STUDY ON THE CONCENTRATION DEPENDENCE OF ORIENTATION OF POLYSTYRENE ON SILVER BY THE SERS TECHNIQUE*

Polystyrene films were adsorbed onto a silver surface from dichloromethane solutions with concentrations of 0.1 to12 wt%, and then studied by the surface enhanced Raman technique. A critical concentration for coil interpenetration wasobserved.     

算法融合的差分吸收光谱法烟气SO2浓度在线监测研究

过去几十年中差分吸收光谱技术(differential optical absorption spectroscopy,DOAS)在大气污染物监测方面取得了成功应用.文章提出了根据差分吸光度最大值(OD'm)设定阈值的思想,将传统DOAS算法与基于卡尔曼滤波的DOAS算法相结合,利用两种算法在相同信噪比下具有不同反演精度的特点,在保证测量精度的前提下提高了DOAS系统的检测极限,较好地解决了短光程下低浓度气体的测量精度问题.在常温常压和流动状态下,对烟气中的SO2浓度测量进行了理论和实验研究.研究结果表明,改进的DOAS算法在OD'm＜0.048 1时,SO2浓度测量精度较高,测量下限可低于28.6 mg·m-3,零点漂移低于2.9 mg·m-3传统DOAS算法在0.048 1＜OD'm＜0.927 2时,SO2浓度测量精度较高;两种算法对OD'm＞0.927 2时的SO2浓度测量都存在较大的误差,必须进行线性度校正.     

Quantum fluctuations as deviation from classical dynamics of ensemble of trajectories parameterized by unbiased hidden random variable

A quantization method based on replacement of c-number by c-number parameterized by an unbiased hidden random variable is developed. In contrast to canonical quantization, the replacement has a straightforward physical interpretation as a statistical modification of classical dynamics of an ensemble of trajectories, and implies a unique operator ordering. We then apply the method to develop quantum measurement without wave function collapse and external observer a la pilot-wave theory.     

Uncertainty functions, a compact way of summarising or specifying the behaviour of analytical systems

Analytical chemists can advantageously use an uncertainty function to describe the performance of an analytical system in terms of the standard uncertainty or standard deviation as a function of the concentration of the analyte. This “characteristic function” is useful for estimating uncertainty at a new concentration. A similar function can be used to prescribe the uncertainty that is regarded as fit for purpose for a particular application. This “fitness function” is useful in setting standards of accuracy in proficiency tests and similar exercises without revealing the concentration of the analyte. In combination, these two functions provide a rational basis for method selection.     

Uncertainty of measurement and legislative limits

 The uncertainty affecting analytical measurements has to be taken into account when evaluating compliance of suspect matrices to legislative limits. To this aim Type 1 and 2 errors must be considered. This necessarily leads to the evaluation of the minimum detectable inadmissible signal, from which the minimum detectable inadmissible concentration can be obtained. The signal of suspect matrices thus has to be compared with the minimum detectable inadmissible signal. This paper aims to discuss practical problems involved in the comparison.     

辐射量热计在HT-6BTokamak上的测量

一、引言 在现行的托卡马克实验中,辐射损失和中性粒子损失是高温等离子体能量损失的主要通道之一。为了更好地了解托卡马克等离子体中能量平衡、辐射损失以及这些损失随等离子体参数的变化;了解等离子体中杂质含量和杂质输运以及等离子体与器壁的相互作用,辐射能量损失的时间特性、空间分布的测量显得很有必要。为     

Experimentally available kinetic codes as a tool for promising data extraction in thermal analysis

By the study of 3000 kinetic runs for all homogeneous two-step models under variation of activation and signal parameters, it has been stated that the generated Mechanistic Concentration Code (=MCC) is the best vehicle for data extraction in Thermal Analysis. It summarises the rate-controlling steps and their molecularities, independently of their activation data and (to 80–90%) of their method-specific signal parameters. Hence, an optimum evaluation needs the internal (best-fitted) reference step, the initial concentration of a reference reactant, and equal weight of theoretical and experimental results, reached using the same algorithms. Thus, the MCC of any series measured in general allows for a reliable model determination via the distribution into all two-step models, using the tools of probability and decision theory. A transfer of the strategy to heterogeneous reactions is discussed.

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Zusammenfassung Durch die Untersuchung von über 3000 kinetischen Abläufen für alle homogenkinetischen Zweistufen-Modelle wurde festgestellt, da\ der Mechanistische Konzentrations-Code (= MCC) ein optimaler Datenträger in der Thermischen Analyse ist: Er beschreibt die geschwindigkeitsbestimmenden Schritte und ihre Molekularität, unab- hängig von deren Aktivierungsdaten und, zu 80–90%, von ihren methodenspezifischen Signalparametern. Ein optimales Auswerteverfahren benötigt einen internen (optimal angepa\ten) Referenzschritt, die Startkonzentration eines Referenz-Reaktanten und Gleichberechtigung theoretischer und experimenteller Befunde, erreicht, durch Verwendung derselben Algorithmen. Allgemein ermöglicht der MCC aus einer Reihe von Experimenten dann eine Modellbestimmung über eine Verteilung, die durch entscheidungstheoretische Kriterien die Wahrscheinlichkeiten aller Zweistufenmodelle auflistet.Eine übertragung des Verfahrens auf heterogene Prozesse wird diskutiert.

     

双反射镜式光电经纬仪测角误差的分析(轴系部分)

双反射镜式光电经纬仪由于采用了反射镜跟踪头,轴系误差对测角精度的影响不同于典型光电经纬仪。本文从建立经纬仪三维直角坐标系入手,建立了该类型经纬仪轴系误差引起测角误差的数学模型,为精度分析和误差修正提供了依据。     

SJTU-1型医用超声诊断设备声输出测量系统的研制

本系统地研究了医用超声诊断设各声输出公布要求的国家标准GB16846—1997(idt.IEC61157—1992)中规定的主要指标的定义和测量方法，给出了相关的计算公式。介绍了为实施国标而研制的专用测量设备SJTU-1型医用超声设备声输出测量系统的工作原理、系统构成和技术性能。