |
1981年 | 14篇 |
1980年 | 4篇 |
1979年 | 21篇 |
1978年 | 12篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1973年 | 2篇 |
排序方式: 共有8017条查询结果,搜索用时 0 毫秒
71.
The technique of temperature waves to measure the complex thermophysical characteristics of materials has been proposed. The relations for the moduli and arguments of these characteristics for the case of plane temperature waves have been calculated. The temperature dependences of the moduli and arguments of complex thermophysical characteristics of polyvinylacetate (PVAc) at different frequencies and also the temperature dependences of its vibrational and configurational heat capacities have been determined. It has been shown that the vibrational heat capacity of PVAc in the region of softening grows sharply and its configurational heat capacity goes through a peak. The segmental mobility has been found to affect the heat transfer in the polymer in an ambivalent way causing both a decrease and increase of thermal conductivity.
Zusammenfassung Zur Bestimmung der komplexen thermophysischen Eigenschaften von Stoffen wurde eine Temperaturwellentechnik vorgeschlagen. Für den Fall zweidimensionaler Temperatur-wellen wurden die Verhältnisse von Moduli und Argumenten dieser Eigenschaften berechnet. Die Temperaturabhängigkeit von Moduli und Argumenten der komplexen thermophysischen Eigen-schaften von Polyvinylacetat (PVAc) bei verschiedenen Frequenzen und auch die Temperatur-abhängigkeit seiner Vibrations- und Konfigurations-Wärmekapazitäten wurden bestimmt. Es wurde gezeigt, daß die Vibrations-Wärmekapazität von PVAc im Erweichungsbereich scharf zunimmt und die Konfigurations-Wärmekapazität durch einen Peak geht. Man fand, daß die Segment-Mobilität den Wärmetransport im Polymer auf eine ambivalente Weise beeinflußt, in dem die Wärmeleit-fähigkeit entweder gesenkt oder angehoben wird.相似文献
72.
H. Brtell G. Rietz S. Sandqvist M. Berg H. Ehrsson 《Journal of separation science》1982,5(11):596-603
A two- dimensional gas chromatograph based on the Deans switching principle is described. The unit comprises two separate ovens, each containing a fused silica capillary column. The columns are joined in a specially designed manifold permitting heart cuts to be performed without significant decrease in efficiency. The switching speed and the retention time stability of the system made it possible to perform heart cuts of only a few seconds' duration. The system has been used under isothermal conditions for the determination of an amino alcohol (KABI 2128) in the low ng/ml range after trifluoroacetylation and with electron capture detection. A much shorter clean-up procedure could be used in combination with the two-dimensional gas chromatograph as compared to a method using a single glass capillary column. 相似文献
73.
The isothermal and temperature scanning calorimeters manufactured by Calorimetry Sciences Corporation are briefly described. Applications of calorimetry to determine thermodynamics and kinetics of reactions of interest in biotechnology are described with illustrative examples. 相似文献
74.
The thermal properties of -lactoglobulin (-LG) were studied by differential scanning calorimetry (DSC) under different medium conditions.pH, neutral salts, protein perturbants, and polyols all affected the DSC characteristics of -LG. Acylation with fatty acids also changed the thermal properties, particularly peak width at half-height. The results suggest that the structural stability of -LG is controlled by non-covalent forces, particularly electrostatic and hydrophobic interactions. Disulfide bonds did not contribute to the thermal response of -LG. Fatty N-acyl-amino acids caused marked increases in thermal stability and decreases in denaturation enthalpy, and additional peaks were observed in the presence of some palmitoyl derivatives.Contribution No. 2310, Centre for Food and Animal Research.We thank D. Raymond for her excellent technical assistance. 相似文献
75.
C.?Korah Bina K.?G.?Kannan K.?N.?NinanEmail author 《Journal of Thermal Analysis and Calorimetry》2004,78(3):753-760
The urethane forming cure reactions of hydroxyl terminated polybutadiene (HTPB) binder with three different isocyanate curatives, viz., toluene diisocyanate (TDI), isophorone diisocyanate (IPDI) and 4,4-methylene bis(cyclohexyl isocyanate) (MCHI), were investigated by differential scanning calorimetry (DSC). The effect of two cure catalysts, viz., dibutyl tin dilaurate (DBTDL) and ferrric tris-acetylacetonate (FeAA) on the cure reactions was also studied. Cure kinetics was evaluated using the multiple heating rate Ozawa method. The reactivities of the three isocyanates and catalytic efficiencies were compared based on the DSC reaction temperatures, activation energies and rate constants. Viscosity build-up in these systems at isothermal temperature was also studied and compared with the results from DSC. 相似文献
76.
Summary Thermomagnetometry has been applied to mineralized archaeological iron samples and samples from accelerated corrosion tests. It has successfully quantified the degree of corrosion, measured by the loss of iron, as well as the amount of magnetite formed and water held in the corrosion and adhered soil layers. Thermomagnetometry, thermogravimetric analysis and differential scanning calorimetry have been applied to the reported corrosion products from archaeological iron. Fourier transform infra-red and Raman spectroscopies and X-ray diffraction analyses were undertaken on the residues and at intermediate heating stages, where the thermal analyses indicated, to identify the reaction products. 相似文献
77.
V. Balek H. Hamerská L. Montanaro A. Negro 《Journal of Thermal Analysis and Calorimetry》1992,38(4):567-573
The results of the investigations of thermal behaviour of Li2ZrO3, prepared in the amorphous state by means of sol-gel technique are demonstrated. The thermal treatment was carried out in air under constant heating rate of 5 deg·min–1 and cooling rate of 2.5 deg·min–1. The methods of DTA, TG, Emanation Thermal Analysis (ETA) and dilatometry were used, for characterization of the thermal behaviour in dynamic conditions. The X-ray diffraction patterns were used for characterization of the phase changes observed by TA Methods.
Zusammenfassung Ergebnisse aus Untersuchungen des thermischen Verhaltens von Li2ZrO3, hergestellt mittels einer Sol-Gel-Technik im amorphen Zustand werden dargelegt. Die thermische Behandlung wurde in Luft bei einer konstanten Aufheizgeschwindigkeit von 5 Grad·min–1 und einer Abkühlgeschwindigkeit von 2,5Grad·min–1 durchgeführt. Zur Beschreibung des thermischen Verhaltens unter dynamischen Verhältnissen wurden DTA, TG, Emanationsthermoanalyse und Dilatometrie angewendet. Zur näheren Charakterisierung der bei TG beobachteten Phasenumwandlungen wurde Röntgendiffraktion verwendet.相似文献
78.
79.
By the use of differential scanning calorimetry (DSC), a new method to measure the wax content of crude oil has been developed. In this paper, the wax content of a crude oil is proposed and proved to be the Q (total thermal effect of wax precipitation in sample) ratio of the crude oil and its corresponding wax obtained by using standard acetone method, i.e. Qoil/Qwax. For the 14 studied crude oils with the wax content ranging from 1 to 27 wt.%, the wax contents determined by the presented method are in good agreement with those determined by standard acetone method, with an absolute average deviation of only 0.82 wt.%. This method has an advantage over reported DSC methods in which the exact dissolution or precipitation enthalpy of wax is a must. It is also found that the wax contents determined by either of the two methods show good linear relationship with the total thermal effect Qoil, with the correlation coefficients over 0.96. According to the empirical correlations, the wax content of a crude oil can be easily determined by using the DSC total thermal effect Qoil. In addition and more significantly, the new method can be applied to improve the accuracy in determining the amount of precipitated wax in a waxy crude oil at different temperatures. 相似文献
80.
Scanning calorimetric methods permit determination of heat capacities at high temperatures up to 1600°C. For disk systems
with power compensation application limits are in order of 700°C, and for cylindrical systems with electrical calibration
up to 1000°C. For the high temperature range above 1000°C DSC plates and a cylindrical calorimetric systems based on the CALVET
principle ('MULTI HTC’) are known. For cylindrical calorimetric systems the precision of the Cp data is between 2 and 5% even
at high temperatures without any requirements on the kind and shape of samples. These results are better than data provided
by DSC plate systems.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献