全文获取类型
收费全文 | 1714篇 |
免费 | 207篇 |
国内免费 | 101篇 |
专业分类
化学 | 493篇 |
晶体学 | 1篇 |
力学 | 131篇 |
综合类 | 87篇 |
数学 | 547篇 |
物理学 | 763篇 |
出版年
2024年 | 6篇 |
2023年 | 37篇 |
2022年 | 144篇 |
2021年 | 185篇 |
2020年 | 94篇 |
2019年 | 75篇 |
2018年 | 49篇 |
2017年 | 93篇 |
2016年 | 113篇 |
2015年 | 69篇 |
2014年 | 125篇 |
2013年 | 96篇 |
2012年 | 100篇 |
2011年 | 102篇 |
2010年 | 89篇 |
2009年 | 93篇 |
2008年 | 94篇 |
2007年 | 93篇 |
2006年 | 71篇 |
2005年 | 59篇 |
2004年 | 34篇 |
2003年 | 29篇 |
2002年 | 13篇 |
2001年 | 18篇 |
2000年 | 17篇 |
1999年 | 11篇 |
1998年 | 16篇 |
1997年 | 14篇 |
1996年 | 17篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 1篇 |
1980年 | 3篇 |
1978年 | 2篇 |
1967年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有2022条查询结果,搜索用时 31 毫秒
31.
32.
33.
Simple matching vs linear assignment in scheduling models with positional effects: A critical review
This paper addresses scheduling models in which a contribution of an individual job to the objective function is represented by the product of its processing time and a certain positional weight. We review most of the known results in the area and demonstrate that a linear assignment algorithm as part of previously known solution procedures can be replaced by a faster matching algorithm that minimizes a linear form over permutations. Our approach reduces the running time of the resulting algorithms by up to two orders, and carries over to a wider range of models, with more general positional effects. Besides, the same approach works for the models with no prior history of study, e.g., parallel machine scheduling with deterioration and maintenance to minimize total flow time. 相似文献
34.
《International journal of quantum chemistry》2018,118(2)
We investigate the success of the quantum chemical electron impact mass spectrum (QCEIMS) method in predicting the electron impact mass spectra of a diverse test set of 61 small molecules selected to be representative of common fragmentations and reactions in electron impact mass spectra. Comparison with experimental spectra is performed using the standard matching algorithms, and the relative ranking position of the actual molecule matching the spectra within the NIST‐11 library is examined. We find that the correct spectrum is ranked in the top two matches from structural isomers in more than 50% of the cases. QCEIMS, thus, reproduces the distribution of peaks sufficiently well to identify the compounds, with the RMSD and mean absolute difference between appropriately normalized predicted and experimental spectra being at most 9% and 3% respectively, even though the most intense peaks are often qualitatively poorly reproduced. We also compare the QCEIMS method to competitive fragmentation modeling for electron ionization, a training‐based mass spectrum prediction method, and remarkably we find the QCEIMS performs equivalently or better. We conclude that QCEIMS will be very useful for those who wish to identify new compounds which are not well represented in the mass spectral databases. 相似文献
35.
Soo Chung Christian M. Jennings Prof. Jeong-Yeol Yoon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(57):13070-13077
In recent years, there has been high interest in paper-based microfluidic sensors or microfluidic paper-based analytical devices (μPADs) towards low-cost, portable, and easy-to-use sensing for chemical and biological targets. μPAD allows spontaneous liquid flow without any external or internal pumping, as well as an innate filtration capability. Although both optical (colorimetric and fluorescent) and electrochemical detection have been demonstrated on μPADs, several limitations still remain, such as the need for additional equipment, vulnerability to ambient lighting perturbation, and inferior sensitivity. Herein, alternative detection methods on μPADs are reviewed to resolve these issues, including relatively well studied distance-based measurements and the newer capillary flow dynamics-based method. Detection principles, assay performance, strengths, and weaknesses are explained for these methods, along with their potential future applications towards point-of-care medical diagnostics and other field-based applications. 相似文献
36.
《Journal of computational chemistry》2017,38(13):1005-1014
The fully polarizable, multipolar, and atomistic force field protein FFLUX is being built from machine learning (i.e., kriging) models, each of which predicts an atomic property. Each atom of a given protein geometry needs to be assigned such a kriging model. Such a knowledgeable atom needs to be informed about a sufficiently large environment around it. The resulting complexity can be tackled by collecting the 20 natural amino acids into a few groups. Using substituted deca‐alanines, we present the proof‐of‐concept that a given atom's charge can be modeled by a few kriging models only. © 2017 Wiley Periodicals, Inc. 相似文献
37.
Chengzhen Hu Wendong Jia Yao Liu Dr. Yuqin Wang Dr. Panke Zhang Prof. Hong-Yuan Chen Prof. Shuo Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(44):e202201033
Acidic catecholamine metabolites, which could serve as diagnostic markers for many diseases, demonstrate an importance of accurate sensing. However, they share a highly similar chemical structure, which is a challenge in the design of sensing strategies. A nanopore may be engineered to sense these metabolites in a single molecule manner. To achieve this, a recently developed programmable nano-reactor for stochastic sensing (PNRSS) technique adapted with a phenylboronic acid (PBA) adaptor was applied. Three acidic catecholamine metabolites, including 3,4-dihydroxyphenylacetic acid (DOPAC), 3,4-dihydroxymandelic acid (DHMA) and 3-methoxy-4-hydroxymandetic acid (VMA) were investigated by PNRSS. Specifically, DHMA, which contains an α-hydroxycarboxylate moiety and an adjacent cis-hydroxyl groups on its benzene ring, reports two binding modes simultaneously resolvable by PNRSS. Assisted with the high resolution of PNRSS, direct regulation of these two binding modes by pH can also be observed. A custom machine learning algorithm was also developed to achieve automatic event classification. 相似文献
38.
针对土壤定量分析受基体效应影响大,LIBS定量分析精度不佳等问题,采用粒子群算法对LSSVM进行优化,提高模型的精确度。选取Pb Ⅰ 405.78 nm和Cr Ⅰ 425.44 nm作为分析谱线进行分析。采集十二个不同浓度样品的特征光谱,每个浓度样品在不同点采集20组数据,将其中17组数据设为训练集,3组数据设为预测集,用LSSVM和PSO-LSSVM两种方法建立定标模型。对比两种模型的拟合相关系数(R2)、训练集均方根误差(RMSEC)和预测集均方根误差(RMSEP)。由于自吸收效应的影响,随着浓度的增加,预测值逐渐低于实际值,LSSVM定标模型的拟合程度较低,无法达到实验要求,模型性能有待提高。利用粒子群算法对LSSVM的模型参数惩罚系数和核函数参数进行优化,得到最佳的参数组合,Pb元素为(8 096.8, 138.865 7),Cr元素为(4 908.6, 393.563 5),用最佳的参数组合构建LSSVM的定标模型。相比于LSSVM,PSO-LSSVM定标模型的精确度更高,Pb和Cr元素的R2提高到了0.982 8和0.985 0,拟合效果明显提升。Pb和Cr元素的训练集均方根误差由0.026 0 Wt%和0.027 2 Wt%下降到0.022 4 Wt%和0.019 1 Wt%,预测集均方根误差由0.101 8 Wt%和0.078 8 Wt% 下降到0.045 8 Wt%和0.042 0 Wt%,模型的稳定性进一步提高。说明PSO-LSSVM算法能够更好地降低土壤基体效应和自吸收效应带来的影响,提高分析结果的精确度与稳定性。 相似文献
39.
Two criteria in a combinatorial problem are often combined in a weighted sum objective using a weighting parameter between 0 and 1. For special problem types, e.g., when one of the criteria is a bottleneck value, efficient algorithms are known that solve for a given value of the weighting parameter. 相似文献
40.
缆机是大坝浇筑过程中的主要运输设备之一,缆机驾驶员操作水平直接关系缆机起重作业安全.为有效提高缆机起重作业驾驶员操作行为可靠性,预防起重作业安全事故,针对缆机起重作业周期性多维运动的特点,分解驾驶员操作流程;剖析操作行为失误,建立驾驶员行为模式;从时间角度量化操作流程,计算缆机驾驶员操作行为响应失误概率;构建操作行为可靠性分析模型,定量表达操作行为可靠性,分析人因失误对缆机起重作业安全事故的影响.结果表明,吊具与吊罐对接、混凝土卸料等作业过程的缆机驾驶员操作行为可靠性低,需加强安全培训,严格考核制度,从根本上提高缆机驾驶员操作行为的可靠性,以期提升缆机生产效率,实现预防安全事故的目标. 相似文献