探索物质微观结构的历史回顾——纪念夸克提出50周年

1964年盖尔曼和兹威格分别提出“基本粒子”由夸克或艾斯组成。至今,这一领域仍是粒子物理研究的前沿领域。经过50年的发展,夸克(艾斯)理论取得诸多辉煌成就。文章简要地回顾了夸克的提出过程及随后实验和理论方面的进展。     

量子频标中的原子物理

频率是自然界中测量得最准的物理量.量子频标是频率的测量标准,它是利用原子跃迁谱线的稳定而准确的频率作为参考频率.频标研究中存在几乎所有的原子物理问题,如原子结构与光谱、原子与电磁场的相互作用以及原子碰撞等问题值得深入研究.本文就量子频标的基本原理和应用,量子频标中存在的原子物理问题做以简要评述.     

Reflection absorption infrared spectroscopy during atomic layer deposition of HfO2 films from tetrakis(ethylmethylamido)hafnium and water

Tetrakis(ethylmethylamido)hafnium and water are commonly used precursors for atomic layer deposition of HfO₂. Using reflection absorption infrared spectroscopy with a buried-metal-layer substrate, we probe surface species present during typical deposition conditions. We observe evidence for thermal decomposition of alkylamido ligands at 320 °C. Additionally, we find that complete saturation of the SiO₂ substrate occurs in the first cycle at ≈100 °C whereas incomplete coverage is apparent even after many cycles at higher temperatures. The use of this technique as an in situ diagnostic useful for process optimization is demonstrated.     

中国医学物理学的过去、现在与未来

医学物理（medical physics，MP）是把物理学的原理和方法应用于人类疾病的预防、诊断、治疗和保健的一门交叉学科，是物理学与医学实践相结合的一门独立的分支学科．它是研究人类疾病诊、治过程中的物理现象，并用物理方法表达这种现象．医学物理包括放射肿瘤物理（rsdiation oncdogy physics，ROP）、医学影像物理（medical imaong physics，MIP）、核医学物理（nuclear medicine physics，NMP），其他非电离辐射如核磁、超声、微波、射频、激光等物理因子在医学中的应用，和保健物理（heath physics，HP）等分支内容．医学物理学和生物医学工程学（biomedical engineefing，BME）是一对栾生的兄弟学科，分别从物理学的角度（前者）和工程学的角度（后者）研究人类疾病诊断、治疗及健康保健过程中的生命现象和采取相应的物理措施和工程手段。医学物理学与物理医学（physical medicine，PM）是完全两个不同的概念，前者是物理学的分支，后者是医学的分支．自上世纪60年代以来，中国医学物理学有了很大的进展，推动了中国现代放射肿瘤学、核医学和医学影像学的发展；成立了自己的学术组织，并成为国际医学物理组织（IOMP）的成员国组织．随着中国逐步奔入小康社会，为适应人民大众对健康的需求和现代化医院发展的需要，中国医学物理应该加快发展．     

原子吸收光谱法间接测定钼精矿中钼的研究

对于钼精矿中钼的测定,标准方法采用钼酸铅重量法,该方法需要将钼酸铅沉淀反复多次洗涤、过滤,以保证沉淀物中夹带的铅离子洗涤完全,再对沉淀物进行灰化、灼烧等多步操作,步骤较繁琐,分析费时,不能快速配合选矿、冶金的科学研究。应用原子吸收光谱法间接测定钼,建立了钼精矿中钼的快速分析方法。钼精矿样品经硝酸、氯酸钾、硫酸加热溶解后,用酚酞和盐酸调节pH值,加入乙酸-乙酸铵缓冲溶液调节pH值至5～7,再加入一定量且过量的铅标准溶液。基于在室温下,钼酸铅为难溶电解质,难溶电解质在一定温度下能否沉淀完全,通常比较离子积Q_c与溶度积常数K_sp的相对大小,当Q_c>K_sp,溶液过饱和,沉淀物完全析出,钼精矿中钼的含量为40～60%,铅的加入量为0.125 0～0.150 0 g,取最小值计算出溶液中钼酸铅的离子积,Q_c＝[Pb2+][MoO2-₄]=2.51×10-5,K_sp＝1.0×10-13,Q_cK_sp,因此钼酸铅沉淀可以完全析出,待钼酸铅沉淀完全后干过滤,用原子吸收光谱法测定滤液中过量的铅离子,用差减法计算得出钼精矿中钼的含量。文中分别考察了乙酸-乙酸铵缓冲溶液的加入量及其浓度、铅标准溶液的加入量、钼酸铅沉淀完全的时间、加热时间以及常见共存离子如W6+,Sn4+和Cu2+等的最大允许量诸多因素对原子吸收光谱法间接测定钼的影响。与钼酸铅重量法相比,该方法省去了对钼酸铅沉淀反复多次的洗涤、灰化以及灼烧等步骤,操作简便易掌握,分析时间缩短一半,并用钼酸铅重量法与本方法进行对照实验,分析结果进行数理统计,得出结论：本方法具有很好的准确度和精密度,可用于选矿、冶金钼精矿样品中钼的快速分析检测。     

Semiclassical information from deformed and escort information measures

Escort distributions are a well established but (for physicists) a relatively new concept that is rapidly gaining wide acceptance in world. In this work we wish to revisit the concept within the strictures of the celebrated semiclassical Husimi distributions (HDs) and thereby investigate the possibility of extracting new semiclassical information contained, not in the HD themselves, but in their associated escort Husimi distributions. We will also establish relations, for various information measures, between their deformed versions [J. Naudts, Physica A 316 (2002) 323] and those built up with escort HDs. Bounds on the concomitant power exponents will be determined.     

悬浮液进样-原子吸收光谱法测定核桃粉中的钙、铁和锌

采用悬浮液进样技术应用于原子吸收光谱法,测定了核桃粉中的钙、铁和锌的含量.将核桃粉悬浮于琼脂胶体中制成悬浮液,直接喷入空气-乙炔火焰,用标准加入法测定,将实验结果与灰化法结果进行了比较,经t检验,在显著性水平a=0.05时两种方法无显著性差异,相对标准偏差≤6.1%,结果吻合较好.该方法简便,快速,灵敏度高,准确性好.     

Thermal stability of alkoxy monolayers grafted on Si(1 1 1)

Direct grafting of organic monolayers on Si is of prime interest in order to give specific properties to a silicon surface. However, for microelectronics applications, this possibility is hampered by the limited stability of the grafted layers. It has been previously established that alkyl layers attached to Si surfaces through Si-C bonds become unstable at 250-300 °C, by desorption of alkenes. Changing the nature of the bonding to the surface might allow one to circumvent this desorption pathway and increase the layer stability. In our work, decanol and decyl aldehyde are reacted with the Si(1 1 1)-H surface at ∼100 °C during 20 h in order to obtain alkoxy monolayers. FTIR measurements performed in ATR geometry show that the grafted molecule surface coverage is on the order of 33% after reaction with decanol and 50% after reaction with decyl aldehyde. Characterization by AFM essentially reveals that the morphology of the grafted surfaces is unaffected as compared to that of Si-H surfaces. However, the edges of the terraces at alcohol-grafted surfaces exhibit some pitting, probably due to the presence of water in the grafting liquid. Thermal stability studies show that alkoxy chains progressively disappear from the Si surface between 200 and 400 °C. From the CH₂/CH₃ ratio in the CH region (2760-3070 cm⁻¹), it appears that the chains undergo progressive dissociation by C-C bond breaking before their complete disappearance from the surface. Therefore, the thermal behaviour of alkoxy monolayers appears quite distinct from that of alkyl monolayers that tend to leave the surface in a much narrower temperature range (250-350 °C), essentially via breaking of the Si-C bonds.     

大学物理实验课程建设的研究与实践

结合课程建设的实践,阐述了吉林大学大学物理实验分层次教学的课程体系,“层次化、自主化、研究化”的教学理念,教学团队的建设思路.构建本科生公共物理创新实践平台的实施措施及所取得的成效,介绍了网络教学与管理平台的构架及课程未来的建设目标.     

A Simple Relation between Line Shifts and Atomic Parameters

A comprehensive study of Xe II line shifts (after considering more than 900 transitions) provides the basis for establishing a simple empirical linear relation between the shifts and the inverse of the ionization potential for the er level.