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Kinga Zr Roberto Ortiz Ebru Saatci Ronald Bardsley Tim Parr Elisabeth Csregi Mihaela Nistor 《Bioelectrochemistry (Amsterdam, Netherlands)》2009,76(1-2):93
An immunological capacitive biosensor for calpastatin was developed, optimized and applied for the analysis of meat extract samples. Anti-calpastatin antibody was immobilized on a gold electrode modified with a self-assembled monolayer of mercaptoundecanoic acid and Protein A from Staphylococcus aureus, and the obtained immunosensor was inserted as the working electrode in an electrochemical cell of a flow injection system. The dynamic range of the sensor was 20 to 160 ng/mL calpastatin. The electrode could be regenerated and re-used for more than 7 days with minimal reduction in sensitivity. For the analysis of real samples, the target analyte was extracted from the Longissimus dorsi muscle from beef carcasses directly after slaughtering. The extract was analyzed both with the developed immunosensor and microtiter plate ELISA, and a good correlation was obtained. However the immunosensor offers advantages of speed, simplicity, sensitivity and possibility for miniaturization over conventional assays for calpastatin quantification. 相似文献
34.
A novel capacitive sensor based on electropolymerized molecularly imprinted polymer (MIP) for thiopental detection is described. The molecularly imprinted film as a recognition element was prepared by electropolymerization of phenol on a gold electrode in the presence of thiopental (template). Cyclic voltammetry and capacitive measurements were used for characterization and evaluation of the polymeric film. The template molecules were removed from the modified electrode surface by washing with an ethanol:water solution. The sensor’s linear response range was between 3 and 20 µM, with a detection limit of 0.6 µM. The proposed sensor exhibited good selectivity, reproducibility. Satisfactory results were obtained in the direct detection of real samples. 相似文献
35.
Kosin Teeparuksapun Proespichaya Kanatharana Warakorn Limbut Chongdee Thammakhet Punnee Asawatreratanakul Bo Mattiasson Booncharoen Wongkittisuksa Chusak Limsakul Panote Thavarungkul 《Electroanalysis》2009,21(9):1066-1074
Disposable electrodes were fabricated by coating chromium (5 nm) and gold (200 nm) on glass strips (5.0 mm×25.4 mm) and used in a label‐free immunosensor. Human serum albumin (HSA) and its antigen (anti‐HSA) were used as a model system. Electropolymerization of o‐phenylenediamine was used for the immobilization of anti‐HSA by covalent binding. A linear relationship was obtained in the range from 1.0×10?14 to 1.0×10?9 M with a limit of detection of 8.0×10?15 M. Each modified electrode can be reused up to 30 times. The developed system was applied for human serum samples and compared to Albumin BCG method. 相似文献
36.
Simple contactless cells with planar or tubular electrodes have been designed for measurement of the permittivity of solutions. The cells, connected to an integrated circuit of astable multivibrator, respond primarily to the capacitance component of the cell impedance, the multivibrator frequency depends in a defined manner on the solution permittivity and is readily used as the analytical signal in determinations of the ratios of components in binary liquid mixtures; water solution of methanol, ethanol and dioxane have been tested. The response of the cell with planar electrodes satisfies well the simple theoretical model and both the cells provide results with a sufficient sensitivity, a low LOD value (units of %vol) and a good precision (around 1%rel). The cell simplicity, small dimensions, long‐term stability and the possibility of powering them from a battery make them suitable for hand‐held meters. As an example of application in practice, the content of ethanol was determined in the car fuel petrol. 相似文献
37.
The application of novel electrosynthesized polydopamine (PDA)-imprinted film as a recognition element for the capacitive sensing of nicotine is reported. The PDA-imprinted film was electropolymerized directly on the gold electrode surface in the presence of nicotine without an additional self-assembled thiol sublayer. The compact PDA film has various functional groups that aid the imprinting procedure. Furthermore, the film shows good capacitive response since it is insulating in nature and ultrathin. The sensor’s linear response range for nicotine was between 1–25 μmol L−1, with a detection limit of 0.5 μmol L−1. The proposed molecularly imprinted polymer capacitive (MIPC) sensor exhibited good selectivity for nicotine. The reproducibility and repeatability of the MIPC senor were all found to be satisfactory. The results from sample analysis confirmed the applicability of the MIPC sensor to quantitative analysis. 相似文献
38.
Teddy Fen-Chong Antonin Fabbri Jean-Pierre Guilbaud Olivier Coussy 《Comptes Rendus Mecanique》2004,332(8):639-645
A capacitive sensor-based apparatus has been settled to determine the liquid water amount and dielectric constant in consolidated porous media. This technique relies on the dielectric properties of water, air, and mineral substrate. The experimental procedure is described for successively oven-dried samples at 323 K. It allows us to determine the sample dielectric constant as a function of the sample water amount. For limestones from Caen region, an affine relationship is found at 293 K. This is then compared with other empirical soils data and with existing homogeneisation techniques applied to undeformable heterogeneous dielectrics. To cite this article: T. Fen-Chong et al., C. R. Mecanique 332 (2004). 相似文献
39.
We propose novel compact multiport power dividers based on one-dimensional photonic crystal omnidirectional reflective waveguides. The proposed power dividers have advantages of wide bandwidth, flexible extended output channel number and compact size. The power dividers are numerical simulations using finite-difference time-domain method. Near-complete transmission and uniform at every branch of output power of multi-port power dividers are observed within wide frequency range. For a 1D PhC 1 × 6 power divider, the six output port achieved nearly 16.5% transmission at each arm from 1545 nm to 1553 nm and the size of 1 × 6 power divider is 14.3 μm × 14.3 μm at 1.55 μm operation wavelength. 相似文献
40.
We propose and experimentally demonstrate a frequency divider implemented by an optically injected Fabry-Perot laser diode (FP-LD) based on the nonlinear dynamical period-one oscillation. Injected by optical pulses, the FP-LD will oscillate in unstable dynamical period-one (P1) oscillation. Through changing the injected strength, emitting wavelength and bias current of the FP-LD, the oscillating frequencies of the P1 state can be varied. Once one of the harmonic frequencies is adjusted to match the repetition frequency of injected optical clock pulse, the P1 oscillation will be locked, and then a divided clock at the fundamental frequency of the P1 oscillation can be generated. By utilizing this divider, we can achieve the optical clock frequency division of divide-by-two, -three and -four in a wide input frequency range, for instance, of 9.0 to 20.0 GHz for divide-by-two. The influence of injected optical power on the timing jitter of the divided clock is also investigated. It is expected that this frequency divider can be applied to high frequency division exceeding 100 GHz due to its fast P1 oscillation. 相似文献