全文获取类型
收费全文 | 2494篇 |
免费 | 312篇 |
国内免费 | 172篇 |
专业分类
化学 | 692篇 |
晶体学 | 9篇 |
力学 | 625篇 |
综合类 | 27篇 |
数学 | 368篇 |
物理学 | 1257篇 |
出版年
2024年 | 3篇 |
2023年 | 23篇 |
2022年 | 42篇 |
2021年 | 52篇 |
2020年 | 58篇 |
2019年 | 58篇 |
2018年 | 49篇 |
2017年 | 50篇 |
2016年 | 51篇 |
2015年 | 43篇 |
2014年 | 110篇 |
2013年 | 193篇 |
2012年 | 125篇 |
2011年 | 135篇 |
2010年 | 135篇 |
2009年 | 168篇 |
2008年 | 184篇 |
2007年 | 172篇 |
2006年 | 189篇 |
2005年 | 148篇 |
2004年 | 154篇 |
2003年 | 109篇 |
2002年 | 99篇 |
2001年 | 75篇 |
2000年 | 66篇 |
1999年 | 53篇 |
1998年 | 70篇 |
1997年 | 56篇 |
1996年 | 48篇 |
1995年 | 47篇 |
1994年 | 34篇 |
1993年 | 21篇 |
1992年 | 26篇 |
1991年 | 26篇 |
1990年 | 26篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有2978条查询结果,搜索用时 15 毫秒
61.
从介质对光的吸收机理出发,研究了吸收系数较小的受激布里渊散射(SBS)新介质六氯-1,3-丁二烯(C4Cl6)。通过基本的物理参数,确定了入射光波长为1 064 nm时C4Cl6的SBS参数,其吸收系数约为0.003 cm-1,声子寿命约为0.25 ns,增益系数约为4.9 cm·GW-1。分析了入射光波长与介质SBS参数的关系,布里渊频移与入射光波长成反比,声子寿命与入射光波长的平方成正比,增益系数一般与入射光波长无关。在单池SBS系统中,利用Nd:YAG调Q激光器研究了C4Cl6的SBS性能。实验结果表明:由于其吸收系数小,与具有相同增益系数的H2O比较,C4Cl6具有较高的能量反射率(饱和能量反射率大于55%)和较宽的SBS脉宽;由于其声子寿命短,与具有相同吸收系数的CS2比较,C4Cl6的SBS波形上升时间较短。吸收系数小和声子寿命短的特点,使C4Cl6适合作为放大池介质,这对优化SBS介质选取,提高SBS系统性能具有一定意义。 相似文献
62.
《Waves in Random and Complex Media》2013,23(1):75-90
In this paper, we seek exact solutions of generalized Zakharov system. We use extended trial equation method to obtain exact solutions of this system. Consequently, we obtain some exact solutions including soliton solutions, rational, Jacobi elliptic and hyperbolic function solutions of this system by using extended trial equation method. 相似文献
63.
An aqueous aza-Michael reaction is efficiently achieved with excellent conversions without any additives. The method works very well on a molar scale with selectively for aliphatic amines. An intermediate for spermine is also made by this green process. 相似文献
64.
65.
Salvatore Campione Michael B. Sinclair Filippo Capolino 《Photonics and Nanostructures》2013,11(4):423-435
We review some of the techniques that lead to the effective medium representation of a three-dimensional (3D) periodic metamaterial. We consider a 3D lattice of lead telluride cubic resonators at mid-infrared (MIR) frequencies. Each cubic resonator is modeled with both an electric and a magnetic dipole, through a method called the dual dipole approximation. The electric and magnetic polarizabilities of a cubic resonator are computed via full-wave simulations by mapping the resonator's scattered field under electric/magnetic excitation only to the field radiated by an equivalent electric/magnetic dipole. We then analyze the allowed modes in the lattice, with transverse polarization and complex wavenumber, highlighting the attenuation that each mode experiences after one free space wavelength. We observe the presence of two modes with low attenuation constant, dominant in different frequency ranges, able to propagate inside the lattice: this allows the treatment of the metamaterial as a homogeneous material with effective parameters, evaluated by using various techniques. We then show that the metamaterial under analysis allows for the generation of artificial magnetism (i.e., relative effective permeability different than unity, including negative permeability with low losses) at MIR frequencies. 相似文献
66.
A general and efficient method for the synthesis of benzo-fused 7- and 8-membered ring lactams via the Beckmann rearrangement of cyclic oximes is presented. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file. 相似文献
67.
Rolf Appel Peter Schulte Falk Knoch 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):195-198
Abstract Two imino(bismethylene)phosphat-ions can be synthesized via reaction of phenylamino- and α-naphthylaminobismethylenephosphorane with n-butyllithium in tetrahydrofuran. Anions containing [sgrave]3λ6-bounded phosphorus are stabilized in the crystal with THF-solvated lithium-kations. Zwei Imino(bismethylen)phosphat-ionen werden durch Umsetzung des Phenylamino- und des α-Naphthylaminobismethylenphosphorans mit n-Butyllithium in Tetrahydrofuran erhalten. Die Anionen mit [sgrave]3λ6-gebundenem Phosphor werden im Kristall durch THF-solvatisierte Lithium-Kationen stabilisiert. 相似文献
68.
We study “large” nonnegative solutions for a class of quasilinear equations model of which is We give a sufficient condition on the exponents and for the removability of isolated singularities. 相似文献
69.
Synthesis of Schiff's bases in aqueous medium: a green alternative approach with effective mass yield and high reaction rates 总被引:1,自引:0,他引:1
《Green Chemistry Letters and Reviews》2013,6(3):217-223
Abstract Schiff's bases constitute a class of pharmaceutical and medicinally important molecules. The conventional methods for the synthesis of Schiff's bases require long reaction times and use of organic solvents. We report a novel and eco-friendly condensation reaction method permitting the “green synthesis” of various Schiff's bases by stirring 1,2-diaminobenzene with various aromatic aldehydes in water as solvent. This method is experimentally simple, clean, high yielding, green, and with reduced reaction times. The product is purified by simple filtration followed by washing with water and drying processes. 相似文献
70.
Aryl–heteroaryl and heteroaryl–heteroaryl compounds are obtained through the Suzuki–Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda–Heck reaction between several monoolefins with aryldiazonium salts. 相似文献