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131.
The effect of stoichiometry on chain segment and ion mobility in partially polymerized epoxy systems
The temperature dependence of steady-shear viscosity and ionic conductivity were measured for a series of unreacted mixtures and partially cured, ungelled samples of diglycidyl ether of bisphenol-A (DGEBA) and an amine cross-linking agent, diamino diphenyl sulfone (DDS). Six stoichiometric ratios of epoxide groups to amine hydrogens were examined. Free volume expressions were used to model the temperature dependence of the conductivity and viscosity for the unreacted DGEBA-DDS mixtures. In addition, these expressions were combined to successfully correlate changes in viscosity and conductivity during the DGEBA-DDS polymerization prior to gelation. It also was demonstrated that the change in weight average molecular weight during polymerization could be interpreted from the dielectric data. Through studying variations in the stoichiometry, it was possible to examine the effects of changes in chemical structure and ion concentration on the fitted parameters in the free volume models. The inherent ion transport factor (ζ0) was found to be inversely proportional to the concentration of ions in the test samples. The fractional free volume for segmental motion (B) was found to increase with an increase in the glass transition temperature and to be a function of the rigidity of the polymer. ©1995 John Wiley & Sons, Inc. 相似文献
132.
J. N. Tsitsiklis 《Journal of Optimization Theory and Applications》1984,44(1):105-136
An infinite horizon, expected average cost, dynamic routing problem is formulated for a simple failure-prone queueing system, modelled as a continuous time, continuous state controlled stochastic process. We prove that the optimal average cost is independent of the initial state and that the cost-to-go functions of dynamic programming are convex. These results, together with a set of optimality conditions, lead to the conclusion that optimal policies are switching policies, characterized by a set of switching curves (or regions), each curve corresponding to a particular state of the nodes (servers). 相似文献
133.
R. K. Mohanty Samir Karaa Urvashi Arora 《Numerical Methods for Partial Differential Equations》2007,23(3):640-651
This article develops a new two‐level three‐point implicit finite difference scheme of order 2 in time and 4 in space based on arithmetic average discretization for the solution of nonlinear parabolic equation ε uxx = f(x, t, u, ux, ut), 0 < x < 1, t > 0 subject to appropriate initial and Dirichlet boundary conditions, where ε > 0 is a small positive constant. We also propose a new explicit difference scheme of order 2 in time and 4 in space for the estimates of (?u/?x). The main objective is the proposed formulas are directly applicable to both singular and nonsingular problems. We do not require any fictitious points outside the solution region and any special technique to handle the singular problems. Stability analysis of a model problem is discussed. Numerical results are provided to validate the usefulness of the proposed formulas. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2007 相似文献
134.
At recent, Hourgat et gave a domain decomposition algorithm for elliptic problems which can be implemented in parallel. Many numerical experiments have illustrated its efficiency. In the present paper, we apply this algorithm to solve the discrete parabolic problems, analyse its convergence and show that its convergence rale is about (1 - 2p + σp2 ) which is nearly optimal and independent of the parameter τ, where σ τ O((1 +H )(1 + ln(H / h))2 ). 0 < p < 1 / σ,τ,h,H are the time step size, finite element parameter and subdomain diameter, respectively. 相似文献
135.
Arnold Greenland 《Stochastic Processes and their Applications》1979,9(3):253-259
A necessary and sufficient condition is given for the existence of a finite invariant measure equivalent to a given reference measure for a discrete time, general state Markov process. The condition is an extension of one given by D. Maharam in the deterministic case and involves an averaging method (called by Maraham ‘density averaging’) applied to the Radon-Nikodym derivatives with respect to the reference measure of the usual sequence of measures induced by the Markov process acting on the fixed reference 相似文献
136.
Richard Barakat 《Stochastic Processes and their Applications》1978,8(1):77-85
The average frequency with which a trigonometric sum having linearly independent frequencies achieves a given value in a specified time interval was solved by Kac in the form of a double integral. In the present paper, Kac's solution is generalized by allowing the amplitudes of the sinusoidal terms to be statistically independent random variables possessing compact probability density functions. The average frequency is expressed as a Fourier cosine series. Representative numerical calculations are shown. The asymptotic form of the average frequency is also discussed. 相似文献
137.
Chris A. Kieslich 《Journal of Non》2011,357(2):707-716
Electrostatically-driven association of proteins is important to many biological functions, and understanding which amino acid residues contribute to these interactions is crucial to protein design. Theoretical calculations that are used to elucidate the role of electrostatics in association are typically based on a single experimentally determined protein structure, while an underlying rigid-body assumption is adopted. The goal of this study was to investigate the role of conformational fluctuations on electrostatic interaction energies, as applied to the electrostatic analysis of barnase-barstar. For our calculations, we apply theoretical alanine-scan mutagenesis to introduce charge perturbations by replacing every ionizable residue with alanine, one at a time. Electrostatic clustering and free energy calculations based on the Poisson-Boltzmann method are used to evaluate the effects of each perturbation. Molecular dynamics simulations are performed for the barnase-barstar parent complex and seven experimental alanine mutations from the literature, in order to introduce relaxation before and after mutation. We discuss the effects of dynamics, in the form of pre- and post-mutation relaxation, on electrostatic clustering and free energies of association in light of experimental data. We also examine the utility of nine electrostatic similarity methods for clustering of barnase alanine-scan mutants. Our calculations suggest that the rigid-body assumption is reasonable for electrostatic calculations of barnase-barstar. 相似文献
138.
以中链脂肪酸(MCFA)为模型材料,比较了高压微射流(HPM)、超声波和微孔过滤3种方法处理后的MCFA脂质体,着重研究了HPM的处理压力和处理次数对脂质体的平均粒度、包封率和稳定性的影响。结果表明:相比超声波和微孔过滤法,HPM处理后的MCFA脂质体的平均粒度最小、包封率最高、稳定性良好;在120 MPa压力条件下处理6次时,MCFA脂质体的平均粒度达到最小,为(73.9±10.2)nm,包封率为(52.20±9.57)%;在120 MPa压力条件下处理4次时,包封率和载药量达到最高,分别为(70.64±11.25)%和(9.42±0.83)%,稳定性系数最高,为0.9990±3.6951,平均粒度为(78.9±21.5)nm。 相似文献
139.
140.
Energy average formula of photon gas rederived by using the generalised Hermann-Feynman theorem 下载免费PDF全文
By virtue of the generalised Hermann-Feynmam theorem we re-derive the energy average formula of photon gas. This is another useful application of the theorem. 相似文献