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101.
102.
Jin-Mok Hur Chung-Seok Seo Sun-Seok Hong Dae-Seung Kang Seong-Won Park 《Reaction Kinetics and Catalysis Letters》2003,80(2):217-222
The concept of a novel electrochemical reduction process for the treatment of spent nuclear fuels in Li2O-LiCl molten salt was proposed and fresh tests using U3O8 powder were carried out to elucidate the reaction mechanism and verify the feasibility of the process. Electrolysis of Li2O and reduction of U3O8 powder took place simultaneously at the cathode part of the electrolysis cell via a catalytic EC mechanism and the conversion of U3O8 to U metal was more than 99%.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
103.
Summary. We consider the spline collocation method for a class of parabolic pseudodifferential operators. We show optimal order convergence
results in a large scale of anisotropic Sobolev spaces. The results cover the classical boundary integral equations for the
heat equation in the general case where the spatial domain has a smooth boundary in the plane. Our proof is based on a localization
technique for which we use our recent results proved for parabolic pseudodifferential operators. For the localization we need
also some special spline approximation results in anisotropic Sobolev spaces.
Received May 17, 2001 / Revised version received February 19, 2002 / Published online April 17, 2002 相似文献
104.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献
105.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献
106.
Dinesh Topwal U. Manju Sugata Ray S. Raj D. D. Sarma S. R. Krishnakumar M. Bertolo S. La Rosa G. Cautero 《Journal of Chemical Sciences》2006,118(1):87-92
Disordered Sr2FeMoO6 shows a drastic reduction in saturation magnetization compared to highly ordered samples, moreover magnetization as a function
of the temperature for different disordered samples shows qualitatively different behaviours. We investigate the origin of
such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish
that extensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples, is
responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with
composition fluctuations of the type Sr2Fe1+x
Mo1-x
O6 with Fe-rich (x > 0) and Mo-rich (x < 0) regions.
Dedicated to Prof J Gopalakrishnan on his 62nd birthday. 相似文献
107.
108.
Vibsanin O, isolated from the leaves and twigs of Viburnum awabuki, is an unprecedented bicyclic diterpenoid. The structures of vibsanin O was established by extensive analysis of spectroscopic data. 相似文献
109.
Parameters of Gaussian multivariate models are often estimated using the maximum likelihood approach. In spite of its merits, this methodology is not practical when the sample size is very large, as, for example, in the case of massive georeferenced data sets. In this paper, we study the asymptotic properties of the estimators that minimize three alternatives to the likelihood function, designed to increase the computational efficiency. This is achieved by applying the information sandwich technique to expansions of the pseudo-likelihood functions as quadratic forms of independent normal random variables. Theoretical calculations are given for a first-order autoregressive time series and then extended to a two-dimensional autoregressive process on a lattice. We compare the efficiency of the three estimators to that of the maximum likelihood estimator as well as among themselves, using numerical calculations of the theoretical results and simulations. 相似文献
110.
Matthew D. Horton 《Linear algebra and its applications》2007,425(1):130-142
After defining and exploring some of the properties of Ihara zeta functions of digraphs, we improve upon Kotani and Sunada’s bounds on the poles of Ihara zeta functions of undirected graphs by considering digraphs whose adjacency matrices are directed edge matrices. 相似文献