Palladium catalyzed mild reduction of α,β-unsaturated compounds by triethylsilane

The palladium(II) chloride/triethylsilane system has been successfully applied for the selective hydrogenation of the carbon-carbon double bond of α,β-unsaturated ketones to yield the corresponding saturated carbonyl compounds. The reaction takes place under mild conditions and affords high yields.     

Regular variation of order 1 nonlinear AR-ARCH models

We prove both geometric ergodicity and regular variation of the stationary distribution for a class of nonlinear stochastic recursions that includes nonlinear AR-ARCH models of order 1. The Lyapounov exponent for the model, the index of regular variation and the spectral measure for the regular variation all are characterized by a simple two-state Markov chain.     

A non-isothermal Ginzburg–Landau model in superconductivity: Existence,uniqueness and asymptotic behaviour

In this paper we study a Ginzburg–Landau model which describes the behaviour of a superconducting material including thermal effects. We extend the traditional formulation of the problem, by introducing the temperature as an additional state variable. Accordingly, together with the Gor’kov–Eliashberg system, we introduce an evolution equation for the absolute temperature. We examine in detail the case which allows only variations of the concentration of superconducting electrons and of the temperature, neglecting the electromagnetic field. For this problem existence and uniqueness of the solution are shown. Finally we analyze the asymptotic behaviour of the solutions, proving that the system possesses a global attractor.     

Another independent self-dual basis for the trivial variety

We give a new independent self-dual 3-basis for the trivial variety with two binary operations. Received October 24, 2006; accepted in final form January 25, 2007.     

The essential Lagrangian-Grassmannian and the homotopy type of the Fredholm Lagrangian-Grassmannian

Let H be a separable infinite dimensional Hilbert space endowed with a symplectic structure and let L₀⊂H be a Lagrangian subspace. Using the results of [A. Abbondandolo, P. Majer, Infinite dimensional Grassmannians, math.AT/0307192], we show that the Fredholm Lagrangian-Grassmannian FL₀(Λ) has the homotopy type of Gc(L₀), the Grassmannian of all Lagrangian subspaces of H that are compact perturbations of L₀. It is well known that the latter has the homotopy type of the quotient U(∞)/O(∞). As a corollary, we recover a result by B. Booss-Bavnbek and K. Furutani (see [B. Booss-Bavnbek, K. Furutani, Symplectic functional analysis and spectral invariants, Contemp. Math. 242 (1999) 53-83; K. Furutani, Fredholm-Lagrangian-Grassmannian and the Maslov index, J. Geom. Phys. 51 (2004) 269-331]) that the L₀-Maslov index is an isomorphism between the fundamental group of FL₀(Λ) and the integers.     

Electronic structure and vibrational spectra of cis-diammine(orotato)platinum(II), a potential cisplatin analogue: DFT and experimental study

Orotic acid (vitamin B₁₃) is a key intermediate in biosynthesis of the pyrimidine nucleotides in living organisms, moreover, it may serve as the biological carrier for some metal ions. cis-Diammine(orotato)platinum(II), cis-[Pt(C₅H₂N₂O₄)(NH₃)₂] can be considered as a new potential cisplatin analogue. The FT-Raman and FT-IR spectra of the title complex are reported, for the first time. The molecular structure, vibrational frequencies, and the theoretical infrared and Raman intensities have been calculated by the density functional mPW1PW91 method. The detailed vibrational assignment has been made on the basis of the calculated potential energy distribution. The theoretically predicted IR and Raman spectra show very good agreement with experiment. Natural bond orbital (NBO) analyses were performed for cisplatin, carboplatin and the title complex. The results provided new data on the nature of platinum–ligand bonding in these compounds. Strong intramolecular hydrogen bond between the orotate ligand and the coordinated ammonia group stabilizes the structure of the platinum(II) complex. Thus, it is suggested that the orotate ligand in the title complex is more inert to the substitution reactions than the chloride ligands in cisplatin.     

On perfectly normal dense subspaces of products

Let M be a separable metric space consisting of more than one point. We construct perfectly normal dense subspaces Z⊂Mc² and (under additional set-theoretic assumption) Y⊂Mc which are not collectionwise Hausdorff.