Is there a universal scale of time?

The assumption that the same universal scale of time applies for different physical laws depends uponthe hypothesis that there is a unique universal scale of time in the universe. Intrinsic to that hypothesis is the assumption that if extraneous factors that affect physical clocks and processes that run on different physical principles could be removed, all clocks are synchronizable with one another. The consequences of that hypothesis not being true are considered. It was found thatclock asynchrony implies that: (1) a mass variation theory is probable; (2) there is a need for multiple clocks; and (3) t in the equations of physics is referring to clocks rather than time such that the properties of time are reduced to its direction (as characterized by thermodynamics and cosmology).     

Surface site dependence to negative ion formation

The processes of electron transfer and dissociative scattering are explored for collisions of hyperthermal NO⁺ on GaAs(110). The experiments reveal a marked angular dependence to O⁻ emergence. A strong correlation between the O⁻ scattering angle and the final atom-surface interaction site provides a map of the lateral dependence to reactivity. The results are modeled by sequential neutralization, dissociation, and electron attachment steps. Classical trajectory calculations, in conjunction with an empirical opacity function, accurately reproduce the experimental results. The opacity function is interpreted as the probability that an electron will attach to a departing O fragment as a function of the last surface site the atom impacts. The experiments indicate that O⁻ emergence occurs predominantly for oxygen atoms which come in close contact with the localized dangling bond states of GaAs(110).     

Semiclassical Method to Schroedinger Equation with Position-Dependent Effective Mass

In this paper, two novel semiclassical methods including the standard and supersymmetric WKB quantization conditions are suggested to discuss the Schroedinger equation with position-dependent effective mass. From a proper coordinate transformation, the formalism of the Schroedinger equation with position-dependent effective mass is mapped into isospectral one with constant mass and therefore for a given mass distribution and physical potential function the bound state energy spectrum can be determined easily by above method associated with a simple integral formula. It is shown that our method can give the analytical results for some exactly-solvable quantum systems.     

Massive and massless neutrinos on unbalanced seesaws

The observation of neutrino oscillations requires new physics beyond the standard model (SM).A SM-like gauge theory with p lepton families can be extended by introducing q heavy right-handed Majorana neutrinos but preserving its SU(2)L x U(1)y gauge symmetry.The overall neutrino mass matrix M turns out to be a symmetric (p+q) x (p+q) matrix.Given p＞q,the rank of M is in general equal to 2q,corresponding to 2q non-zero mass eigenvalues.The existence of (p-q) massless left-handed Majorana neutrinos is an exact consequence of the model,independent of the usual approximation made in deriving the Type-I seesaw relation between the effective p x p light Majorana neutrino mass matrix M,and the q x q heavy Majorana neutrino mass matrix MR.In other words,the numbers of massive left- and right-handed neutrinos are fairly matched.A good example to illustrate this "seesaw fair play rule"is the minimal seesaw model with p ＝ 3 and q ＝ 2,in which one masslese neutrino sits on the unbalanced seesaw.     

Hypernuclear physics for neutron stars

The role of hypernuclear physics for the physics of neutron stars is delineated. Hypernuclear potentials in dense matter control the hyperon composition of dense neutron star matter. The three-body interactions of nucleons and hyperons determine the stiffness of the neutron star equation of state and thereby the maximum neutron star mass. Two-body hyperon–nucleon and hyperon–hyperon interactions give rise to hyperon pairing which exponentially suppresses cooling of neutron stars via the direct hyperon URCA processes. Nonmesonic weak reactions with hyperons in dense neutron star matter govern the gravitational wave emissions due to the r-mode instability of rotating neutron stars.     

Rapid analysis of ultraviolet filters using dispersive liquid–liquid microextraction coupled to headspace gas chromatography and mass spectrometry

An ionic‐liquid‐based in situ dispersive liquid–liquid microextraction method coupled to headspace gas chromatography and mass spectrometry was developed for the rapid analysis of ultraviolet filters. The chemical structures of five ionic liquids were specifically designed to incorporate various functional groups for the favorable extraction of the target analytes. Extraction parameters including ionic liquid mass, molar ratio of ionic liquid to metathesis reagent, vortex time, ionic strength, pH, and total sample volume were studied and optimized. The effect of the headspace temperature and volume during the headspace sampling step was also evaluated to increase the sensitivity of the method. The optimized procedure is fast as it only required ∼7–10 min per extraction and allowed for multiple extractions to be performed simultaneously. In addition, the method exhibited high precision, good linearity, and low limits of detection for six ultraviolet filters in aqueous samples. The developed method was applied to both pool and lake water samples attaining acceptable relative recovery values.     

Spin polarization and temperature dependence of electron effective mass in quantum wires

The electron effective mass in GaAs quantum wires has been estimated by using a full dynamical random-phase approximation to examine its properties versus spin polarization, temperature, and carrier density. A decrease of mass with spin polarization is seen. The minority mass increases with the polarization while the majority mass decreases and this behaviour is seen for all densities. A maximal enhancement of mass at moderate temperature around 25 K is also presented. These calculations show a qualitative consistence with results in two-dimensional systems and help to control the electronic transport in quantum wires.     

Recent advances in liquid chromatographic methods for the determination of selective serotonin reuptake inhibitors and serotonin norepinephrine reuptake inhibitors

Depression is now the second largest public health burden throughout the world. Selective serotonin reuptake inhibitors (SSRIs) and serotonin norepinephrine reuptake inhibitors (SNRIs) have replaced older antidepressants to become first-line medications to treat this disease with increased remission rates and markedly decreased incidence of severe adverse events. Traditional and modern bioanalytical strategies for SSRI and SNRI determination are being continuously improved. There has also been a recent increase in the use of unconventional sample preparation methods. This review critically evaluates the development of SSRI and SNRI liquid chromatographic analytical methods published between 2014 and mid-2019, with special attention to novel sample preparation methods.     

Modified layered bimetallic compound used as a novel adsorbent for the solid-phase extraction of monoaromatic hydrocarbons from water samples prior to gas chromatography–mass spectrometry

This study reports a promising method of solid-phase extraction for determining the toluene, ethylbenzene, p-xylene, m-xylene, o-xylene, 1,3,5-trimethylbenzene, and 1,2,4-trimethylbenzene in water samples by gas chromatography–mass spectrometry (GC–MS). Prior to this procedure, the magnesium–aluminum bimetallic hydroxides modified with sodium dodecylbenzenesulfonate (Mg/Al-SDBS-LDH) were prepared and served as the novel solid-phase extractant. The Mg/Al-SDBS-LDH has advantage of good hydrophobicity and larger spacing which facilitates the monoaromatic hydrocarbons (MAHCs) into the interlayer for adsorption. As a result, the seven MAHCs in 500 mL water samples were enriched greatly, and the theoretical enrichment factor reached to 125 times. Under the optimized conditions of solid-phase extraction (SPE) and GC–MS, the mass concentration of each MAHC (0.005–10, 0.01–10, or 0.05–10 ng/mL) had a fine linear relationship with peak area. The correlation coefficients were more than 0.995. The detection limits were between 0.001 and 0.01 ng/mL, and the RSD were between 3.1% and 6.6%. The method had been applied to determine the seven MAHCs in the Dongfengqu river water and laboratory wastewater of Chengdu University of Technology successfully.