气-质联用/沸点-Lee保留指数法快速分析胆固醇裂解产物

利用高分辨裂解气相色谱-质谱（HRPyGC-MS）技术在600、750、900℃条件下对胆固醇进行裂解,通过NIST02质谱数据库、沸点和Lce保留指数法对胆固醇裂解产物进行了定性分析;利用峰面积归一化法对其中48种化合物包括脂肪族碳氢化合物和芳香族碳氢化合物进行了相对含量分析,组分含量最小为0.08%,最大为65.07%.     

Influence of gravity on pool boiling on a flat plate: Results of parabolic flights and ground experiments

Experiments of pool boiling of HFE7000 on a flat plate have been performed in both earth and microgravity conditions in parabolic flights. The effects of pressure, subcooling and gravity are studied. Experiments show that in fully developed boiling regime gravity and subcooling have a weak influence on heat transfer. By identifying mechanisms that control heat transfer, the weak influences of gravity and subcooling are explained.     

Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

The vapor pressure and vaporization enthalpy of codlemone (trans, trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 ± 2.6) kJ · mol⁻¹ and a vapor pressure, p/Pa = (0.083 ± 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of T_B = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of T_B = (549.1 ± 0.1) K is also estimated by extrapolation.     

The effect of internal surface modification on flow instabilities in forced convection boiling in a horizontal tube

This paper presents the experimental result of a study on the effects of heat transfer enhancement on two-phase flow instabilities in a horizontal in-tube flow boiling system. Five different heat transfer surface configurations and five different inlet temperatures are used to observe the effect of heat transfer enhancement and inlet subcooling. All experiments are carried out at constant heat input, system pressure and exit restriction. Dynamic instabilities, namely pressure-drop type, density-wave type and thermal oscillations are found to occur for all the investigated temperatures and enhancement configurations, and the boundaries for the appearance of these oscillations are found. The effect of the enhancement configurations on the characteristics of the boiling flow dynamic instabilities is studied in detail. The comparison between the bare tube and the enhanced tube configurations are made on the basis of boiling flow instabilities. Differences among the enhanced configurations are also determined to observe which of them is the most stable and unstable one. The amplitudes and periods of pressure-drop type oscillations and density-wave type oscillations for tubes with enhanced surfaces are found to be higher than those of the bare tube. The bare tube is found to be the most stable configuration, while tube with internal springs having bigger pitch is found to be the most unstable one among the tested tubes. It is found that system stability increases with decreasing equivalent diameter for the same type heater tube configurations; however, on the basis of effective diameter there is no single result such as stability increase/decrease with increasing/decreasing effective diameter.     

Boiling heat transfer enhancement of water on tubes in compact in-line bundles

In desalinization devices and some heat exchangers making use of low-quality heat energy, both wall temperatures and wall heat fluxes of the heated tubes are generally quite low; hence they cannot cause boiling in flooded tube-bundle evaporators with common large tube spacing. However, when the tube spacing is very small, the incipient boiling in restricted spaces can generate and results in higher heat transfer than that of pool boiling at the same heat flux. This study investigated experimentally the effects of tube spacing, positions of tubes and test pressures on the boiling heat transfer of water in restricted spaces of the compact in-line bundles consisting of smooth horizontal tubes. The experimental results show that tube spacing and tube position have significant effects on the boiling heat transfer in a compact tube bundle. There is an optimum tube spacing that provides the largest heat transfer coefficient at the same heat flux.     

Improvement in Heat Transfer of a Two-Phased Closed Thermosyphon Using Silver-Decorated MWCNT/Water

Hereby, a comparative study of thermal and thermodynamic properties of nanofluids based on multiwalled carbon nanotubes (MWCNTs) and water is described. The first nanofluid includes pristine MWCNT while the second nanofluid prepared by MWCNT decorated with silver. To achieve the covalent functionalization, morphology of MWCNT-Ag was studied by transmission electron microscopy. Subsequently, the value of the entropy generation and thermal performance of nanofluids (MWCNT/water and MWCNT-Ag/water) were inspected in a two-phased closed thermosyphon (TPCT). The results suggested as the concentration and input power increased, the thermal resistance decreased. Also in different concentrations, the thermal efficiency of nanofluids obeyed the sequence: MWCNT-Ag (1 wt%) > MWCNT-Ag (0.5 wt%) > MWCNT (1 wt%) > MWCNT (0.5 wt%) > water. A variation of the vacuum pressure was also studied in the synthesized nanofluids as compared with pure water. The results were shown a lower pressure drop of MWCNT-Ag/water than MWCNT/water and the water. Also it was found that the higher thermal performance is produced using higher extent of covalent functional groups (with higher thermal conductivity). MWCNT-Ag/water can be an appropriate substitution for the water in the thermal equipment due to the intensive thermal efficiency and/or low thermal resistance compared with pure water.      

Natural convection boiling of water and surfactants in narrow horizontal annular channels

Natural convection boiling of water and surfactants at atmospheric pressure in narrow horizontal annular channels was studied experimentally in the range of Bond numbers Bo = 0.185–1.52. The flow pattern was visualized by high-speed video recording to identify the different regimes of boiling of water and surfactants. The channel length was 24 mm and 36 mm, the gap size was 0.45, 1.2, 2.2, and 3.7 mm. The heat flux was in the range of 20–500 kW/m², the concentration of surfactant solutions was varied from 10 to 600 ppm. For water boiling at Bond numbers Bo < 1 the CHF in restricted space is lower than that in unconfined space. This effect increases with increasing the channel length. For water at Bond number Bo = 1.52, boiling can almost be considered as unconfined. Additive of surfactant led to enhancement of heat transfer compared to water boiling in the same gap size, however, this effect decreased with decreasing gap size. For the same gap size, CHF in surfactant solutions was significantly lower than that in water. Hysteresis was observed for boiling in degraded surfactant solutions.     

A new microstructure for pool boiling

Combining electrocoating and etching processes, we have developed a new type of microstructure for nucleate boiling. The basic elements of the structure are cylindrically shaped; their density ranges up to 10⁷ cm⁻².To test the efficiency of the structure, the outer surface of a tube has been provided with such a structure and used in pool boiling experiments with the refrigerant R141b at atmospheric pressure. The results obtained show the heat flux to remain independent of the wall superheat in the fully developed boiling region. The behavior is novel. It is most probably associated with the density of active bubble nucleation sites. Activated at a certain wall superheat, the density of the sites generating bubbles remains apparently unaffected by raising the heat flux. Given that these preliminary results should be confirmed by further experiments, the microstructure developed will be suitable for nucleate boiling in general, but for keeping the heating surface largely isothermal, despite the variation of the heat flux, in particular.