COIL腔镜薄膜参数实验研究

 利用HITACHI U-4001型分光光度计和基于光腔衰荡光谱的高反射率测量仪对氧碘化学激光器（COIL）输出镜的透过率和高反镜的反射率进行了膜层均匀性、测量重复性、激光辐照等方面的测量和实验研究。实验结果显示：离子束溅射膜的性能比电子枪蒸发膜更为稳定;只要保证镜片存放于干燥处,长时间放置对其薄膜的透过率和反射率均无明显影响。     

Computation of streamwise vorticity in a compressible flow of a winglet nozzle-based COIL device

Chemical oxygen iodine laser (COIL) is a high-power laser with potential applications in both military as well as in the industry. COIL is the only chemical laser based on electronic transition with a wavelength of 1.315 μm, which falls in the near-infrared (IR) range. Thus, COIL beam can also be transported via optical fibers for remote applications such as dismantling of nuclear reactors. The efficiency of a supersonic COIL is essentially a function of mixing specially in systems employing cross-stream injection of the secondary lasing (I₂) flow in supersonic regime into the primary pumping (O₂¹Δ_g) flow. Streamwise vorticity has been proven to be among the most effective manner of enhancing mixing and has been utilized in jet engines for thrust augmentation, noise reduction, supersonic combustion, etc. Therefore, a computational study of the generation of streamwise vorticity in the supersonic flow field of a COIL device employing a winglet nozzle with various delta wing angles of 5°, 10°, and 22.5° has been carried out. The study predicts a typical Mach number of approximately 1.75 for all the winglet geometries. The analysis also confirms that the winglet geometry doubles up both as a nozzle and as a vortex generator. The region of maximum turbulence and fully developed streamwise vortices is observed to occur close to the exit, at x/λ of 0.5, of the winglets making it the most suitable region for secondary flow injection for achieving efficient mixing. The predicted length scale of the scalloped mixer formed by the winglet nozzle is 4λ. Also, the winglet nozzle with 10° lobe angle is most suitable from the point of view of mixing developing cross-stream velocity of 120 m/s with acceptable pressure drop of 0.7 Torr. The winglet geometry with 5° lobe angle is associated with a low cross-stream velocity of 60 m/s, whereas the one with 22.5° lobe angle is associated with a large static and total pressure drop of 1.87 and 9.37 Torr, respectively, making both the geometries unsuitable for COIL systems. The experimental validation shows a close agreement with the computationally predicted values. The studies for the most suitable 10° lobe angle geometry show an observed Mach number of 1.72 with an improved mixing efficiency of 74% due to the occurrence of predicted streamwise vortices in the flow.     

单重态氧的气固化学反应发生体系的热力学分析

 采用Gaussian程序软件包,在RHF/Lanl2dz计算水平上,计算了由4类无机固体反应物(包括碱金属的过氧化物或超氧化物、碱土金属的过氧化物或超氧化物)与3类气体反应物(包括卤素气体、卤化氢气体和卤化氘气体)所组合的12种可产生单重态氧(O2(1Δg))的气固化学反应体系的热力学参数(如反应焓变、Gibbs反应自由能变化值以及化学反应平衡常数)。计算结果结合O2(1Δg)在氧碘化学激光器(COIL)中的实际应用,分析比较了不同固体反应物和不同气体反应物对气固化学反应体系产生O2(1Δg)的影响。分析结果表明：大部分的上述气固化学反应体系的Gibbs反应自由能变化值为负值,反应可自发进行;但在所有的气固化学反应体系组合中,由碱金属超氧化物与F2或Cl2组成的气固化学反应体系的反应生成热是比较少的,这有利于气固化学反应体系产生的O2(1Δg)用于COIL中。分析同时表明由碱金属超氧化物(如LiO2,NaO2或KO2)与卤素气体(如F2或Cl2)所组成的气固化学反应体系能更高效地产生O2(1Δg),较适合用于COIL中。     

氧碘化学激光器中相位扰动的模拟研究

 建立了含相位扰动的1维流场3维物理光学负载光腔模型。选用折叠非稳腔,模拟计算了斜激波中心距光轴不同距离时以及不同强度的斜激波对腔内光场相位分布和输出功率的影响。研究表明激光输出光束质量与腔内激波的分布位置和激波的强度有密切关系,应该避免激波中心近光轴时的强扰动效应引起的光束质量退变。实验装置的计算结果再现了实验现象。     

无缓冲气COIL扩压器流场数值模拟

 以无缓冲气化学氧碘激光器(COIL)实验器件的数据计算得到的混合喷管出口参数平均值作为光腔入口条件,对6种不同构型的扩压器从光腔入口至扩压器出口的流场进行了数值模拟,得出了各流场参数分布;对不同构型扩压器的流场特点、总压恢复性能进行了分析;研究了扩压器出口背压对流场参数的影响。结果表明：对于主流无缓冲气的COIL,等截面扩压器具有较好的压力恢复性能;增大扩压器出口背压可以使扩压器的压力恢复性能提高,然而,较高的背压使激波串向光腔方向移动,从而使光腔流场受到干扰,影响光腔的光束质量。     

改进的红外辐射-量热法测量O2(1△)绝对浓度

对应用于单重态氧发生器 (SOG)O2 (1 △ )绝对浓度测量的红外辐射 量热法从理论和实验两方面进行了改进 ,修正了过去忽略O2 (1 △ )温度变化所造成的系统误差 .此外 ,还详细介绍了在短时间工作的SOG上进行O2 (1△ )绝对浓度测量所必须的自动平衡电桥装置 ,并通过氧气热容的测量检验了它的可靠性 .最后的误差分析表明 ,O2 (1 △ )绝对浓度的相对误差为± 16% ,误差主要来源于光度池红外信号、压力和温度的测量 .     

Supersonic COIL with angular jet singlet oxygen generator

Supersonic Chemical Oxy-iodine Laser has been developed using a Singlet Oxygen Generator (SOG) with a novel approach. Generated singlet oxygen is taken out of the SOG at an angle of 40° to avoid the problem of carry over of droplets, which is one of the major drawbacks of horizontal system. The system has been operated up to 22 mmol/s chlorine flow rates. Chlorine utilization and singlet oxygen observed have been more than 90% and 60%, respectively. The observed maximum output power was 350 W, thus yielding a chemical efficiency of 17.5%.     

COIL简化模型计算

 采用简化动力学、增益模型，分析了常规虚共焦非稳腔和含屋脊镜折叠非稳腔这两种腔型在COIL中的应用，计算表明，折叠腔在改善COIL近场光强分布均匀性和提高近场输出功率方面明显优于常规腔。     

自发喇曼成像法在线测量流场组分浓度（Ⅱ）

介绍了利用自发Raman散射光谱测量低压气流组分绝对浓度的方法，在流动状态下得到了不同压力的自发喇曼散射光谱，检测最低压力为133Pa；对于含N2氧气流在已知N2浓度时实时标定检测了O2的绝对浓度，测量误差小于8％。，     

流量配比对Coil增益分布影响的数值研究

利用三维CFD技术,通过求解层流Navier-Stokes方程与组分输运方程,对简化后的化学氧碘激光RADICL模型进行数值模拟与分析,结合10种组分和21个基元反应的化学反应模型,对COIL亚声速段横向射流情况下,不同的主副流流量配比对化学氧碘激光器性能的影响进行分析与比较.结果证明,过高或过低的碘分子浓度状态均不利于合理、可观的小信号增益系数产生.存在一个最佳流量配比范围,与之对应的工作状态下,COIL的小信号增益系数会得到显著提高.