“海纹石”的矿物学及谱学特征研究

“海纹石”是具有蓝色条带的针钠钙石,是一种稀有的宝石材料,具有较好的市场前景。为查明其矿物学特征及成因,采用常规宝石学测试并结合X射线衍射(XRD)、傅里叶红外吸收光谱(FTIR)、拉曼光谱(Raman)、扫描电镜(SEM)及紫外-可见分光光度计(UV-Vis)等现代测试方法,对“海纹石”不同颜色部分的矿物成分及特征进行了深入分析。XRD,FTIR,Raman分析结果表明,“海纹石”的主要组成矿物为针钠钙石,并含有少量的方解石,与SEM分析结果较为一致。FTIR分析显示,“海纹石”白色部分在1 500 cm-1处出现一个明显的宽吸收带并伴有883和710 cm-1的吸收峰,表明含有少量方解石,而蓝色部分在该处没有此吸收。紫外可见吸收光谱分析显示蓝色部分在可见光区有640 nm宽吸收峰,表明可能含有微量元素Cu。“海纹石”白色和蓝色部分矿物组分的差异,表明两者可能形成于不同的地质环境。     

使用改进的形状优化方法设计高均匀度的超导MRI磁体

针对设计带铁磁的超导磁共振成像磁体,提出了一种确定类的优化算法来优化极靴的形状以达到匀场的目的。这种方法集合了灵敏度分析、形状优化的理论和有限元方法计算非线性铁磁材料极靴的配置,来改善两个极靴之间大体积成像区的磁场均匀度。需要指出的是,本优化方法不受极靴初始形状的限制,均可以快速收敛。我们通过一个紧凑型的1.2T双平面磁共振磁体,展示了这种方法。     

The giant enhancement of Fano-type resonance in a gain-assisted silicon slab array

Giant resonance enhancement is demonstrated to be due to the Fano interference in a grating waveguide composed of gain-assisted silicon slabs. The Fano mode is characterized by its ultra-narrow asymmetric spectrum, different from that of a pure electric or magnetic dipole. The simulation indicates that a sharp Fano-interfered lineshape is responsible for the giant resonance enhancement featuring the small-gain requirements.     

高性能计算机用热管复合制冷系统设计研究

根据高性能计算机全天候温控的需要,提出了综合应用蒸气压缩和动力型分离式热管制冷技术的复合冷源方案。在冬季及春、秋过渡的低温季节,运行热管循环不仅大幅降低环控装置的能耗,而且可以避免在低温环境运行压缩式制冷易发生的冷启动、回油润滑等问题。提出了蒸气压缩制冷、蒸气压缩/热管复合制冷和热管制冷的分区工作模式,引入复合制冷模式有效拓宽了热管运行温区,大幅提高了制冷系统的综合COP。模拟分析了在北京地区应用热管复合制冷技术的节能性能,相比常规的压缩制冷节能率高达40%。研究表明:热管复合制冷系统具有显著的节能减排优势,特别适用于全天候工作的机房、基站等高热密度电子集成系统的温控。     

An experimental study of impact-induced failure events in homogeneous layered materials using dynamic photoelasticity and high-speed photography

The generation and the subsequent evolution of dynamic failure events in homogeneous layered materials that occur within microseconds after impact were investigated experimentally. Tested configurations include three-layer and two-layer, bonded Homalite specimens featuring different bonding strengths. High-speed photography and dynamic photoelasticity were utilized to study the nature, sequence and interaction of failure modes. A series of complex failure modes was observed. In most cases, and at the early stages of the impact event, intra-layer failure (or bulk matrix failure) appeared in the form of cracks radiating from the impact point. These cracks were opening-dominated and their speeds were less than the crack branching speed of the Homalite. Subsequent crack branching in several forms was also observed. Mixed-mode inter-layer cracking (or interfacial debonding) was initiated when the intra-layer cracks approached the interface with a large incident angle. The dynamic interaction between inter-layer crack formation and intra-layer crack growth (or the so-called “Cook–Gordon Mechanism”) was visualized for the first time. Interfacial bonding played a significant role in impact damage spreading. Cracks arrested at weak bonds and the stress wave intensity was reduced dramatically by the use of a thin but ductile adhesive layer.     

探针尖带金属微粒的光子扫描隧道显微镜成像数值模拟

引入了色散介质的时域有限差分法散射场方程,并针对光子扫描隧道显微镜的带金属尖光纤扫描成像问题进行三维的数值模拟。在考虑了光纤和样品相互作用的情况下,采用等效入射波法设置入射波,探针扫描模式为等高扫描模式,从成像分辨力和灵敏度的角度,比较了不同入射角、不同的光纤一样品间距,不同金属类型,及不同金属尖大小的成像情况。数值模拟结果显示,带金属颗粒光纤探针尖的光子扫描隧道显微镜在成像分辨力和灵敏度上有显著的改进,而带不同类型金属颗粒情况下对分辨力影响不大,灵敏度是银最好。     

单轴晶体包层啁啾光纤光栅中电光效应和弹光效应的理论研究

提出了以单轴晶体材料为包层,光轴平行于光栅主轴(z轴)的新型啁啾光纤光栅模型,应用耦合模理论和传输矩阵方法在理论上分析了该类光纤光栅中的电光效应和弹光效应,理论研究发现在包层施加沿光栅轴向的电场和应变场可以改变布拉格波长和反射谱。得到了3种不同单轴晶体为包层时布拉格波长λB和反射光谱随外加电场和应变场变化的曲线。研究结果表明当轴向外加电场从1×107V/m变化到8×107V/m时λB减小0.12nm,当外加应变场从0变化到0.04时,λB减小0.45nm。     

High coercivity nanocrystalline YCo5 powders produced by mechanical milling

High coercivity nanostructured YCo₅ powders were successfully prepared by mechanical milling of as-cast alloys and subsequent vacuum annealing. Almost single phase YCo₅ alloys, obtained by arc melting, were processed by high energy mechanical milling using a SPEX 8000 mill. After 4 h of milling, powders become nearly amorphous. DSC scans revealed the existence of an irreversible broad exothermic transition with a maximum at 516 °C associated with the crystallization process. Annealing in high vacuum at 800 °C during 2.5 min led to the formation of YCo₅ nanoparticles with an average particle size of 12 nm. A high intrinsic coercivity of 7.23 kOe together with a σ_r/σ_s ratio of 0.75 were obtained.     

Growth of monodisperse nanospheres of MnFe_2O_4 with enhanced magnetic and optical properties

Highly dispersive nanospheres of MnFe204 are prepared by template free hydrothermal method. The nanospheres have 47.3-nm average diameter, narrow size distribution, and good crystallinity with average crystallite size about 22 nm. The reaction temperature strongly affects the morphology, and high temperature is found to be responsible for growth of uniform nanospheres. Raman spectroscopy reveals high purity of prepared nanospheres. High saturation magnetization （78.3 emu/g）, low coercivity （45 Oe, 10e = 79.5775 A.cm-1）, low remanence （5.32 emu/g）, and high anisotropy constant 2.84 × 10^4 J/m3 （10 times larger than bulk） are observed at room temperatures. The nearly snperparamagnetic behavior is ~ spin due to comparable size of nanospheres with superparamagnetic critical thameter Dcr spm The high value of Keff may be due to coupling between the pinned moment in the amorphous shell and the magnetic moment in the core of the nanospheres. The nanospheres show prominent optical absorption in the visible region, and the indirect band gap is estimated to be 0.98 eV from the transmission spectrum. The prepared Mn ferrite has potential applications in biomedicine and photocatalysis.     

A meshless model for transient heat conduction analyses of 3D axisymmetric functionally graded solids

A meshless numerical model is developed for analyzing transient heat conductions in three-dimensional （3D） axisymmetric continuously nonhomogeneous functionally graded materials （FGMs）. Axial symmetry of geometry and boundary conditions reduces the original 3D initial-boundary value problem into a two-dimensional （2D） problem. Local weak forms are derived for small polygonal sub-domains which surround nodal points distributed over the cross section. In order to simplify the treatment of the essential boundary conditions, spatial variations of the temperature and heat flux at discrete time instants are interpolated by the natural neighbor interpolation. Moreover, the using of three-node triangular finite element method （FEM） shape functions as test functions reduces the orders of integrands involved in domain integrals. The semi-discrete heat conduction equation is solved numerically with the traditional two-point difference technique in the time domain. Two numerical examples are investigated and excellent results are obtained, demonstrating the potential application of the proposed approach.