Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tert-butyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation

Fluorophilic ethers having the structure RC(CF₃)₂O(CH₂)₃C_nF_2n + 1 are obtained in high yields, when F-tert-butyl alcohol (R = CF₃), F-acetone hydrate (R = O(CH₂)₃C_nF_2n + 1), F-pinacol (R = C(CF₃)₂O(CH₂)₃C_nF_2n + 1) are reacted with 3-perfluoroalkyl-1-propanols (C_nF_2n + 1(CH₂)₃OH, n = 4, 6, 8, 10) in a Mitsunobu reaction (Ph₃P/DIAD [i-PrO₂CN = NCO₂Pr-i]/ether). The parent lipophilic ethers with the structure of (CF₃)₃CO(CH₂)₃C_nH_2n + 1 were prepared analogously using the corresponding fatty alcohols and F-tert-butyl alcohol. To achieve ideal separations, products were transferred to orthogonal phases relative to the other reaction components using fluorous extraction, fluorous solid-organic liquid filtration, or steam-distillation. Selected physical properties including melting and boiling point, together with fluorous partition coefficients of these ethers were determined and the figures obtained were qualitatively analyzed using relevant thermodynamic theories. Some of these ethers are liquids with rather low freezing points and are miscible with fluorocarbon solvents.     

Heat transfer correlation for boiling flows in small rectangular horizontal channels with low aspect ratios

In the present experimental study, a correlation is proposed to represent the heat transfer coefficients of the boiling flows through horizontal rectangular channels with low aspect ratios. The gap between the upper and the lower plates of each channel ranges from 0.4 to 2 mm while the channel width being fixed to 20 mm. Refrigerant 113 was used as the test fluid. The mass flux ranges from 50 to 200 kg/m² s and the channel walls were uniformly heated up to 15 kW/m². The quality range covers from 0.15 to 0.75 and the flow pattern appeared to be annular. The modified Lockhart–Martinelli correlation for the frictional pressure drop was confirmed to be within an accuracy of ±20%. The heat transfer coefficients increase with the mass flux and the local quality; however the effect of the heat flux appears to be minor. At the low mass flux condition, which is more likely to be with the smaller gap size, the heat transfer rate is primarily controlled by the liquid film thickness. A modified form of the enhancement factor F for the heat transfer coefficient in the range of Re_LF200 well correlates the experimental data within the deviation of ±20%. The Kandlikar's flow boiling correlation covers the higher mass flux range (Re_LF>200) with 10.7% mean deviation.     

Review of nucleate pool boiling bubble heat transfer mechanisms

Enhanced convection, transient conduction, microlayer evaporation, and contact line heat transfer have all been proposed as mechanisms by which bubbles transfer energy during boiling. Models based on these mechanisms contain fitting parameters that are used to fit them to the data, resulting a proliferation of “validated” models. A review of the recent experimental, analytical, and numerical work into single bubble heat transfer is presented to determine the contribution of each of the above mechanisms to the overall heat transfer. Transient conduction and microconvection are found to be the dominant heat transfer mechanisms. Heat transfer through the microlayer and at the three-phase contact line do not contribute more than about 25% of the overall heat transfer.     

Seed bubbles stabilize flow and heat transfer in parallel microchannels

Seed bubbles are generated on microheaters located at the microchannel upstream and driven by a pulse voltage signal, to improve flow and heat transfer performance in microchannels. The present study investigates how seed bubbles stabilize flow and heat transfer in micro-boiling systems. For the forced convection flow, when heat flux at the wall surface is continuously increased, flow instability is self-sustained in microchannels with large oscillation amplitudes and long periods. Introduction of seed bubbles in time sequence improves flow and heat transfer performance significantly. Low frequency (∼10 Hz) seed bubbles not only decrease oscillation amplitudes of pressure drops, fluid inlet and outlet temperatures and heating surface temperatures, but also shorten oscillation cycle periods. High frequency (∼100 Hz or high) seed bubbles completely suppress the flow instability and the heat transfer system displays stable parameters of pressure drops, fluid inlet and outlet temperatures and heating surface temperatures. Flow visualizations show that a quasi-stable boundary interface from spheric bubble to elongated bubble is maintained in a very narrow distance range at any time. The seed bubble technique almost does not increase the pressure drop across microsystems, which is thoroughly different from those reported in the literature. The higher the seed bubble frequency, the more decreased heating surface temperatures are. A saturation seed bubble frequency of 1000–2000 Hz can be reached, at which heat transfer enhancement attains the maximum degree, inferring a complete thermal equilibrium of vapor and liquid phases in microchannels. Benefits of the seed bubble technique are the stabilization of flow and heat transfer, decreasing heating surface temperatures and improving temperature uniformity of the heating surface.     

Natural convection boiling of water and surfactant solutions having negligible environmental impact in vertical confined space

Natural convection boiling of water and surfactant solutions in a confined space between two vertical plates was studied experimentally in the range of heat flux 19–170 kW/m². The surfactant used was Alkyl (8–16) Glucoside having negligible environmental impact. The gap size was changed in the range of s = 1–80 mm, the concentration of surfactant solutions was changed in the range of C = 200–600 ppm. Generally, an addition of surfactant leads to an enhancement of heat transfer compared to water boiling at the same gap size. Enhancement of the heat transfer depending on the solution concentration at fixed gap size yields maximum value at the solution concentration close to the critical micelle concentration. The effect of confined space on a bubble dynamic was studied. Temperature field on the heater was determined using the infrared thermography technique. Quasi periodic wall temperature fluctuations were observed in the regime of high heat flux. An increase in the Bond number leads to an increase in the dimensionless frequency of the heated wall temperature fluctuations. The correlation between the dimensionless parameter of heat transfer and the Bond number under condition of quasi periodic boiling was derived and discussed.     

Effect of acoustic cavitation on boiling heat transfer

Boiling heat transfer on a horizontal circular copper tube in an acoustical field is investigated experimentally and the relation between the liquid cavitation, the boiling and the micro bubble radii are analyzed theoretically. The results show that cavitation bubbles have an important influence on the nucleation, growth and collapse of vapor embryo within cavities on the heat transfer surface and that the enhancement of boiling heat transfer by acoustic cavitation mainly depends on whether the vapor embryo is activated by the cavitation bubbles to initiate boiling.     

Theoretical analyses on boiling critical heat flux with porous media

Porous media has been widely applied to enhance boiling heat transfer in industry, especially for increasing the value of critical heat flux (CHF). Two cases were considered in the paper: boiling within porous bed and boiling above on porous coatings. For boiling within porous bed, simplified Rayleigh–Taylor stability was analyzed and parametric effects of porous media on boiling critical heat flux were revealed. For boiling above on porous coatings, a simple new critical heat flux model was proposed basing on the analysis of liquid film stability and parametric effect of porous coatings on CHF was elaborated.     

盐酸消解-原子荧光光谱仪测定土壤中总汞

本研究利用原子荧光光谱仪,探寻适合本实验室测定土壤总汞的方法。实验中对沸水浴消解和电热板消解这两种土壤样品的前处理方法、消解液种类以及仪器检测等因素进行条件试验,结果表明：土壤样品选用(1+1)盐酸溶液在沸水浴下加热消解、在热汞条件下分析待测液中的总汞含量是最佳样品消解及测定方法,该方法标准曲线的相关系数大于0.999,仪器最低检出限为0.006μg/g,精密度为1.2%~4.8%(n=7),样品准确度满足标准土样的要求。该方法快速简单,空白背景低,样品精密度准确度较高,适用于土壤中总汞的测定。