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991.
Udai B. Singh D.C. AgarwalS.A. Khan Manish KumarA. Tripathi R. SinghalB.K. Panigrahi D.K. Avasthi 《Applied Surface Science》2011,258(4):1464-1469
Hydrophilic Ag nanostructures were synthesized by physical vapour deposition of 5 nm Ag thin films followed by irradiation with 1.5 keV Ar atoms. Optical absorbance measurements show a characteristic surface plasmon resonance absorption band in visible region. A blue-shift in absorbance from 532 to 450 nm is observed with increasing fluence from 1 × 1016 to 3 × 1016 atoms/cm2. Atomic force microscopy was performed for the pristine and irradiated samples to study the surface morphology. The atom beam irradiation induced sputtering and surface diffusion lead to the formation of plasmonic surface. Rutherford backscattering spectroscopy of the pristine and irradiated film indicates that metal content in the film decreases with ion fluence, which is attributed to the sputtering of Ag by Ar atoms. The contact angle measurement demonstrates the possibility of engineering the hydrophilicity by atom beam irradiation. 相似文献
992.
Co(OH)2 nanoparticles were synthesized using only CoSO4·7H2O and NaOH as reactants without other auxiliary reagents via a simple, low-cost and practical ball-milling technique and investigated as the active electrode materials for supercapacitors. The structure and morphology of the resulting Co(OH)2 samples were examined by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and transmission electron microscopy (TEM). The observations revealed the formation of brucite-like phase of β-Co(OH)2, which had an irregular sphere-like shape with an average size of 50-100 nm. When investigated as electrode materials for supercapacitors, the β-Co(OH)2 exhibited good energy-storage performances in terms of high specific capacitance of 599 F g−1 and excellent capacity retention, suggesting its potential application in the electrode material for supercapacitors. 相似文献
993.
The nanocrystalline samples of La0.9Sr0.1MnO3 (LSMO) have been prepared by the combustion method. The thermo gravimetric analysis of precursor was carried out. The X-ray diffraction study confirms the rhombohedral crystal structure without any other impurity phases. The morphology and magnetic properties change with annealing temperature. The saturation magnetization increases linearly and coercivity of the nanoparticles varies significantly as annealing temperature increases. The maximum saturation magnetization and lower coercivity found for the sample heat treated at 1200 °C are 52.5 emu/g and 10.7 Oe respectively. 相似文献
994.
995.
Xiao-Ping WeiXian-Ru Hu Bin LiuYi Lei Hong DengMing-Kun Yang Jian-Bo Deng 《Journal of magnetism and magnetic materials》2011,323(12):1606-1610
The first-principle calculations within density functional theory are used to investigate the electronic structure and magnetism of the Mn2ZnGe Heusler alloy with CuHg2Ti-type structure. The half-metallic ferrimagnets (HMFs) in Mn2ZnGe are predicted. The energy gap lies in the minority-spin band for the Mn2ZnGe alloy. The calculated total spin magnetic moment is −2μB per unit cell for Mn2ZnGe alloy, the magnetic moments of Zn and Mn(B) are antiparallel to that of Mn(A), and we also found that the half-metallic properties of Mn2ZnGe are insensitive to the dependence of lattice within the wide range of 5.69 and 5.80 Å where exhibiting perfect 100% spin polarization at the Fermi energy. 相似文献
996.
Ravindar Tadi Yong-Il KimDebasish Sarkar CheolGi KimKwon-Sang Ryu 《Journal of magnetism and magnetic materials》2011,323(5):564-568
BaTiO3+MgFe2O4 material system was synthesized by hybrid chemical process using chlorides and nitrates of barium, titanium, iron, and magnesium. Magnetic properties of the composite samples measured as a function of annealing conditions indicated soft magnetic behavior. Saturation specific magnetization from 8 21 emu/g was observed for samples annealed at temperature between 950 and 1150 °C. Variation of specific saturation magnetization with respect to annealing temperature was related with the distribution of Fe cations in the tetrahedral and octahedral sites of MgFe2O4. Electrical properties of the samples annealed at different temperatures were measured to analyze the coexistence of ferroelectric phase. Dielectric constant varying from 15 to 200 with respect to frequency was observed for samples annealed from 950 to 1150 °C. 相似文献
997.
Anisotropic Sm-Fe-N bulk magnets were produced by the compression shearing method using a hardened steel plate and a tungsten-carbide (WC) plate. It was found that the magnets retained the original Sm2Fe17N3 phase structure without any appreciable decomposition of the Sm2Fe17N3 phase. The anisotropic Sm-Fe-N bulk magnet produced using a WC plate had a higher density and higher crystallographic alignment of the Sm2Fe17N3 phase than that produced using a hardened steel plate, and exhibited high maximum energy products of 228 kJ/m3 with a high coercivity of 0.88 MA/m. 相似文献
998.
Barium hexaferrite BaFe12O19 powders have been synthesized using the modified co-precipitation method. Modification was performed via the ultrasonication of the precipitated precursors at room temperature for 1 h and the additions of the 2% KNO3, surface active agents and oxalic acid. The results revealed that single phase magnetic barium hexaferrite was formed at a low annealing temperature of 800 °C for 2 h with the Fe3+/Ba2+ molar ratio 8. The microstructure of the powders appeared as a homogeneous hexagonal platelet-like structure using 2% KNO3 as the crystal modifier. A saturation magnetization (60.4 emu/g) was achieved for the BaFe12O19 phase formed at 1000 °C for 2 h with Fe3+/Ba2+ molar ratio 8 using 5 M NaOH solution at pH 10 in the presence of 2% KNO3. Moreover, the saturation magnetization was 52.2 emu/g for the precipitated precursor at Fe3+/Ba2+ molar ratio 12 in was achieved for the precipitated precursor ultrasonicated for 1 h and then annealed at 1200 °C for 2 h. Coercivities from 956.9 to 4558 Oe were obtained at different synthesis conditions. 相似文献
999.
Yan Zhang Ying-Ni DuanJian-Min Zhang Ke-Wei Xu 《Journal of magnetism and magnetic materials》2011,323(6):842-848
Under GGA, size dependence of the geometrical structures, stabilities and magnetic properties of FeCon−1 clusters (n≤16) have been investigated together with the Con clusters for comparison using DFT within the PAW method implemented in VASP. The replaced Fe atom is favorable to occupy the surface position except for FeCo13. The peaks appeared at n=6, 9 and 11 for FeCon−1 clusters and at n=6, 9 and 12 for Con clusters on the size dependence of second difference of total energy imply that these clusters possess relatively higher stability. The magnetic moment is strongly correlated with the effective hybridization, which is closely related to the average bond length 〈d〉 and average coordination number 〈nc〉. A small change in the total charge of Fe atom in FeCon−1 clusters will lead to a relative large reverse change in the total magnetic moment of Fe atom. 相似文献
1000.
Sudhakar PandayB.S.S. Daniel P. Jeevanandam 《Journal of magnetism and magnetic materials》2011,323(17):2271-2280
Nanocrystalline Co-Ni alloys with different compositions were prepared by polyol reduction of mixed cobalt nickel hydroxides. The precursors (mixed cobalt nickel hydroxides) were prepared by co-precipitation. Powder X-ray diffraction analysis indicated the formation of fcc phase in the alloys and their crystallite size in the range 17-25 nm. Scanning electron microscopy and transmission electron microscopy studies revealed the morphology of the particles as being close to spherical, and the energy dispersive X-ray analysis showed the stoichiometry of the alloys. The magnetization as a function of field and temperature of the alloys, measured using a superconducting quantum interference device, showed superparamagnetic behavior with negligible coercivity and remanence values. 相似文献