Detection and analysis of new bands of O3 by CRDS between 6500 and 7300 cm

The absorption spectrum of the ¹⁶O₃ isotopologue of ozone has been recorded in the 7000-7920 cm⁻¹ region by high sensitivity CW-Cavity Ring Down Spectroscopy. This report is devoted to the analyses of the 7065-7300 cm⁻¹ region dominated by the ν₁ + 2ν₂ + 5ν₃ and ν₁ + 5ν₂ + 3ν₃ A-type bands at 7130.8 and 7286.8 cm⁻¹ respectively. 289 transitions were assigned to the ν₁ + 2ν₂ + 5ν₃ band. The corresponding line positions were modeled with an effective Hamiltonian involving Coriolis resonance interactions between the (1 2 5) upper state and the (4 4 0), (0 2 6) and (6 1 0) dark states, and an anharmonic resonance interaction with the (2 0 5) state. The very strong interaction (up to 50% mixing of the wavefunctions) between the (1 2 5) and (6 1 0) states leads to the observation of two extra lines of the 6ν₁ + ν₂ band due to a resonance intensity transfer. 213 transitions of the ν₁ + 5ν₂ + 3ν₃ band were assigned and modeled taking into account a Coriolis resonance interaction with the (3 6 0) state.We take the opportunity of the present work to report the analysis of the very weak 4ν₂ + 4ν₃ B-type band at 6506.1 cm⁻¹ which was assigned from previously recorded CRDS spectra. 286 transitions were modeled using the effective Hamiltonian approach.The dipole transition moment parameters of the three analyzed bands were determined by a least-squares fit to the measured line intensities. For the three studied band systems, the effective Hamiltonian and transition moment operator parameters were used to generate line lists provided as Supplementary Materials.     

High sensitivity cavity ring down spectroscopy of CO2 overtone bands near 790 nm

The dyad bands of near 790 nm have been recorded with a continuous-wave cavity ring-down spectrometer. Two cold bands and the two associated hot bands are observed in this region. High sensitivity of the 1×10⁻¹⁰/cm level allows one to detect weak transitions with satisfied accuracy. The absolute line intensities have also been retrieved with an estimated accuracy of 2% for majority of the unblended lines. The vibrational transition dipole moment squared values and the empirical Herman-Wallis coefficients are presented for two cold bands. The comparison of the retrieved line positions and intensities with those given in the Carbon Dioxide Spectroscopic Databank shows clear deviation and indicates the empirical calculation can be further improved using the present spectroscopy data.     

Cavity linewidth narrowing by voltage-controlled induced transparency in asymmetry quantum dot molecules

We theoretically investigate cavity-linewidth narrowing by means of voltage-controlled induced transparency in asymmetric double quantum dot system. The impact of voltage on frequency pulling and cavity linewidth narrowing is discussed. The linewidth and position of the cavity transmission can be engineered by the bias voltage. The scheme may be useful in designing novel optoelectronic devices.     

Generation of atomic entangled states in a bi-mode cavity via adiabatic passage

We propose schemes to prepare atomic entangled states in a bi-mode cavity via stimulated Raman adiabatic passage (STIRAP) and fractional stimulated Raman adiabatic passage (f-STIRAP) techniques. Our scheme should be realizable in the near future because of the existence of all experimental ingredients. Our numerical simulation shows we can entangle the atoms with high fidelities by choosing proper laser pulses.     

Study of the excitation properties of the Si3O2 cluster under an external electric field

The structure of the Si₃O_x (x=2, 3) cluster is investigated; we find that the geometry of Si₃O₂ is similar to that of Si₃O₃ except for the oxygen-deficient defect structure (Si-Si band) which exists only in the Si₃O₂ cluster. It is known that oxygen-deficient defects are used to explain visible luminescence (especially blue, purple and ultraviolet light) from silicon-based materials, which are directly bound up with the excited states of the molecules. Therefore the excitation properties of the two clusters are also studied. Our results show that the absorption spectrum of Si₃O₂ is concentrated in the visible light region. In contrast, the absorption spectrum of Si₃O₃ is mainly located in the ultraviolet light region. The calculations are perfectly consistent with experimental data and also support the theory of oxygen-deficient defects.     

Searching for robust quantum memories in many coupled oscillators

The relation between microscopic symmetries in the system-environment interaction and the emergence of robust states is studied for many linearly coupled harmonic oscillators. Different types of symmetry, which are introduced into the model as terms in the coupling constants between each system?s oscillator and a common reservoir, lead to distinct robust modes. Since these modes are partially or completely immune to the symmetric part of the environmental noise, they are good candidates for building quantum memories. A comparison of the model investigated here, with bilinear system-reservoir coupling, and a model where such coupling presents an exponential dependence on the variables of interest is performed.     

Measurements of NH3 in the ν2 = 1 state by a solid-state, photomixing, THz spectrometer, and a simultaneous analysis of the microwave, terahertz, and infrared transitions between the ground and ν2 inversion-rotation levels

In this paper, we report 30 THz measurements of ammonia in its excited, ν₂ = 1, inversion state. These measurements include transition frequencies and pressure shifts (where significant enough to be observed). Included in the data are two forbidden and three ro-inversion transitions, as well as 18 transitions never directly measured before. The measurements were made with an all-solid-state, diode-laser, difference-frequency spectrometer. Using an innovative laser-frequency locking scheme, this spectrometer provided accurately determined and continuously tuned THz-frequencies without requiring accurate knowledge of the absolute laser frequencies. The details of the spectrometer’s frequency calibration is discussed. A global analysis of NH₃ based on the available ground state, ν₂ = 1 state, and ν₂-band transitions was carried out, and the resulting set of recommended molecular effective-Hamiltonian parameters for ammonia is presented. In addition, calculated center frequencies and intensities for all possible transitions up to J = 20 between rotation, inversion, and vibration levels in the ground and ν₂ = 1 states are included as supplementary material.     

Charge transport properties in microcrystalline KDyFe(CN)6

Microcrystalline solid dysprosium(III) hexacyanoferrate(II) was synthesized by co-precipitation in aqueous solution. The resulting solid has been studied by Fourier transform infrared spectroscopy, X-ray analysis and solid state electrochemistry. The use of a cavity microelectrode was necessary to explore a wide range of time scale and minimize the (undesired) capacitive currents. Cyclic voltametric experiments were very helpful to understand the kinetic of charge transfer in such microstructure. A structure-properties relationship has been established from the crystallographic and the electrochemical properties. A square-scheme is presented to explain the unique electrochemical behavior of hexacyanoferrate containing dysprosium since this compound exhibits a second redox system. The solid presents an open channel-like morphology in which the motion of charged species occurs during the redox processes. Precisely, the electronic transfer is accompanied by a cation diffusion inside the microcrystalline structure. The size of these channels strongly suggests that the kinetic of charge transfer is limited by the cation transport into these structures.     

Near-field optics and control of photonic crystals

We discuss recent progress and the exciting potential of scanning probe microscopy methods for the characterization and control of photonic crystals. We demonstrate that scanning near-field optical microscopy can be used to characterize the performance of photonic crystal device components on the sub-wavelength scale. In addition, we propose scanning probe techniques for realizing local, low-loss tuning of photonic crystal resonances, based on the frequency shifts that high-index nanoscopic probes can induce. Finally, we discuss prospects for on-demand spontaneous emission control. We demonstrate theoretically that photonic crystal membranes induce large variations in spontaneous emission rate over length scales of 50 nm that can be probed by single light sources, or nanoscopic ensembles of light sources attached to the end of a scanning probe.     

A DQ based approach to simulate the vibrations of buckled beams

In this paper, the nonlinear planar response of a hinged–hinged buckled beam to a primary-resonance excitation of its first vibration mode is computed by a new numerical scheme. The beam is subjected to an axial force beyond the critical load of the first buckling mode and to a transverse harmonic excitation. The nonlinear dynamical problem is solved by deducing directly the discretized equations governing the problem thanks to a new approach, here called DQ based approach, since it is based on the application of the quadrature rules of the DQM. As it will be shown, for the problem here considered, the minimum number of degrees of freedom to be retained to limit the numerical errors is four. Computer simulations of the dynamic behaviour of the discretized system are conducted by means of the IDQ method, a method proposed and recently generalized by the author. A sequence of supercritical period-doubling bifurcations leading to chaos, snapthrough motions and quasi-periodic motions can be observed, similarly to some cases existing in literature.