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71.
Rachelle S. Jacobson Andrew R. Korte Akos Vertes J. Houston Miller 《Angewandte Chemie (International ed. in English)》2020,59(11):4484-4490
Soot (sometimes referred to as black carbon) is produced when hydrocarbon fuels are burned. Our hypothesis is that polynuclear aromatic hydrocarbon (PAH) molecules are the dominant component of soot, with individual PAH molecules forming ordered stacks that agglomerate into primary particles (PP). Here we show that the PAH composition of soot can be exactly determined and spatially resolved by low‐fluence laser desorption ionization, coupled with high‐resolution mass spectrometry imaging. This analysis revealed that PAHs of 239–838 Da, containing few oxygenated species, comprise the soot observed in an ethylene diffusion flame. As informed by chemical graph theory (CGT), the vast majority of species observed in the sampled particulate matter may be described as benzenoids, consisting of only fused 6‐membered rings. Within that limit, there is clear evidence for the presence of radical PAH in the particulate samples. Further, for benzenoid structures the observed empirical formulae limit the observed isomers to those which are nearly circular with high aromatic conjugation lengths for a given aromatic ring count. These results stand in contrast to recent reports that suggest higher aliphatic composition of primary particles. 相似文献
72.
Chengfei Wang Xiaowei Li Ziquan Lv Yingyu Wang Yuebin Ke Xi Xia 《Journal of separation science》2020,43(12):2321-2329
A rapid and reliable method for the detection of five carbapenems (biapenem, imipenem, doripenem, meropenem, and faropenem) in water was developed and validated. After acidification of water samples with acetic acid, carbapenems were isolated using a Bond Elut PPL cartridge. The target compounds were separated using ultra high performance liquid chromatography with a chromatographic run time of 5 min and detected on a triple quadrupole mass spectrometer operated in positive electrospray ionization and multiple reaction monitoring mode. Mean recoveries were in the range of 76.6–106.5%, with satisfactory intraday and interday relative standard deviations lower than 10.0 and 10.8%, respectively. The limits of detection and quantification were in the ranges of 0.05–0.2 µg/L and 0.1–0.5 µg/L, respectively, depending on the analyte. The proposed method was applied to the analysis of river samples and wastewater samples from swine farms, and no carbapenems were detected in the collected samples. 相似文献
73.
Xigao Jin Yi Shi Li Yao Liusheng Chen Jianrong Feng Mitchell A. Winnik 《Journal of polymer science. Part A, Polymer chemistry》1996,34(10):2045-2049
Pyrolysis–GC/mass spectrometry experiments reveal that naphthalene groups attached to maleated polyethylene as the 1-naphthylethyl ester are stable for relatively long periods of time at 170°C. Decomposition can be detected for samples heated for 2.0 min at 200°C, but even at that temperature, the extent of decomposition is very small. At higher temperatures, two of the decomposition products from the labeled polymer are readily understood: 1-vinylnaphthalene and 1-naphthylethanol can form by reactions that are well-precedented in the organic chemistry literature. At 200°C, only naphthalene is formed, which requires scission of the bond between the naphthyl ring and the C1 carbon of the ethyl group. We suggest two possible pathways for this reaction. © 1996 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 34:2045–2049, 1996 相似文献
74.
75.
The analysis of volatile compounds, and particularly of certain hydrocarbons, e.g. pentane, and some aldehydes, e.g. hexanal, has been used to estimate the degree of oxidation of vegetable oil. We have tested a dynamic headspace technique without heating the sample during the purge time of the analysis. Some tests have been performed after heating the sample at 180°C for a specified time before the analysis, to compare the results of analysis with and without heating. The best results were obtained at room temperature. 相似文献
76.
William R. Cullen Hao Li Spiros A. Pergantis Guenter K. Eigendorf Andrew A. Mosi 《应用有机金属化学》1995,9(7):507-515
The microorganism Apiotrichum humicola (previously known as Candida humicola) grown in the presence of either arsenate, arsenite, methylarsonic acid or dimethylarsinic acid, produces arsenic-containing metabolites in the growth medium. When L-methionine-methyl-d3 is added to the cultures, the CD3 label is incorporated intact into the metabolites to a considerable extent to form deuterated dimethylarsenic and trimethyl-arsenic species, indicating that S-adenosylmethionine, or some related sulphonium compound, is involved in the biological methylation. Conclusive evidence of CD3 incorporation in the arsenicals found in the growth medium was provided by using a specially developed hydride generation-gas chromatography-mass spectrometry system (HG–GC–MS). 相似文献
77.
The application of the combination of gas chromatography and a self-developed plasma emission detector for organomercury speciation is presented. The system, basing on interference filter technology, is described briefly. The plasma and the optical system have to be optimized to reach highest sensitivity for mercury detection. Dimethyl-, methyl- and inorganic mercury as selected compounds have been separated on a GC column and calibrated to obtain the analytical performance data of the system used. Finally, the analysis of some real samples has been performed. 相似文献
78.
Philippe Savarino Emmanuel Colson Guillaume Caulier Igor Eeckhaut Patrick Flammang Pascal Gerbaux 《Molecules (Basel, Switzerland)》2022,27(2)
Saponins are plant and marine animal specific metabolites that are commonly considered as molecular vectors for chemical defenses against unicellular and pluricellular organisms. Their toxicity is attributed to their membranolytic properties. Modifying the molecular structures of saponins by quantitative and selective chemical reactions is increasingly considered to tune the biological properties of these molecules (i) to prepare congeners with specific activities for biomedical applications and (ii) to afford experimental data related to their structure–activity relationship. In the present study, we focused on the sulfated saponins contained in the viscera of Holothuria scabra, a sea cucumber present in the Indian Ocean and abundantly consumed on the Asian food market. Using mass spectrometry, we first qualitatively and quantitatively assessed the saponin content within the viscera of H. scabra. We detected 26 sulfated saponins presenting 5 different elemental compositions. Microwave activation under alkaline conditions in aqueous solutions was developed and optimized to quantitatively and specifically induce the desulfation of the natural saponins, by a specific loss of H2SO4. By comparing the hemolytic activities of the natural and desulfated extracts, we clearly identified the sulfate function as highly responsible for the saponin toxicity. 相似文献
79.
电感耦合等离子体发射光谱法定量测试明胶中的微量金属元素Hg和Rh--应用MSF模型改进Hg结果的精密度和检测限 总被引:3,自引:0,他引:3
应用电感耦合等离子体发射光谱技术,建立了定量测试明胶中微量金属元素Hg和Rh的方法。采用湿法消解对明胶样品进行前处理。讨论了ICP-AES同时测定明胶中微量金属元素Hg和Rh时,应用MSF模型校正对汞的光谱干扰和背景干扰,改善了检测结果的精密度和检测限。实验结果表明,建立的方法准确、快速、高效、线性范围宽,得到的分析结果令人满意。 相似文献
80.
气相色谱和原子荧光联用测定生物和沉积物样品中甲基汞 总被引:11,自引:0,他引:11
提出了一种气相色谱和原子荧光在线联用测定甲基汞的方法。对气相色谱和原子荧光的在线联用进行了设计,优化了进样口温度、载气流速、尾吹气流量及氩气流量等实验条件。在最佳仪器条件下,甲基汞(MMC)和乙基汞(EMC)的绝对检出限(3σ)可达0.005 ng。对于10 ng·mL-1 MMC和EMC标准溶液,连续5次进样测得精密度(RSD)分别为2.5%和1.3%。对标准参考物(DORM-2)的分析结果与标准值一致。两个沉积物中甲基汞的加标回收率分别为70%和77%。方法准确、灵敏,可应用于生物和沉积物样品中甲基汞的分析。 相似文献