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101.
Shigeo Minami 《Mikrochimica acta》1987,93(1-6):309-324
Multichannel Fourier transform spectrometers utilizing image sensing devices are reviewed along with the instrumental design concepts. Although the idea itself is fairly simple, a photographic plate in holographic spectroscopy is replaced by an image sensor, there are stringent requirements to be satisfied in order to realize the system for field use. Mainly two types of the instrument, which are characterized by the Sagnac common-path interferometer and the polarization interferometer optics, respectively, are described with regard to their system performances. Examples of the system operation introduced show that Fourier transform spectrometers without mechanical moving parts play an important role in a variety of spectroscopic applications under severe surroundings. In a summary, methods for the resolution enhancement and comments on the signal-to-noise ratio are also included. 相似文献
102.
Until now the study of organic compounds in which the π-electron system is excited by absorbed light has been mainly concentrated on the ultraviolet and visible regions of the electromagnetic spectrum. Various new applications, such as the use of conjugated organic compounds as dye lasers or as materitals for storing information with the help of diode lasers, led to the synthesis of new compounds which absorb light in the near in infrared (NIR). It is possible to use structure-color relationships to predict the properties of such new compounds when they belong to dyestuff classes which have already been studied in detail; in this case the approach involves decreasing the energy difference between the ground state and the first excited state. A less conventional starting point is provided by molecular structures in which from the outset there is only a very small energy difference between the lowest-energy electronic states; such diradicaloid molecules occupy a special position among the various types of organic compounds. It is possible by means of suitable structural modification to stabilize such molecules in a singlet from which absorbs light at very long wavelengths (i.e. at small wave numbers). 相似文献
103.
The molecular structure and absorption spectra of monothio- and dithio-naphthalimides were compared to their naphthalimide analogues using AM1, PM3 and ZINDO/S semiempirical quantum chemical methods. The substitution of the 4R-naphthalimide oxygen atoms by sulphur atoms resulted in a red-shift of the absorption spectra by Δλmax60-65 and 100-140 nm, respectively. The thionated naphthalimide derivatives do not show observable fluorescence due to intersystem crossing to the triplet -states localised at the CS groups. The -absorption bands of monothioimides are located at 525-580 nm (ε=60-80) and those for dithioimides at 535-560 nm (ε=140-390) and 628-686 nm (ε=34-68). None of these transitions are solvent sensitive. The -transitions of N-phenylthioimides have also a small contribution from -states due to a partial conjugation between CS group and π-electronic system of the N-phenyl ring. As a result, the bands of aromatic substituted N-phenylthioimides are red-shifted as compared to those of the aliphatic N-methyl-thioimides. 相似文献
104.
研究了客体模型FTO的闪光照相系统X光输运过程,给出了直穿照射量、散射照射量、直散比、直穿照射量能谱、散射照射量能谱、直穿X光通量能谱和散射X光通量能谱在记录平面的空间分布。结果表明:后锥是照射量散射成分的主要来源,后锥照射量占总散射量97%;后锥也是造成散射的空间分布不均匀的主要器件,这一不均匀性高达58%。照相系统的最小直散比非常小,表明锥造成的散射已经严重地淹没了直穿(轫致辐射)信号。计算中使用高空间分辨率记录法进行分点,合成图像对吸收系数的复原结果与国外报道的结果相符。 相似文献
105.
Investigations have been performed on convective heat transfer in water flowing through mini-channels using the non intrusive technique of laser interferometry coupled with digital image processing. Optical glass channels, fabricated with metallic heating surfaces, were studied using a Mach-Zehnder interferometer configuration. Fringe patterns captured using a high-sensitivity CCD camera were analyzed digitally based on a calculation method developed for the liquid medium. Results of parametric studies were compared and contrasted with relevant theoretical solutions from the literature. Indication of the onset of turbulence at Reynolds numbers smaller than the conventional transition Reynolds number for large channels has also been noticed in the experimental investigation. 相似文献
106.
航空遥感监测中变焦镜头的广泛应用以及飞行高度的变化会获得不同地面分辨率的航空影像,因此为了实时监控到飞行区域的整体情况,需要对不同地面分辨率的图像进行拼接。提出了针对不同地面分辨率图像进行拼接的方法。首先用四分法对图像进行分割,检测变化倍率,选择配准策略;然后用基于加速鲁棒性特征(Speeded-Up Robust Features,SURF)的算法对相邻图像进行拼接。获得了焦距变化从高倍过渡到低倍,或从低倍过渡到高倍的拼接图像。通过航空变焦模拟影像的拼接实验和地面变焦影像的拼接实验表明,该方法能够对不同地面分辨率的图像进行拼接,且拼接结果均以高分辨率为基准。 相似文献
107.
Comment on “On the Neumann function and the method of images in spherical and ellipsoidal geometry”
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In this note, we point out two errors in the article “On the Neumann function and the method of images in spherical and ellipsoidal geometry” by Dassios and Sten. Two corrections are then proposed. 相似文献
108.
R. M. Montereali 《辐射效应与固体损伤》2013,168(6-12):545-551
Research activities concerned with color centers in alkali halide films started recently. The use of versatile, well-assessed, and low-cost fabrication techniques consisting of physical vapor deposition of Lithium Fluoride (LiF) films combined with direct writing lithographic processes allows the realization of miniaturized structures, like broad-band emitters, channel waveguides, optical microcavities and point-light sources emitting in the visible spectral range. Promising results have been obtained in the generation, amplification and waveguiding of visible light in LiF treated by low energy electron beams, where the efficient formation of stable primary and aggregate color centers also induces a local modification of the refractive index. A brief overview of the investigated optical properties is presented together with a short discussion about their perspectives of applications in optoelectronics. 相似文献
109.
The necessity of odor sensing has been increasing from environmental and health standpoints. Here, we propose the novel concept of a small device which can select odor molecules based on electrostatic spraying. For high selectivity of the target gas or odor, we conducted computational fluid dynamics coupled with an electrostatic field, as well as measurements by particle image velocimetry and anemometry. The computational model successfully reproduced characteristic features of ionic wind. Different trajectories of charged particles were computationally obtained owing to their electrical mobility. The results imply that different materials might be separated by the arrangement of the collecting electrode. 相似文献
110.