1.3μm分布反馈二极管激光器组件

开发了一种用于光纤公用天线电视（ＣＡＴＶ）的分布反馈激光二极管组成，组件包括１．３μｍＩｎＧａＡｓ／ＩｎＰ双沟－平面掩埋双异质结（ＤＣ－ＰＢＨ）分布反馈激光二极管和光隔离器，封装在蝴蝶型管壳内，组件的出纤线性功率为２．５ｍＷ，并具有极低的失真。     

Characterization and chemical behavior of submonolayer coverages of titania on a Pt foil

The interaction between submonolayer titania coverages and Pt foil has been studied by Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), temperature programmed desorption (TPD) and high-resolution electron energy loss spectroscopy (HREELS). The submonolayer titania can be fully oxidized to TiO₂ at 923 K under 10⁻⁸ Torr O₂, and partially oxidized to TiO_x at lower oxidation temperatures. The oxidized surface can be reduced by annealing to 1000 K or higher, or by heating in H₂ at 823 K, or by interacting with surface carbon formed from acetone decomposition. Under certain conditions (e.g., hydrogen reduction at 923 K), the surface titania can be fully reduced to metallic Ti which diffuses into bulk Pt readily. The reduced metallic Ti can resurface when the surface is oxidized at 923 K. Both XPS and HREELS data indicate the existence of subsurface oxygen, which plays an important role for the diffusion of Ti into and out of the Pt foil. Although no special interfacial active sites were revealed by HREELS studies of adsorbed acetone and CO, some TPD and XPS data suggest the presence of sites active for acetone decomposition.     

STM and chemistry: a qualitative molecular orbital understanding of the image of CO on a Pt surface

Theoretical calculations of STM images for isolated carbon monoxide on Pt(111) have been performed. These simulations are directly comparable to experimental data from Eigler's group. They also confirm a strong site dependence of the STM molecular contrast and assign the two experimental STM forms of CO with two distinct binding sites (the top and the bridge sites) which have already been well-characterised by other surface techniques. Moreover, the approach used here allows a detailed understanding of the electronic origin of the STM molecular pattern. Hence, we demonstrate that the CO STM pattern results from the superposition, with interference effects, of two current contributions. The direct through space tunneling process between the tip and the metal surface is decreased by the presence of the adsorbate molecule, but this depression in the current is more or less compensated, depending on the binding site, by the tunnel current mediated by the molecular levels of the adsorbate. The frontier π orbitals of CO have a small contribution to the current and the σ framework has the major influence with the 5σ lone pair (HOMO of CO) and also the low-lying 3σ. These two MO contributions, however, show a destructive interference effect, and this, together with the absence of π current, is responsible for the weak amplitude of the CO STM image.     

应用于LED灯具散热的平板热管传热特性

平板热管作为一种新型的热管技术,具有高热导率,良好的均温性等优点,成为解决大功率LED散热问题很有前途的技术之一。本文通过实验与数值模拟相结合的方法,研究了平板热管散热模组的传热性能,探讨了热源布置方式(集中式布置与分散式布置)的影响,为LED芯片的布置提供理论指导。结果表明:该平板热管散热模组的散热效果良好,能有效解决LED灯的散热问题。     

Preparation, magnetic and electromagnetic properties of polyaniline/strontium ferrite/multiwalled carbon nanotubes composite

Strontium ferrite particles were firstly prepared by sol-gel method and self-propagating synthesis, and then the polyaniline/strontium ferrite/multiwalled carbon nanotubes composites were synthesized through in situ polymerization approach. Structure, morphology and properties of the composite were characterized by various instruments. XRD analysis shows that the output of PANI increases with the increase of the content of MWCNTs, due to the large surface area of MWCNTs. Because of the coating of PANI, the outer diameter of MWCNTs increases from 10 nm to 20-40 nm. The electrical conductivity of the composites increases with the amount increase of MWCNTs and reaches 7.2196 S/cm in the presence of 2 g MWCNTs. The coercive force of the composites prepared with 2 g MWCNTs is 7457.17 Oe, which is much bigger than that of SrFe₁₂O₁₉ particles 6145.6 Oe, however, both the saturation magnetization and the remanent magnetization of the composite become much smaller than those of SrFe₁₂O₁₉ particles. The electromagnetic properties of the composite are excellent in the frequency range of 2-18 GHz, which mainly depend on the dielectric loss in the range of 2-9 GHz, and mainly on the magnetic loss in the range of 9-18 GHz.     

Reaction mechanism for CO oxidation on Cu(3 1 1): A density functional theory study

The microscopic reaction mechanism for CO oxidation on Cu(3 1 1) surface has been investigated by means of comprehensive density functional theory (DFT) calculations. The elementary steps studied include O₂ adsorption and dissociation, dissociated O atom adsorption and diffusion, as well as CO adsorption and oxidation on the metal. Our results reveal that O₂ is considerably reactive on the Cu(3 1 1) surface and will spontaneously dissociate at several adsorption states, which process are highly dependent on the orientation and site of the adsorbed oxygen molecule. The dissociated O atom may likely diffuse via inner terrace sites or from a terrace site to a step site due to the low barriers. Furthermore, we find that the energetically most favorable site for CO molecule on Cu(3 1 1) is the step edge site. According to our calculations, the reaction barrier of CO + O → CO₂ is about 0.3 eV lower in energy than that of CO + O₂ → CO₂ + O, suggesting the former mechanism play a main role in CO oxidation on the Cu(3 1 1) surface.     

基于碳纤维复合材料的月基极紫外相机照准架结构设计

为了减少月基极紫外相机的质量并保证相机的二维转动机构在卫星发射、地月变轨及月表着陆过程中受到大量级振动冲击以及月表超大温差环境下能正常工作,设计并研制了基于碳纤维复合材料（CFRP）的照准架结构。首先,设计了基于金属材料和CFRP的不同照准架结构,通过有限元法对不同材料的照准架进行分析对比,证明了CFRP照准架的优越性。温度和力学验证试验表明：基于CFRP的照准架质量小于其它材料的照准架,其刚度和热稳定性能满足极紫外相机环境适应性的要求。     

碳原子线的电子传输特性

单分子电子器件的电子传输特性是当前分子电子学领域研究的热点.本文采用第一原理的ab inito法与格林函数方法,对Au电极-碳原子线-Au电极体系的电子结构以及电子传输等特性进行了分析,给出了C5、C10与C15原子线的电导 -电压曲线与伏安曲线.研究结果表明:碳原子线与Au电极之间的"接触"(结合)既有共价键的成分,又有离子键的成分;碳原子线的电导率及伏安特性具有特殊的量子效应和尺寸效应.