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81.
运用密度泛函理论方法研究了烷基碳链长度对氯化三烷基铵络合氯化汞的影响,计算结果表明,氯化三烷基铵与氯化汞的络合作用随着氯化三烷基铵中烷基碳链的增长而增强.通过对络合物的键长、Mayer键级和Mulliken电荷分析可知,电子富集在氯化三烷基铵的Cl原子上,并和Hg原子之间形成静电吸引作用.当烷基长度小于3时,烷基的电子效应影响较为明显,增强了原子之间的电子转移,使得络合物更稳定;当氯化三烷基铵烷基碳链长度大于3后,烷基链长对络合物中的电子转移不再有影响,络合物的稳定性受到烷基的几何效应影响更为明显. 相似文献
82.
根据高炉冲渣水的余热特点,提出了一个采用分离式热管换热器的余热回收的方案。文中对余热回收方案中换热设备的结构特点进行了描述。 相似文献
83.
David L. Henann 《Journal of the mechanics and physics of solids》2010,58(11):1947-1962
Recent experiments in the literature show that micro/nano-scale features imprinted in a Pt-based metallic glass, Pt57.5Ni5.3Cu14.7P22.5, using thermoplastic forming at a temperature above its glass transition temperature, may be erased by subsequent annealing at a slightly higher temperature in the supercooled liquid region (Kumar and Schroers, 2008). The mechanism of shape-recovery is believed to be surface tension-driven viscous flow of the metallic glass. We have developed an elastic-viscoplastic constitutive theory for metallic glasses in the supercooled liquid temperature range at low strain rates, and we have used existing experimental data in the literature for Pt57.5Ni5.3Cu14.7P22.5 (Harmon et al., 2007) to estimate the material parameters appearing in our constitutive equations. We have implemented our constitutive model for the bulk response of the glass in a finite element program, and we have also developed a numerical scheme for calculating surface curvatures and incorporating surface tension effects in finite element simulations. By carrying out full three-dimensional finite-element simulations of the shape-recovery experiments of Kumar and Schroers (2008), and using the independently determined material parameters for the bulk glass, we estimate the surface tension of Pt57.5Ni5.3Cu14.7P22.5 at the temperature at which the shape-recovery experiments were conducted. Finally, with the material parameters for the underlying elastic-viscoplastic bulk response as well as a value for the surface tension of the Pt-based metallic glass fixed, we validate our simulation capability by comparing predictions from our numerical simulations of shape-recovery experiments of Berkovich nanoindents, against corresponding recent experimental results of Packard et al. (2009) who reported shape-recovery data of nanoindents on the same Pt-based metallic glass. 相似文献
84.
Point‐to‐Plane Nonhomogeneous Electric‐Field‐Induced Simultaneous Formation of Giant Unilamellar Vesicles (GUVs) and Lipid Tubes 下载免费PDF全文
Chuntao Zhu Ying Zhang Yinan Wang Qingchuan Li Dr. Wei Mu Prof. Dr. Xiaojun Han 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(9):2906-2909
It is well‐known that homogeneous electric fields can be used to generate giant unilamellar vesicles (GUVs). Herein we report an interesting phenomenon of formation of GUVs and lipid tubes simultaneously using a nonhomogeneous electric field generated by point‐to‐plane electrodes. The underlying mechanism was analyzed using finite element analysis. The two forces play main roles, that is, the pulling force (F) to drag GUVs into lipid tubes induced by fluid flow, and the critical force (Fc) to prevent GUVs from deforming into lipid tubes induced by electric fields. In the center area underneath the needle electrode, the GUVs were found because F is less than Fc in that region, whereas in the edge area the lipid tubes were obtained because F is larger than Fc. The diffusion coefficient of lipid in the tubes was found to be 4.45 μm2 s?1 using a fluorescence recovery after photobleaching (FRAP) technique. The method demonstrated here is superior to conventional GUV or lipid tube fabrication methods, and has great potential in cell mimic or hollow material fabrication using GUVs and tubes as templates. 相似文献
85.
Hua-xing Chen Xiao-yan Wu Yi-gang Liu Jian-hua Bai Feng Zhao 《Journal of Dispersion Science and Technology》2016,37(4):486-495
A novel hydrophobically modified polyacrylamide p(AM/NaA/OP-10-AC/BOAM) was successfully synthesized via an aqueous micellar copolymerization method from acrylamide (AM), sodium acrylate (NaA), octylphenol polyoxyethylene acrylate (OP-10-AC), and small amounts of N-benzyl-N-octylacrylamide (BOAM), with the aim of investigating the copolymer's rheological behaviors under various conditions such as polymer concentration, shearing, temperature, and salinity. The copolymer was characterized by infrared spectroscopy, scanning electron microscopy, and atomic force microscope. Scanning electron micrographs show large aggregates in solution formed by the association from the hydrophobic groups of the copolymer. Compared with partially hydrolyzed polyacryamide (HPAM), the copolymer shows a much higher thickening capability and a much greater ability to resist shearing, heat, and salts. This good property of the copolymer is attributed to its three-dimensional dimensional network structure. According to the core flooding test, it can be obtained that oil recovery is enhanced about 4.3% by the copolymer flooding contrasted to the HPAM flooding in mid-low permeability cores under conditions of 1500 mg/L of polymers and 45°C. All the results prove that the copolymer has the capability of increasing oil recovery by improving waterflood sweep efficiency in high-salinity reservoirs. 相似文献
86.
THILO GIPSER HUBERT A. JAGER LUTZ RAPP Swiss Federal Institute of Technology Communication Technology Laboratory ETH Zentrum Zurich Switzerland 《Fiber and Integrated Optics》1998,17(1):21-40
All-optical networks are a sound answer to the huge data traffic demand expected for the forthcoming information society. Interesting networking aspects are the broadcasting, scalability, and reconfiguration in an all-optical environment. These issues are addressed in the present article for an all-optical network called MATRIX, which is time slotted and uses packet switching. The architecture enables the all-optical interconnection of a large number of nodes with both a small number of wavelengths and wavelength continuity based on a consequent exploitation of wavelength-division multiplexing and space-division multiplexing (i.e., multiple fibers per cable are used). For an efficient use of the resources, each node is equipped with multiple transmitters and receivers, respectively. Two different broadcasting schemes are investigated. An analytical model is developed, and the corresponding simulation results are in good agreement. It is further shown how different networks of arbitrary size can be interconnected to larger all-optical network clusters, thereby providing scalability not only with respect to the number of nodes but also to the geographical extension. Finally, wavelength reassignments allow change of optical paths through the network in case of changing traffic patterns or network failures in order to best exploit the available network resources. The total number of possible configurations is determined by the theory of Latin Squares. 相似文献
87.
LINUX下一种改进的音频会议系统的实现方法 总被引:2,自引:0,他引:2
提出了一种计算缓存区大小的改进方案.根据RTCP包中反馈回的丢包率,动态地改变音频数据的发送策略,有区分地采取差错控制手段,提高了网络带宽的利用率.在此基础上,设计了一个以RTP协议为基础的音频会议系统的模型,并在Linux平台上用多线程的方法实现了各个模块.模拟实验表明,该系统能自适应地调整缓存区大小和数据包的发送策略,在实时性及带宽资源的利用上都达到了较理想的效果. 相似文献
88.
C. Carstensen. 《Mathematics of Computation》2004,73(247):1153-1165
All first-order averaging or gradient-recovery operators for lowest-order finite element methods are shown to allow for an efficient a posteriori error estimation in an isotropic, elliptic model problem in a bounded Lipschitz domain in . Given a piecewise constant discrete flux (that is the gradient of a discrete displacement) as an approximation to the unknown exact flux (that is the gradient of the exact displacement), recent results verify efficiency and reliability of
in the sense that is a lower and upper bound of the flux error up to multiplicative constants and higher-order terms. The averaging space consists of piecewise polynomial and globally continuous finite element functions in components with carefully designed boundary conditions. The minimal value is frequently replaced by some averaging operator applied within a simple post-processing to . The result provides a reliable error bound with .
in the sense that is a lower and upper bound of the flux error up to multiplicative constants and higher-order terms. The averaging space consists of piecewise polynomial and globally continuous finite element functions in components with carefully designed boundary conditions. The minimal value is frequently replaced by some averaging operator applied within a simple post-processing to . The result provides a reliable error bound with .
This paper establishes and so equivalence of and . This implies efficiency of for a large class of patchwise averaging techniques which includes the ZZ-gradient-recovery technique. The bound established for tetrahedral finite elements appears striking in that the shape of the elements does not enter: The equivalence is robust with respect to anisotropic meshes. The main arguments in the proof are Ascoli's lemma, a strengthened Cauchy inequality, and elementary calculations with mass matrices.
89.
Ví ctor Padró n 《Transactions of the American Mathematical Society》2004,356(7):2739-2756
In this paper we study the equation
in a bounded domain of , , with homogeneous boundary conditions of the Neumann type, as a model of aggregating population with a migration rate determined by , and total birth and mortality rates characterized by . We will show that the aggregating mechanism induced by allows the survival of a species in danger of extinction. Numerical simulations suggest that the solutions stabilize asymptotically in time to a not necessarily homogeneous stationary solution. This is shown to be the case for a particular version of the function .
in a bounded domain of , , with homogeneous boundary conditions of the Neumann type, as a model of aggregating population with a migration rate determined by , and total birth and mortality rates characterized by . We will show that the aggregating mechanism induced by allows the survival of a species in danger of extinction. Numerical simulations suggest that the solutions stabilize asymptotically in time to a not necessarily homogeneous stationary solution. This is shown to be the case for a particular version of the function .
90.
F. Selleri 《Foundations of Physics Letters》2003,16(1):71-82
Transformations of space and time, depending on a synchronisation parameter e
1, indicate the existence of a privileged inertial system S
0. The Lorentz transformations are obtained for a particular e
10. No classical experiment on relativity is expected to depend on the choice of e
1. We show, consistently with expectations, that the result of the Fizeau experiment is explained equally well by theories adopting different values of e
1. In previous papers we showed that if accelerated reference frames are considered only e
1=0 remains possible. 相似文献