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41.
S. V. Fokin G. V. Romanenko M. Baumgarten V. I. Ovcharenko 《Journal of Structural Chemistry》2003,44(5):864-869
The organomercury biradical HgL2 (L is deprotonated 4,4,5,5-tetramethyl-2-imidazoline-3-oxide-1-oxyl) is capable of performing the bridging function for design of multinuclear heterospin systems. This paper describes synthesis and crystal structure of HgL2 and the first multinuclear complexes of Cu(hfac)2 with HgL2. 相似文献
42.
IntroductionCatal}ticrcactionsaffcctcdb}'diffosionaIlimitationincatal}'stporcshavcbccnextensive1}dcaltx`ithinlit.rat.rcll~5I.Scvcraltcchniqucsonthcspccialcase0fFischcr-Tropschs}'nthcsis(FTS)t\crcapplicdtocxplorcthebchaviorofthiscatal}ticrcactionundercxpcrimcntalandopcrationaIconditionsI3~5l.It`"ouldbeofvaluctoindicatchcrcthatthcseinvcstigationsx"ercmainl}'bascdonthesimplcstkineticsofthcfirstordcrinH2proposedbyAndersonl6]attheearIystages.However-thesetboents,striCtlyspeaking,areinvalidfor… 相似文献
43.
The ENDOR spectrum of ~(14)N-~(63)Cu-HAP complex in DMSO/EtOH (5:1) freezing solution at 20 K has been studied using orientational selective method in this paper. The anisotropic superhyperfine coupling tensor and qusdrupole coupling tensor of ligand ~(14)N nucleus, and the superhyperfine coupling tensor of various ~1H nuclei have been measured precisely. Comparing the superhyperfine coupling tensor of ~(14)N-nucleus with previous work shows that the analytical method of spectrum is reasonable and the data are reliable in our previous work. 相似文献
44.
A fluorescent aminoacid was designed for selective and sensitive detection of Cu(II) in aqueous solution. The designing of this Cu(II) fluorescent chemosensing molecule, N ± (1‐naphthyl). aminoacetic acid (NAA), was based on the binding of Cu(II) to aminoacetic acid and the novel charge transfer photophysics of 1‐aminonaphthalenes. The fluorescence of NAA was found quenched by Cu (II) and several other metal ions of similar electronic structure such as Co(II), Ni(II) and Zn(II). The quenching was shown to occur via electron transfer within the metal‐NAA complex, which required an optimal combination of high binding affinity and favorable redox properties of the components in the metal‐NAA complex and hence afforded selective fluorometric detection of Cu(II). The calibration graph obeyed Stern‐Volmer theory and was shown for Cu(II) over the range of 0–2.75 ± 10–4 mol/L. The quenching constant of Cu(II) was measured as 8.0 ± 103 mol/L that was two orders of magnitude higher than those of Co(II), Ni(II) and Zn(II). The 3SD limit of detection for Cu(II) was 8.00 ± 10?6 mol/L with a coefficient of variation of 1.65%. Linear range for quantitative detection of Cu(II) was 2.67 ± 10?5‐2.75 ± 10?4 mol/L. The method was applied to synthetic sample measurements which gave recoveries of 105%‐112%. 相似文献
45.
纳米材料,包括尺寸为纳米量级的超细微粒?线?薄膜?量子阱和超晶格等引起了人们广泛的重视 [1,2] ?其中 , 半导体纳米微粒和由其构成的纳米固体结构开辟了材料科学研究的新领域?硫化镉 (CdS) 作为一种重要的Ⅱ - Ⅵ族无机半导体材料 , 具有独特的光电性质 , 在光电化学电池和多相光催化反应中都有广泛应用?近年来 , 已有大量关于合成 CdS 纳米结构的文献报导 [3~12] , 所采用的方法如反胶束法?单分子膜法?自组装法以及电化学沉积法等 , 其中非水电解与模板技术相结合的制备方法引起了人们高度的重视并且被广泛的采用?自从 Baranski 等在上… 相似文献
46.
添加剂铜和银离子对MnO2催化燃烧CH4的影响 总被引:2,自引:1,他引:2
催化燃烧法,由于起燃温度低、去除率高、适用氧浓度范围大、无二次污染、燃烧缓和等,是国内外治理有机废气时,回收利用能量最有效的方法之一[1].但目前用于该过程的催化剂中均含有来源有限、价格昂贵的贵金属铂或钯[2].因此,寻找来源丰富、价格低廉、性能相当... 相似文献
47.
48.
I. F. Tcholakova R. D. Shopova D. D. Rustschev 《Journal of Thermal Analysis and Calorimetry》1995,44(5):1155-1158
The thermal behaviour of some Cu(II) compounds formed with 1,4-disubstituted piperazine derivatives has been studied. The investigations were performed on a MOM 1500 derivatograph. The endothermic effects observed at 170–180°C are associated with the processes of dehydration and dehalogenation of the compounds, with general formula LH2·CuCl4·H2O, whereL is the piperazine derivative. The residue at 600°C remains relatively constant. 相似文献
49.
MENG Jian REN Yu-Fang LI Xiao-GuangLaboratory of Rare Earth Chemistry Physics Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin ChinaPopov V.V. Repin S.M. Smirnov LA. loffe Physicotechnical Institute Russian Academy of Sciences Saint Petersburg Russia 《中国化学》1994,12(5):419-424
YBa2Cu3-xVxO7-y(x=0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) superconductors have been prepared. X-ray diffraction shows that the system remains orthorhombic for all compositions studied, but for x > 0.4 V2O5 was detected as an impurity phase. Substitution of V5+ for Cu2+ occurs in the Cu(2) sites on the Cu(2)-O planes. The introduction of the high valence element, vanadium, produces the extra free-electrons. These electrons recombine with the positive carrier of the system. It makes depression of the mobility and the Hall number of YBa2Cu3-xVxO7-v and also results in a depression of TC. 相似文献
50.
H. A. Azab A. M. El-Nady A. Hassan R. S. A. Azkal 《Monatshefte für Chemie / Chemical Monthly》1993,124(6-7):637-646
Summary Potentiometric equilibrium measurements have been made at 25±0.1°C (=0.1 mol dm–3 KNO3) for the interaction of adenosine-5-mono-, -di- and -triphosphate (AMP,ADP andATP) and Cu(II) with biologically important secondary ligand acids (malic, maleic, succinic, tartaric, citric and oxalic acids) in a 1:1:1 ratio and the formation of various 1:1:1 mixed ligand complex species inferred from the potentiometricpH titration curves. Initial estimates of the formation constants of the resulting species and the acid dissociation constants ofAMP,ADP,ATP, and secondary ligand acid, have been refined with the SUPERQUAD computer program. In some systems logK values are positive, i.e. the ternary complexes are found to be more stable than the corresponding binary complexes. In some Cu(II) ternary systems the interligand interactions between the coordinate ligands, possibly H bond formation, have been found to be most effective in deciding the stability of the ternary complexes formed in solution. Stabilities of mixed ligand complexes increase in the orderAMP <ADP <ATP. With respect to the secondary ligands, the formation constants of the mixed ligand complexes decrease in the order succinic > maleic > tartaric > malic > citric > oxalic acid.
Ternäre Komplexe in Lösung. Vergleich der Koordinationstendenz einiger polybasischer Sauerstoffsäuren gegenüber binären Komplexen von Cu(II) mitAMP,ADP oderATP
Zusammenfassung Es wurden potentiometrische Gleichgewichtsmessungen bei 25±0.1°C bei =0.1 mol dm–1 KNO3 durchgeführt, um die Wechselwirkung von Adenosin-5-mono-, -di- und triphosphat mit Cu(II) und biologisch relevanten Sekundärliganden wie Äpfel-, Malein-, Bernstein-, Wein-, Zitronen- und Oxalsäure im Verhältnis 1:1:1 festzustellen. Aus den potentiometrischenpH-Titrationskurven ergaben sich verschiedene 1:1:1 gemischte Ligandenkomplexe. Anfänglich abgeschätzte Komplexbildungskonstanten der Komplexe und Säuredissoziationskonstanten vonAMP,ADP undATP und den Sauerstoffsäuren wurden mittels des Computerprogramms SUPERQUAD verfeinert. In einigen Systemen ist logK positiv, demzufolge sind die ternären Komplexe stabiler als die korrespondierenden binären. In einigen ternären Cu(II)-Komplexen bestehen zwischen den Liganden Wechselwirkungen, vermutlich auf der Basis von stabilitätsfördernden Wasserstoffbrückenbindungen. Die Stabilitäten der gemischten Komplexe steigen in der ReihenfolgeAMP <ADP <ATP. Bezüglich der Sekundärliganden ergibt sich für die Bildungskonstanten der ternären Komplexe die Reihung Bersteinsäure > Maleinsäure > Weinsäure > Äpfelsäure > Zitronensäure > Oxalsaure.相似文献