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181.
四苯硼钠-甲苯胺蓝缔合物纳米微粒体系减色效应研究 总被引:2,自引:2,他引:2
在PH4.0醋酸-醋酸钠介质中,甲苯胺蓝在600nm处有一个吸收峰,随着四苯硼钠浓度的增大甲苯胺蓝在600nm处吸收峰降低,颜色减弱,这是由于甲苯胺蓝-四苯硼钠缔合物分子间存在较强的疏水作用及分子间作用力,聚集形成纳米微粒所致,甲苯胺蓝-四苯硼钠纳米微粒体系亦在600mm处有1个吸收峰,在400mm、470mm和580mm处产生3共振散射峰,其中400mm和580mm为甲苯胺蓝-四苯硼钠复合纳米微粒产生的特征共振散射峰,这也表明有纳米微粒存在,丙酮浓度的影响实验结果等表明,纳米微粒的形成是产生其减色效应的原因。 相似文献
182.
Bérangère C Caussarieu N Morin P Morin-Allory L Lafosse M 《Journal of separation science》2004,27(12):964-970
An original system which uses Porous Graphitic Carbon as support and a mixture of organic solvents as mobile phase is proposed for the analysis of triterpenic acids by liquid chromatography. The separation of betulinic acid, ursolic acid, oleanolic acid, and 18alpha- and 18beta-glycyrrhetinic acids was carried out within a short time and monitored by evaporative light scattering detection as universal detection method. Molecular modelling studies show that the main contribution to the selectivity comes from the electrostatic interaction characterised by the dipole moment of the products. 相似文献
183.
Decroos K Vincken JP Heng L Bakker R Gruppen H Verstraete W 《Journal of chromatography. A》2005,1072(2):185-193
A novel method utilizing high-performance liquid chromatography (HPLC) with evaporative light scattering detection (ELSD) and electrospray ionisation mass spectrometry (ESI-MS) was developed for the analysis of soyasaponins, a divers group of triterpenic compounds with one or two sugar side chains, occurring in soy. Group A soyasaponins in different degrees of acetylation, as well as group B soyasaponins in both their 2,3-dihydro-2,5-dihydroxy-6-methyl-4H-pyran-4-one (DDMP)-conjugated and non-conjugated forms could be separated and quantified using authentic soyasaponin standards, in one single run. The method was tested by the determination of the soyasaponin content and composition of eight soygerm samples of different origin. Differences in the composition and the degree of acetylation of the group A soyasaponins were observed among these samples. The group B soyasaponins showed much less variability and they were mainly present in their DDMP-conjugated form. 相似文献
184.
In weakly acidic buffer medium, the interaction of amikacin with calf thymus DNA, yeast RNA and denatured DNA has been investigated by using resonance Rayleigh scattering (RRS) technique. The result shows that calf thymus DNA is capable of enhancing the RRS intensity of the amikacin, while yeast RNA and denatured DNA have very little enhancement effect. Based on the characteristics, a sensitive assay for detecting double-stranded DNA in the presence of denatured DNA and yeast RNA has been developed. The enhancement of the RRS signal is directly proportional to the concentration of double-stranded DNA in the range 0.02-12.0 μg ml−1 for calf thymus DNA and its detection limit (3σ) is 2.5 ng ml−1. The method shows a wide linear range and high sensitivity, and almost no interference can be observed from RNA, denatured DNA, amino acid and most of the metal ions. The trace amounts of nucleic acid in synthetic samples and practical samples are determined with satisfactory results. Therefore, the proposed method is promising for as an effect means for recognition in vivo and determination in situ of double-stranded DNA. 相似文献
185.
186.
Atactic polystyrene, both side group and main chain deuterated, was investigated by inelastic neutron scattering in a wide temperature range around the glass transition from 2 to 450 K. In the glass the Boson peak position is only very weakly influenced by the deuteration of the phenyl group. In the neighborhood of the glass transition temperatureT
g we find a fast relaxation process similar to other glasses. The onset of the fast relaxation in polystyrene, however, is observed already at temperaturesT
g — 200 K. Results from partially deuterated polystyrene suggest a change of the phenyl ring dynamics already far belowT
g. 相似文献
187.
The effect of a roughening procedure on surface-enhanced Raman scattering (SERS) intensity of pyridine at copper and gold electrodes subjected to negative potential has been investigated. Among four procedures tested for a copper electrode the one consisting of electrochemical activation in a solution of LiCl and CuCl2 resulted in the most stable and effective surface. It was proved that the presence of pyridine during the pretreatment procedure caused a very fast, irreversible decay of SERS intensity for both copper and gold electrodes. Quite stable, at least at room temperatures, gold surfaces were obtained by oxidation-reduction cycles activation in KCl solution. 相似文献
188.
Chemical reactions occurring at the mineral–water interface are controlled by an interfacial layer, nanometers thick, whose properties may deviate from those of the respective bulk mineral and water phases. The molecular-scale structure of this interfacial layer, however, is poorly constrained, and correlations between macroscopic phenomena and molecular-scale processes remain speculative. The application of high-resolution X-ray scattering techniques has begun to provide substantial new insights into the molecular-scale structure of the mineral–water interface. In this review, we describe the characteristics of synchrotron-based X-ray scattering techniques that make them uniquely powerful probes of mineral–water interfacial structures and discuss the new insights that have been derived from their application. In particular, we focus on efforts to understand the structure and distribution of interfacial water as well as their dependence on substrate properties for major mineral classes including oxides, carbonates, sulfates, phosphates, silicates, halides and chromates. We compare these X-ray scattering results with those from other structural and spectroscopic techniques and integrate these to provide a conceptual framework upon which to base an understanding of the systematic variation of mineral–water interfacial structures. 相似文献
189.
Coherent anti-Stokes Raman scattering (CARS) microscopy is presented as a new nonlinear optical technique. The combination of vibrational spectroscopy and microscopy allows highly sensitive investigations of unlabelled samples. CARS is an ideal tool for studying a broad variety of samples. The main drawback of the technique is its non-zero-background nature, which implies that the signal has to be detected against a nonresonant background. The need to solve this problem is reflected in the rapid technological developments that have been observed during the last decade. Recent results show that CARS microscopy has the potential to become an important complementary technique that can be used with other well-established microscopic methods. Although it has some limitations, it offers unique access to many problems that cannot be tackled with conventional techniques. For this reason, it can be expected that the impressive growth of the field will continue. 相似文献
190.
Dynamic light scattering experiments have been performed at various concentrations, of pharmaceutical oil-in-water microemulsions
consisting of Eutanol G as oil, a blend of a high (Tagat O2) and a low (Poloxamer 331) hydrophilic–lipophilic balance surfactant,
and a hydrophilic phase (propylene glycol/water). We probe the dynamics of these microemulsions by dynamic light scattering.
In the measured concentration range, two modes of relaxation were observed. The faster decaying mode is ascribed classically
to the collective diffusion D
c (total droplet number density fluctuation). We show that the slow mode is also diffusive and suggest that its possible origin
is the relaxation of polydispersity fluctuations. The diffusion coefficient associated with this mode is then the self-diffusion
D
s of the droplets. It was found that D
c and D
s had opposite volume fractions of oil plus surfactants (ϕ) dependence and a common limiting value D
0 for ϕ=0. Average hydrodynamic radius (R
h=10.5 nm) of droplets was calculated from D
0. R
h is supposed to compose the inner core, a surfactant film including possible solvent molecules, which migrate with the droplet.
The concentration dependence of diffusion coefficients reflects the effect of hard sphere and the supplementary repulsive
interactions which arises due to loss of entropy, when absorbed chains of surfactant intermingle on the close approach of
the two droplets. This mechanism could also explain the observed stability of our systems. The estimated extent of polydispersity
is 0.22 from the amplitude of slower decaying mode. The polydispersity in microemulsion systems is dynamic in origin. Results
indicate that the time scale for local polydispersity fluctuations is at least three orders of magnitude longer than the estimated
time between droplet collisions. 相似文献