可溶液加工的蒽醌/芴类双极性荧光材料的合成及其光电性质

通过Suzuki反应合成得到了一种可溶液加工的蒽醌/芴类双极性荧光材料2-蒽醌基-9, 9'-二异辛基芴（FAA）,利用紫外吸收光谱和荧光发射光谱对其光物理性质进行了初步研究,并采用密度泛函理论计算方法分析了分子光物理性质的本质。通过单载流子器件的性能测试,证实了FAA具有较好的双极性传输特性。进而研究了该材料的电致发光性能,将其掺杂于主体材料1, 3-双（9-咔唑基）苯（mCP）中,利用旋涂法制备了结构为ITO（氧化铟锡）/PEDOT：PSS（聚3, 4-乙撑二氧噻吩：聚苯乙烯磺酸盐）/mCP：FAA/TmPyPb（1, 3, 5-三[（3-吡啶基）-3-苯基]苯）/LiF/Al的有机发光二极管。器件的启亮电压约为7.4 V,最大亮度为1719 cd·m^-2,最大电流效率和最大功率效率分别为1.66 cd·A^-1和0.56 lm·W^-1;同时,结合器件各功能层的能级结构图,探讨了其电致发光机制。     

双极性流对低阻抗器件的影响

 分析讨论了双极性流对平面二极管发射电流的影响,并利用PIC程序对平面二极管中的双极性流问题进行了数值对比。在此基础上模拟研究了具有径向发射特点的低阻抗高功率微波器件MILO中的双极性流问题。结果表明：双极性流的出现使器件偏离最佳工作点,使输出功率和效率降低,电压越高,器件偏离最佳工作点就会越远,当电压高到一定值以后会使器件的工作点移至B-H曲线以下,器件处于过绝缘状态,不能正常工作。     

双极型晶体管损坏与强电磁脉冲注入位置的关系

 利用时域有限差分法,对双极型晶体管(BJT)在强电磁脉冲作用下的瞬态响应进行了2维数值模拟,研究了电磁脉冲从不同极板注入时BJT的响应情况,根据温度分布的集中程度分析了发生烧毁的难易程度。模拟得出：发射极注入最容易导致烧毁,集电极注入次之,基极注入相对不易导致烧毁;发射极注入烧毁所消耗能量随着脉冲电压上升而下降,到30 V以后基本与电压的升高无关,集电极注入烧毁所消耗的能量则随着电压上升而上升,到100 V以后由于BE结上热点的出现而开始下降。     

mCMC-PEG-CS双极膜在电还原制备巯基乙酸中的应用

以Fe3+改性羧甲基纤维素(CMC)和聚乙二醇(PEG)共混物为阳膜, 以戊二醛改性壳聚糖(CS)和聚乙二醇共混物为阴膜, 制备了mCMC-PEG-CS双极膜, 并将其用作电解还原制备巯基乙酸(TGA)电解槽中阴阳两室间的隔膜. 以硫代硫酸钠法合成的巯基乙酸(TGA)和二硫代二乙酸(DTDGA)混合物为原料, 研究了酸浓度、温度及电解电流密度对电还原DTDGA制备TGA的生成量和电流效率的影响. 实验结果表明, 在TGA初始合成质量分数为2.79%, 电流密度为10 mA/cm2, 35 ℃电解时, 阴极室电还原产物巯基乙酸的电流效率为74.69%, 电解过程中的平均电流效率为54.02%. 与传统的金属还原法还原DTDGA制备的TGA相比, 不仅避免了昂贵的金属还原剂锌的消耗, 而且消除了反应副产物锌泥对环境的污染.     

InP/In0.53Ga0.47As/InP双异质结双极型晶体管的仿真与分析

运用Silvaco-TCAD软件构建了InP/In_(0.53)Ga_(0.47)As/InP双异质结双极型晶体管模型,研究了掺杂浓度、厚度以及温度对器件特性的影响.结果表明:双异质结双极型晶体管DHBT的开启电压能达到约0.4V,当浓度达到4×10^(19) cm^(-3)的时候,电流增益可以达到一个最佳状态,其峰值能达到约125左右,且浓度对截止频率以及最高振荡频率没有太大的影响;当增大基区厚度时,电流增益会减小,改变厚度能够使DHBT输出特性得以提升,并且提高基区电流的注入;双异质结双极型晶体管具有很好的温度稳定性.     

含有三苯胺-三唑双极性单元的橙红光阳离子型铱(Ⅲ)配合物的合成及在LEDs中的应用

以2-萘基吡啶(npy)为主配体,N,N-二苯基-4-[4-苯基-5-(吡啶-2-基)-4H-1,2,4-三唑-3-基]苯胺(DPPTA)为辅助配体,合成了含有三苯胺-三唑双极性结构单元的橙红光阳离子型有机铱(Ⅲ)配合物[(npy)₂Ir(DPPTA)]PF₆.该配合物的热分解温度高达345℃,从20℃升温到100℃时,相对发光强度衰减28.0%,发光颜色稳定.其所含的双极性结构单元使其能有效地吸收Ga N芯片的蓝光(λ_em,max=455 nm),进而可被蓝光高效激发.以Ga N蓝光芯片作为激发光源,[(npy)₂Ir(DPPTA)]PF₆为下转换发光材料,可以制得橙红光LEDs;进一步与黄光材料Y₃Al₅O₁₂∶Ce³⁺(YAG:Ce³⁺)联用,可以制得高效的中性白光和暖白光LEDs.     

不同惰性填料复极性固定床电解槽处理对硝基酚钠废水行为比较

分别以磺化煤、果壳、PVC塑料、回收旧塑料等4种密度与活性炭相当的惰性填料替代工程上广泛使用的石英砂,结合适当的反冲洗解决复极性固定床电解槽(BPBC,b ipolar packed bed cell)存在的电极污染及填料分层问题.并以含有对硝基酚钠的废水降解实验考察其应用的可行性.结果表明,以回收旧塑料及磺化煤作为填料的BPBC处理效果优于石英砂的,而果壳、PVC塑料的与石英砂的处理效果相当.反冲洗后,以磺化煤、果壳、PVC塑料和回收旧塑料作填料的电解槽再生率均大于石英砂的.     

Control of Interfacial Potentials and Redox Reactions on Bipolar Electrodes Using Ag/AgCl

The interfacial potential difference on the surface of bipolar electrodes was controlled by placing Ag/AgCl on part of the electrode. Oxygen reduction on the cathodic pole was coupled with an electrochemiluminescence (ECL) reaction on the anodic pole. In an open bipolar system, the ECL intensity depended on the location of Ag/AgCl and the concentration of Cl⁻ ions. A current flowed through Ag/AgCl and the ratio of currents generated at the anodic and cathodic poles was affected by the position of Ag/AgCl. Further, the effect of Ag/AgCl placement was also demonstrated in a closed bipolar system using hydrogen peroxide (H₂O₂) and glucose as analytes. Ag/AgCl was also effective in adjusting the sensitivity to these analytes to achieve the best performance. This method of interfacial potential control is expected to contribute toward the development of reliable sensing devices and applications such as redox cycling, which require precise potential control.     

Digital versatile disc bipolar electrode: A fast and low-cost approach for visual sensing of analytes and electrocatalysts screening

This work represents a new, extremely low cost and easy method for fabrication of bipolar electrode (BPE) for rapid and simultaneous screening of potential candidates for electrocatalytic reactions and sensing applications. Our method takes advantage of the silver reflective layer deposited on already available recordable digital versatile disc (DVD-R) polycarbonate substrate which acts as BPE. Oxidation of the reflective layer of the DVD-R in anodic pole of the BPE results in a permanent and visually measurable dissolute length. Therefore, one could correlate the electrocatalytic activity of the catalyst at the cathodic pole of the BPE, as well as the concentration of analyte in the solution, to the dissolution length of the BPE. To illustrate the promising applications of this new substrate as BPE, p-benzoquinone (BQ) and hydrogen peroxide were tested as model targets for the sensing application. Moreover, in order to show the feasibility of using DVD BPEs for screening applications, the electrocatalytic activity of Pt, Pd, Au, and pristine DVD substrate toward hydrogen evolution reaction (HER) were compared using an array of BPEs prepared on DVD substrate.     

Investigation of bipolar matrix based mixed host in highly efficient green delayed fluorescence organic light-emitting diodes

The mixed cohosts of electron transport host (E-host): 4,40-bis(carbazol-9-yl)biphenyl (CBP) have been comparatively investigated for an efficient green fluorescent organic light emitting diode (OLED) doped with a thermally activated delayed fluorescence (TADF) emitter (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile (4CzIPN). The E-host:CBP systems significantly enhance the electroluminescent (EL) properties. After doping E-host, the lifetime of the emissive layer decreases and the surface becomes smoother, together with the impedance decreases for one magnitude and the hole-injection depresses. The charge balance and improved interface both contribute to the EL performance enhancement. Here we develop a universal mixed host system suitable to most of emitters.