Synthesis, morphology and random laser action of ZnO nanostructures

Three-dimensional (3-D) ZnO random-wall nanostructures and one-dimensional (1-D) ZnO nanorods were prepared on silicon substrates by a simple solid-vapour phase thermal sublimation technique. Optical pumped random lasing has been observed in the ZnO random-wall arrays with a threshold intensity of 0.38 MW/cm² in the emission wavelength from 380 to 395 nm. The optical gain was attributed to the closed-loop scattering and light amplification of the ZnO random-wall. The experimental result suggests that the morphology of nanostructure is the key factor to effect random lasing.     

Implementation and experimental study on fast object modeling based on multiple structured stripes

In this paper, a practical structured light-based system for fast object modeling and reconstruction is reported. The system consists of an off-the-shelf digital projector, a video camera and a turntable. The system calibration is implemented accurately and automatically by taking a single image of an illuminated calibration template. The multiple color light stripes emitted by the projector adopt only three colors and the color can be modified easily according to the surface texture of the object. This makes the system widely applicable in many situations, and the assumption about color neutrality, which is a limitation to other similar systems, can be largely relaxed. The registration and merging algorithm is greatly simplified by employing a turntable. The validity and high accuracy of the method are demonstrated by extensive real experiments.     

MgO films grown on yttria-stabilized zirconia by molecular beam epitaxy

MgO films were grown on (0 0 1) yttria-stabilized zirconia (YSZ) substrates by molecular beam epitaxy (MBE). The crystalline structures of these films were investigated using X-ray diffraction and transmission electron microscopy. Growth temperature was varied from 350 to 550 °C, with crystalline quality being improved at higher temperatures. The MgO films had a domain structure: (1 1 1)[1 1 2¯]_MgO(0 0 1)[1 0 0]_YSZ with four twin variants related by a 90° in-plane rotation about the [1 1 1]_MgO axis. The observed epitaxial orientation was compared to previous reports of films grown by pulsed laser deposition and sputtering and explained as resulting in the lowest interface energy.     

Geometry and electronic structure of a heterometallic cluster Mo<Subscript>2</Subscript>Mg<Subscript>2</Subscript> in different oxidation states of Mo: a DFT study

Reduction of tetranuclear heterometallic complex Mo₂Mg₂ was simulated using the B3LYP and PBE density functional methods. The results of geometry calculations of the initial complex [Mo^VIO₂Mg(MeOH)₂(OMe)₄]₂ and a partially reduced Mo^V complex are in good agreement with experimental data. The reduced Mo^III complex is characterized by a decrease in the binding energy of aqua ligands. Structural rearrangement of the complex with release of a coordination position at the Mo atoms requires small energy expenditure. One can assume that the reduction of the polynuclear complex causes overcrowding of its coordination sphere, which favors formation of dinitrogen complexes. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 441–457, March, 2008.     

Extensions of Banach Lie-Poisson spaces

The extension of Banach Lie-Poisson spaces is studied and linked to the extension of a special class of Banach Lie algebras. The case of W∗-algebras is given particular attention. Semidirect products and the extension of the restricted Banach Lie-Poisson space by the Banach Lie-Poisson space of compact operators are given as examples.     

Small zeros of quadratic forms with linear conditions

Given a quadratic form and M linear forms in N+1 variables with coefficients in a number field K, suppose that there exists a point in K^N+1 at which the quadratic form vanishes and all the linear forms do not. Then we show that there exists a point like this of relatively small height. This generalizes a result of D.W. Masser.     

Equilibrated thermodesorption studies of adsorption of n-hexane and n-heptane on zeolites Y, ZSM-5 and ZSM-11

Gravimetric measurements of thermodesorption of n-hexane and n-heptane were performed under quasi-equilibrium conditions. Differential thermodesorption profiles for ZSM-5 and ZSM-11 showed two peaks, but for Y zeolites, only one thermodesorption peak was observed. A model function, derived from the Langmiur adsorption model, was fitted to the experimental data, and the model parameters (the adsorption entropy and enthalpy) were estimated. The two-step desorption profiles observed for ZSM-5 and ZSM-11 were attributed to the commensurate freezing effect, i.e. a transition in the adsorbed phase resulting in ordering of the adsorbed molecules in the zeolite channels. The results observed for ZSM-11 indicate that the zigzag channels typical for ZSM-5 micropore system are not necessary for this transition to occur.     

基于可靠性的相位去包裹算法

提出了一种新的基于可靠性的相位去包裹算法。采用了队列算法及去包裹可靠性的判别标准。与传统方法相比,能够自动避开噪声区域,解决了相位去包裹中的阴影遮挡以及空洞等问题,克服了传统去包裹方法中的误差传播效应,能准确快速地对全场进行相位去包裹。设计了一套基于此算法的三维形面测量系统。     

Ab initio X-ray powder diffraction characterisation of molecule-based magnetic materials

Use of ab initio X-ray powder diffraction (XRPD) methods in the study of magnetically active species of covalent nature is presented. Selected cases are chosen in order to underline the power of XRPD methodologies, highlighting the importance of independent physico-chemical information from ancillary techniques.