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51.
针对正交频分复用水声移动通信中频域变采样技术联合信道稀疏度检测的多普勒估计算法在冰水混合区复杂信道环境下多普勒估计效果欠佳且计算量大的问题,提出了一种改进的多普勒估计算法。采用时域重采样技术对信号进行不同压缩因子的补偿,避免了频域变采样技术中的高阶快速傅里叶变换运算,从而降低了算法复杂度。利用梳状导频位置向量结合时域变采样技术更准确提取的导频子载波,进而获得更加精确的信道估计和信道稀疏度检测结果,提高了多普勒估计精度。仿真结果和冰下试验结果表明,与原始算法相比,改进的方法在冰水混合水域复杂多径时变信道环境下可以有效实现对信号多普勒畸变的跟踪并且计算量显著下降,能够保障正交频分复用水声移动实时通信。 相似文献
52.
圆合成孔径声呐(CSAS)的成像性能受平台运动误差影响而下降,利用单侧回波可估计CSAS基阵的斜距误差,但单侧回波在小测绘带时无法估计升沉误差,针对此问题,提出了一种利用单侧回波信号的声呐平台三维运动估计和补偿方法。首先,对CSAS在不同观测角度的目标回波取极大值获得目标回波的到达时间;其次,基于多个点目标的到达时间建立CSAS三维定位模型;然后利用列文伯格-马夸尔特方法对声呐三维坐标进行估计;最后将位置估计结果与时域反投影成像方法结合实现对目标的成像.仿真结果表明:该方法能精确估计声呐平台运动误差,其空间坐标的估计误差小于仿真信号波长的1/8,从而精确补偿了CSAS在不同空间采样点上的阵元回波时间差,显著提高了目标成像质量。湖上试验结果表明,该算法能够实现对CSAS的运动误差补偿。仿真和试验结果均验证了方法的可行性和有效性。 相似文献
53.
由于同轴电缆的低通传输特性,脉冲信号在同轴电缆中传输时不可避免地会出现畸变,并且畸变程度会随着脉冲信号频率、带宽以及传输距离的增加而增大。创新性地将图像处理领域中的一种图像复原方法——维纳滤波法应用于脉冲信号同轴电缆传输畸变补偿,仅利用同轴电缆的S参数和输出信号即可完成输入信号的重构。并以10 m同轴电缆为对象,采用该方法分别对双指数脉冲信号、高斯调制脉冲信号、调制方波信号进行传输畸变补偿。结果表明:对于不同样式的信号,该方法均具有优异的补偿性能;并且,与工程上常用的衰减补偿法相比,该方法不仅补偿精度高,还具有高的计算效率,在同轴电缆脉冲信号传输畸变补偿中具有很好的实用价值。 相似文献
54.
55.
A picosecond widely tunable deep-ultraviolet laser for angle-resolved photoemission spectroscopy
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We develop a picosecond widely tunable laser in a deep-ultraviolet region from 175 nm to 210 nm,generated by two stages of frequency doubling of a 80-MHz mode-locked picosecond Ti:sapphire laser.A β-BaB2O4 walk-off compensation configuration and a KBe2BO3F2 prism-coupled device are adopted for the generation of second harmonic and fourth harmonics,respectively.The highest power is 3.72 mW at 193 nm,and the fluctuation at 2.85 mW in 130 min is less than ±2%. 相似文献
56.
Combining the experimental research with the simulation calculation, the error evaluation for Zernike polynomials fitting (ZPF) based phase compensation of digital holographic microscopy (DHM) is performed. The obtained results show that the reconstructed phase with high precision can be obtained by ZPF phase compensation algorithm. Moreover, the phase error for ZPF based phase compensation algorithm increases with both the variation of object height and object transverse area, the larger variation of object height, the larger of phase error, and the larger of object transverse area, the faster increase of RMS phase error. To decrease the error of ZPF phase compensation algorithm, it is required to ensure one of the variations of object height and object transverse area to be a small value. Importantly, the proposed method supplies a useful tool for the error evaluation of phase compensation algorithm. 相似文献
57.
《高分子科学杂志,C辑:聚合物评论》2013,53(2):99-124
Thermally stimulated recovery (TSR) is a non‐conventional mechanical spectroscopy technique that allows to analyse in detail the relaxation processes of polymeric systems in the low frequency region. This work reviews the main aspects and potentialities of this technique. The different kinds of TSR experiments that can be performed, global and thermal sampling (TS) experiments, are described and illustrated with several examples. Also, the different methods for the determination of the thermokinetic parameters (activation energy and pre‐exponential factor) of the thermal sampling (TS) procedure are explained and compared. In this context, the compensation phenomenon, which always appears in TSR results when the studies are performed in the glass transition region of a given system, is discussed. Examples of the application of this technique to different polymeric systems during the last 20 years are provided. An emphasis will be made on the analysis of the effect of crystallinity degree and crosslink density on the TSR response. A comparison between the results (characteristic times and activation energies) obtained by different techniques, namely TSR, dynamic mechanical analysis (DMA), and differential scanning calorimetry (DSC), is made. 相似文献
58.
The synthesis and characterization of five homologous series of symmetrical compounds composed of banana-shaped molecules containing a biphenyl moiety are reported. All these compounds are non-Schiff's bases and are esters. The effects of lateral substituents such as fluoro, methyl and ethyl in the side arms of these molecules are examined. These substituents have a strong influence in reducing the clearing temperatures. Banana phases such as B1, B2 and B6 were observed in the above series of compounds. The mesophases were characterized by a combination of polarizing optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optic studies. 相似文献
59.
Thibault Dutronc Dr. Emmanuel Terazzi Dr. Laure Guénée Kerry‐Lee Buchwalder Aurore Spoerri Dr. Daniel Emery Dr. Jiri Mareda Dr. Sébastien Floquet Prof. Claude Piguet 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(26):8447-8456
This work illustrates how minor structural perturbations produced by methylation of 4′‐(dodecyloxy)‐4‐cyanobiphenyl leads to enthalpy–entropy compensation for their melting processes, a trend which can be analyzed within the frame of a simple intermolecular cohesive model. The transformation of the melting thermodynamic parameters collected at variable temperatures into cohesive free‐energy densities expressed at a common reference temperature results in a novel linear correlation, from which melting temperatures can be simply predicted from molecular volumes. 相似文献
60.
HU Hao 《中国科学:化学(英文版)》2014,57(1):156-164
The origin of the catalytic power of enzymes with a meta-stable native state,e.g.molten globular state,is an unsolved challenging issue in biochemistry.To help understand the possible differences between this special class of enzymes and the typical ones,we report here computer simulations of the catalysis of both the well-folded wild-type and the molten globular mutant of chorismate mutase.Using the ab initio quantum mechanical/molecular mechanical minimum free-energy path method,we determined the height of reaction barriers that are in good agreement with experimental measurements.Enzyme-substrate interactions were analyzed in detail to identify factors contributing to catalysis.Computed angular order parameters of backbone N–H bonds and side-chain methyl groups suggested site-specific,non-uniform rigidity changes of the enzymes during catalysis.The change of conformational entropy from the ground state to the transition state revealed distinctly contrasting entropy/enthalpy compensations in the dimeric wild-type enzyme and its molten globular monomeric variant.A unique catalytic strategy was suggested for enzymes that are natively molten globules:some may possess large conformational flexibility to provide strong electrostatic interactions to stabilize the transition state of the substrate and compensate for the entropy loss in the transition state.The equilibrium conformational dynamics in the reactant state were analyzed to quantify their contributions to the structural transitions enzymes needed to reach the transition states.The results suggest that large-scale conformational dynamics make important catalytic contributions to sampling conformational regions in favor of binding the transition state of substrate. 相似文献