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151.
建立高效液相色谱-串联质谱(LC-MS/MS)测定动物血浆中罗匹尼罗浓度的方法。血浆经乙酸乙酯萃取后,以HPLC分离,电喷雾离子化(ESI~+)串联质谱检测。以甲醇-乙腈-0.1‰冰醋酸(36:9:55)为流动相,流速为0.2mL·min~(-1),采用Ultimate XB-C 18柱(150mm×2.1mm,3μm)分离,在三级四极杆串联质谱中经电喷雾电离源(ESI)离子化,以多反应监测(MRM)方式进行检测。盐酸罗匹尼罗、盐酸苯海拉明(内标)的扫描离子对m/Z分别为261→114和m/Z 256→167。LC-MS/MS测定血浆中罗匹尼罗线性范围为0.02—400ng·mL~(-1),范围内线性关系良好(r=0.9998);以3个浓度水平的质量控制样品求得各浓度水平日内、日间精密度(RSD)均小于15.2%。在非临床药代动力学研究中,应用此法测定了受试兔子血浆中罗匹尼罗的浓度。该法灵敏、快速、准确,操作简便,样品处理方便,线性范围宽,该方法检测快速、专一、灵敏,可满足罗匹尼罗临床前药代动力学研究和临床药动学研究的要求。 相似文献
152.
Sascha Bachmann Matthias Reitzner 《Stochastic Processes and their Applications》2018,128(10):3327-3352
Concentration bounds for the probabilities and are proved, where is a median or the expectation of a subgraph count associated with a random geometric graph built over a Poisson process. The lower tail bounds have a Gaussian decay and the upper tail inequalities satisfy an optimality condition. A remarkable feature is that the underlying Poisson process can have a.s. infinitely many points.The estimates for subgraph counts follow from tail inequalities for more general local Poisson U-statistics. These bounds are proved using recent general concentration results for Poisson U-statistics and techniques involving the convex distance for Poisson processes. 相似文献
153.
154.
In a letter to Born, Einstein wrote [42]: “Quantum mechanics is certainly imposing. But an inner voice tells me that it is not yet the real thing. The theory says a lot, but does not really bring us any closer to the secret of the ‘old one.’ I, at any rate, am convinced that He does not throw dice.” In this paper we take seriously Einstein’s famous metaphor, and show that we can gain considerable insight into quantum mechanics by doing something as simple as rolling dice. More precisely, we show how to perform measurements on a single die, to create typical quantum interference effects, and how to connect (entangle) two identical dice, to maximally violate Bell’s inequality. 相似文献
155.
Adam T. Smith 《Applied Mathematical Finance》2013,20(2):123-141
The uncertain volatility approach to financial derivatives is extended to American options (which allow early exercise before expiry). The requirement to model at the portfolio level made necessary by the non-linearity of the approach is found to lead to a recursive structure to the exercise possibilities across options. Other novel features include: the optimality sometimes of partial exercise; an interesting resolution to the issues surrounding short options whose exercise is controlled by a buyer counterparty; and the occurrence of a simple game structure for portfolios containing both long and short options. It is demonstrated that the exercise strategies resulting can significantly alter measured uncertain volatility risk. Contrary to the set of attributes for sensible risk measures put forward by Artzner, Delbaen, Eber and Heath, this risk need not be homogenous in portfolio size- forming a convincing argument for weakening this particular requirement. 相似文献
156.
157.
Diana B. Muñiz-Márquez Guillermo C. Martínez-Ávila Jorge E. Wong-Paz Ruth Belmares-Cerda Raúl Rodríguez-Herrera Cristóbal N. Aguilar 《Ultrasonics sonochemistry》2013,20(5):1149-1154
Bay leaves (BL) (Laurus nobilis L., Family: Laureceae) are traditionally used to treat some symptoms of gastrointestinal problems, such as epigastric bloating, impaired digestion, eructing and flatulence. These biological properties are mainly attributed to its phenolic compounds. In this paper, ultrasound-assisted extraction of phenolic compounds from Laurus nobilis L. (Laureceae) was studied.Effects of several experimental factors, such as sonication time, solid/liquid ratio and concentration of solvent on extraction of phenolic compounds were evaluated through a randomized complete block design with factorial treatment arrangement (33). The best extraction conditions were: 1 g plant sample with 12 mL of 35% ethanol, for 40 min, obtaining a yield of phenolic compounds of 17.32 ± 1.52 mg g?1 of plant. In addition, free radical-scavenging potential of DPPH and lipid oxidation inhibition, by linoleic acid peroxidation of the selected extract was measured in order to evidence their antioxidant properties. Results indicated that high amounts of phenolic compounds can be extracted from L. nobilis by ultrasound-assisted extraction technology. 相似文献
158.
The concentration polarization phenomena and its effects represent one of the main challenges for the optimal operation of many nanofluidic systems. A numerical investigation of the different electric current transition regimes observed during the concentration polarization phenomena in nanochannels is performed. This included a 2D‐axisymmetric simulation of the nanofluidic system (reservoir‐nanochannel‐reservoir). From these simulations, a novel mechanism is discovered that explains that different current transition regimes. This driving mechanism involves the applied electric field penetration while the convective flow mechanism is found to be negligible. This differs with the classical statement that the mixing process with less depleted areas initiated by an electrokinetic vortex instability starts the overlimiting regime. Additionally, the numerical approach allows us to identify new characteristics of the linear‐limiting transition such as source‐like and saddle‐like points of the electric field streamlines. The three voltage–current regimes (linear, limiting and overlimiting) are explained by observing and quantifying changes in electric field, potential, ion concentration and ion concentration gradients within the system. 相似文献
159.
160.
Daniel Lehmann 《International Journal of Theoretical Physics》2008,47(5):1333-1353
The concept of a superposition is a revolutionary novelty introduced by Quantum Mechanics. If a system may be in any one of
two pure states x and y, we must consider that it may also be in any one of many superpositions of x and y. An in-depth analysis of superpositions is proposed, in which states are represented by one-dimensional subspaces, not by
unit vectors as in Dirac’s notation. Superpositions must be considered when one cannot distinguish between possible paths,
i.e., histories, leading to the current state of the system. In such a case the resulting state is some compound of the states
that result from each of the possible paths. States can be compounded, i.e., superposed in such a way only if they are not
orthogonal. Since different classical states are orthogonal, the claim implies no non-trivial superpositions can be observed
in classical systems. The parameter that defines such compounds is a proportion defining the mix of the different states entering
the compound. Two quantities, p and θ, both geometrical in nature, relate one-dimensional subspaces in complex Hilbert spaces: the first one is a measure of proximity
relating two rays, the second one is an angle relating three rays. The properties of superpositions with respect to those
two quantities are studied. The algebraic properties of the operation of superposition are very different from those that
govern linear combination of vectors.
This work was partially supported by the Jean and Helene Alfassa fund for research in Artificial Intelligence, by the Israel
Science Foundation grant 183/03 on “Quantum and other cumulative logics” and by EPSRC Visiting Fellowship GR/T 24562 on “Quantum
Logic”. 相似文献