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21.
在1.2×1013W·cm-2低功率密度下,对基频激光预主短脉冲驱动类镍银X光激光机理进行了数值模拟和理论分析。证实了在靶长23 mm范围内X光激光都能获得有效放大,取得了和实验相符合的结果。考虑了单柱面镜线聚焦沿靶长度方向功率密度的非均匀性对X光激光放大的影响,采用弯曲靶能有效克服折射以及单柱面镜线聚焦功率密度非均匀带来的不利影响。理论模拟给出的类镍银X光激光的出光下限泵浦功率密度也与实验符合得很好。理论模拟还表明,采用1%左右的预脉冲强度并对预主脉冲时间间隔进行优化,X光激光的输出能量和能量转换效率将获得大幅度提高。 相似文献
22.
分析了高功率光纤激光器中受激布里渊散射(SBS)效应的抑制方法。研究表明,利用宽带噪声源高速相位调制展宽光谱的方法对于抑制SBS十分有效,可实现kW级用于光谱组束的数10 GHz高功率光纤激光子束。通过理论计算线宽与SBS阈值的关系,并分析噪声相位调制各参数对SBS阈值提升的影响,优化了光纤激光器设计参数。通过宽带噪声高速相位调制的方法,展宽单频种子源线宽至13 GHz,通过两级预放大至10 W后,使用20/400 m掺Yb光纤最终实现了中心波长1064 nm、线宽13 GHz、最高功率1.06 kW的激光输出,光束质量M2<1.2,光-光转换效率86%,实验过程未观测到模式不稳定性现象。进一步扩宽噪声源频带,加大调制深度,有望实现更高功率的窄线宽光纤激光输出。 相似文献
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利用一种用于光腔模式及光束传输模拟计算的特征向量法计算有源腔的2维失调,通过对谐振腔几何关系的求解,以及对增益进行薄层模型处理,最后利用特征向量法计算有源腔失调后的模式分布,发现失调造成了模式强度分布不均匀,并带来模式阶数的改变。计算了相应的光束质量因子,结果表明:在一定失调范围内,失调可能会带入新的模式竞争;谐振腔在一定范围的失调情况下,各阶模式的光束质量可能变好,也有可能变差,随着模式阶数的增加光束质量整体趋势是越来越差;原来简并的模式可能不再简并。该方法可以为计算失调后谐振腔的模场带来方便。 相似文献
25.
准确预测化学过程中分子内各原子提供或接受电子的能力以及化学反应可能的位点,即定量确定亲电性、亲核性和区域选择性,是一个十分重要却仍然亟待解决的课题.此前,基于我们新近提出的信息守恒原理,曾建议使用Hirshfeld电荷和信息增益作为两个等价的描述符用于此目的.我们的这个想法已经被成功地应用于两个系列的分子体系,且其有效性得到了充分的验证.然而,先前我们只考察了碳元素的这些性质,所以其结论的普遍性仍存在疑问.我们尚不清楚它是否适用于其他元素,而且对于同一元素的不同价态该结论是否适用也不清楚.为此,本文将考察含氮体系.对5个不同类别的含氮体系共计40个分子进行了研究,其中包括重氮苯、偶氮、重氮、一级和二级胺体系.结果表明,对所有五个含氮体系其Hirshfeld电荷与实验得到的亲电性和亲核性标度之间仍然存在着较强的线性关联.然而,这些相关性却依赖于氮元素的化合价类型和键合环境.该线性关系只能在同一类型中成立.我们对其可能的原因进行了讨论. 相似文献
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The hypothesis of the classical chemistry about bond dipoles resulting from shifts of separate pairs of electrons is proved using the non-canonical method of molecular orbitals (MOs). To this end, a relation is sought between the total charge distribution inside an individual chemical bond of a polyatomic molecule and the square of the respective single localized MO (LMO). General expressions for these MOs are obtained directly on the basis of the Brillouin theorem without invoking additional localization criteria. The two characteristics under comparison are presented in an explicit algebraic form in terms of meaningful components. Reshaping of square of the ‘own’ LMO of the given bond is shown to play the decisive role in the formation of secondary dipoles of initially homopolar bonds (e.g. of C–C and C–H bonds in substituted alkanes), as well as of bonds of relatively low initial polarity. Thus, representability of these dipoles by shifts of the ‘own’ pairs of electrons of respective bonds is supported. For bonds of a high initial polarity, the secondary dipoles are shown to originate mainly from contributions of LMOs of other bonds extending over the antibonding basis orbital of the given bond. Moreover, the actual secondary bond dipole takes an opposite direction vs. that predicted by the shift of the respective ‘own’ pair of electrons in this case. The latter result serves to account for the known low nucleofugality of highly electronegative heteroatoms in the SN2 reactions. 相似文献
28.
Pumping dye-doped organic polymer by interference pattern of a frequency-doubled Nd:YAG 532 nm laser to induce a periodic gain-structure and confining it within a stable optical resonator, the oscillation output can be effectively enhanced in comparison with either that of uniform irradiation, i.e., pumping, or of distributed feedback (DFB) operation, and the oscillation wavelength becomes tunable by adjusting the period of the interference pattern. Using Rhodamine-B as a dopant over the range from 200 to 1000 ppm, the oscillation output was enhanced by - 10 dB, which was larger than the output of the uniform irradiation and was - 30% greater than the DFB scheme. Moreover, changing the period of the interference pattern by adjusting the setting angle of the Koster prism enables us to vary the oscillation wavelength around 600 nm. 相似文献
29.
Arantza Estévez-Fernández Peter Borm Pedro Calleja Herbert Hamers 《Annals of Operations Research》2008,158(1):189-203
Two classes of one machine sequencing situations are considered in which each job corresponds to exactly one player but a
player may have more than one job to be processed, so called RP(repeated player) sequencing situations. In max-RP sequencing
situations it is assumed that each player’s cost function is linear with respect to the maximum completion time of his jobs,
whereas in min-RP sequencing situations the cost functions are linear with respect to the minimum completion times. For both
classes, following explicit procedures to go from the initial processing order to an optimal order for the coalition of all
players, equal gain splitting rules are defined. It is shown that these rules lead to core elements of the associated RP sequencing
games. Moreover, it is seen that min-RP sequencing games are convex.
We thank two referees for their valuable suggestions for improvement.
Financial support for P. Calleja has been given by the Ministerio de Educación y Ciencia and FEDER under grant SEJ2005-02443/ECON,
and by the Generalitat de Catalunya through a BE grant from AGAUR and grant 2005SGR00984. 相似文献
30.
Most of the literature on coded excitation describes the signal-to-noise ratio gain of a coded waveform in terms of the time-bandwidth product. We have shown that in the context of ultrasound imaging, the expression for the SNR gain provided by matched filtering a coded waveform, can be reduced to the total number of chips in the transmit signal. Hence, the SNR gain is independent of both the bandwidth and the duration of a single-chip. This concept is described in detail, clarifying this seeming contradiction. The impact of bandwidth and pulse duration on the SNR, SNR gain and axial resolution is described. Bandwidth requirements and the impact of regulatory peak-power limitations are also addressed. 相似文献