全文获取类型
收费全文 | 1013篇 |
免费 | 73篇 |
国内免费 | 52篇 |
专业分类
化学 | 349篇 |
晶体学 | 5篇 |
力学 | 59篇 |
综合类 | 4篇 |
数学 | 142篇 |
物理学 | 579篇 |
出版年
2023年 | 9篇 |
2022年 | 20篇 |
2021年 | 12篇 |
2020年 | 15篇 |
2019年 | 13篇 |
2018年 | 12篇 |
2017年 | 37篇 |
2016年 | 34篇 |
2015年 | 41篇 |
2014年 | 75篇 |
2013年 | 70篇 |
2012年 | 36篇 |
2011年 | 73篇 |
2010年 | 48篇 |
2009年 | 70篇 |
2008年 | 65篇 |
2007年 | 62篇 |
2006年 | 70篇 |
2005年 | 48篇 |
2004年 | 30篇 |
2003年 | 34篇 |
2002年 | 27篇 |
2001年 | 24篇 |
2000年 | 16篇 |
1999年 | 20篇 |
1998年 | 19篇 |
1997年 | 17篇 |
1996年 | 14篇 |
1995年 | 15篇 |
1994年 | 17篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 8篇 |
1988年 | 3篇 |
1987年 | 9篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1972年 | 1篇 |
排序方式: 共有1138条查询结果,搜索用时 15 毫秒
91.
Apparent correlations are found between the N-H chemical shifts of congeneric series of compounds and the dipole moments of the molecules, such as lactams and thiolactams, cyclic ureas and thioureas. When there is a high degree of correlation, either the N-H chemical shift or the dipole moment of the molecule can be used as an electronic parameter in correlating the biological activity with the chemical structure. In a series of substituted salicylaldehydes the Hammett σ constant gives better correlation with the biological activity than the O-H chemical shift. This is probably due to the anisotropic effect of the substituent besides the electronic effect. Other factors affecting the N-H chemical shift, e.g. intramolecular hydrogen-bonding of nitrosoureas and the deshielding effect of a benzene ring, in o-phenyleneureas are also presented. In spite of the limitations, the chemical shifts of many compounds can be obtained very easily, therefore, their uses in structure-activity correlations deserve further investigation. 相似文献
92.
Density and viscosity were determined for the binary mixtures containing the ionic liquid 1-butyl-3-methylimidazolium thiocyanate
([BMIM][SCN]) and 1-alcohols (1-butanol, 1-pentanol and 1-hexanol) at six temperatures (298.15, 308.15, 318.15, 328.15, 338.15
and 348.15) K and ambient pressure. The density and viscosity correlation for these systems was tested by an empirical second-order
polynomial and by the Vogel-Fucher-Tammann equation in wide ranges of temperatures. Excess molar volumes were described by
the Redlich-Kister polynomial expansions. The density and viscosity variations with composition were described by polynomials.
A qualitative analysis of the trend of the properties with solvent and temperature was performed. The obtained results indicate
that ionic liquid interactions with 1-alcohols are strongly dependent on the special trend of packing of this ionic liquid
into hydroxylic solvents. As previously observed, an increase of the 1-alcohol carbon-chain length leads to lower interactions
on mixing.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献
93.
The validity of many efficiency measurement methods rely upon the assumption that variables such as input quantities and output mixes are independent of (or uncorrelated with) technical efficiency, however few studies have attempted to test these assumptions. In a recent paper, Wilson (2003) investigates a number of independence tests and finds that they have poor size properties and low power in moderate sample sizes. In this study we discuss the implications of these assumptions in three situations: (i) bootstrapping non-parametric efficiency models; (ii) estimating stochastic frontier models and (iii) obtaining aggregate measures of industry efficiency. We propose a semi-parametric Hausmann-type asymptotic test for linear independence (uncorrelation), and use a Monte Carlo experiment to show that it has good size and power properties in finite samples. We also describe how the test can be generalized in order to detect higher order dependencies, such as heteroscedasticity, so that the test can be used to test for (full) independence when the efficiency distribution has a finite number of moments. Finally, an empirical illustration is provided using data on US electric power generation. 相似文献
94.
ABSTRACTUsing transfer matrices up to next-nearest-neighbour interactions, we examine the structural correlations of quasi-one-dimensional systems of hard disks confined by two parallel lines and hard spheres confined in cylinders. Simulations have shown that the non-monotonic and non-smooth growth of the correlation length in these systems accompanies structural crossovers [Fu et al., Soft Matter 13, 3296 (2017)]. Here, we identify the theoretical basis for these behaviours. In particular, we associate kinks in the growth of correlation lengths with eigenvalue crossing and splitting. Understanding the origin of such structural crossovers answers questions raised by earlier studies, and thus bridges the gap between theory and simulations for these reference models. 相似文献
95.
96.
András Krámli 《Journal of statistical physics》1996,83(1-2):167-191
An exposition of some methods of proving exponential (stretched exponential) decay of correlations is given. One-dimensional strictly hyperbolic and quadratic maps and two-dimensional piecewise smooth, uniformly hyperbolic maps are considered. The emphasis is on the fundamental constructions of the Markov sieve method due to Bunimovich-Chernov-Sinai and those of Liverani's Hilbert metric method. 相似文献
97.
李相波 《数学物理学报(A辑)》2005,25(3):428-432
该文根据波动理论,推证了脏腑病变对寸、关、尺压力波的 影响,分析了寸、关、尺部位的脉状与脏腑病变的关系。 相似文献
98.
The oxidation of 34 organic sulphides hy 2,2′-hipyridinium chlorochromate (BPCC) resulted in the formation of the corresponding
sulphoxides. The reaction is first order with respect to both BPCC and the sulphide, and is catalysed by hydrogen ions. The
hydrogen-ion dependence has the form:k
obs = a+b[H+]. The oxidation was studied in 19 different organic solvents. An analysis of the solvent effect by Swain’s equation showed
that the both cation-and anion-solvating powers of the solvents play important roles. The rates of oxidation meta- andp-substituted phenyl methyl sulphides were correlated with Charton’s LDR equation. The rates of theo-compounds showed excellent correlation with the LDRS equation. Oxidation of thep-compounds is more susceptible to the delocalizationeffect. Oxidation of themcompounds exhibited a greater dependence on the field effect. In the oxidation of theo-compounds, the contribution of delocalized effect is slightly more than that of the field effect. The oxidation of alkyl
phenyl sulphides is subject to both polar and steric effects of the alkyl groups. Polar reaction constants are negative, indicating
an electron-deficient sulphur centre in the rate-determining step. A mechanism involving formation of a sulphurane intermediate
in the slow step has been proposed. 相似文献
99.
Correlation spectroscopy as a tool for detecting losses of ligand elements in laser welding of aluminium alloys 总被引:1,自引:0,他引:1
T. Sibillano A. Ancona V. Berardi E. Schingaro P. Parente P.M. Lugar 《Optics and Lasers in Engineering》2006,44(12):1324-1335
The plasma plume induced during laser welding of metals is a mixture of metal vapour, coming from the vaporised weld pool surface and shielding gas. The influence of the shielding gas on the welded joints quality is not yet well understood and very few investigations, to the best of our knowledge, were addressed to study its role in case of welding of aluminium–magnesium alloys. In this paper we present a study of the dynamics of plasma plume produced in laser welding of 5xxx aluminium alloys by means of correlation spectroscopy. By our results we can correlate the influence of the welding speed, in case of ineffective gas shielding, to the loss of alloying elements. Finally, the results obtained are consistent with the EDX analysis performed in post-processing on the welded joints. 相似文献
100.