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241.
The 2900-3400 cm−1 spectral range is revisited for an accurate determination of line positions and line intensities of the 3ν3, ν1+2ν3, 2ν1+ν3, and 3ν1 bands of ozone. The fit on 4520 rotational energy levels of (012), (111), (210), (130), (003), (102), (201), and (300) vibrational states determined from observed transitions of cold and hot bands in the 2400-3400 cm−1 region with Jmax=65 and Ka max=20 gives a r.m.s.=7×10−4 cm−1 and provides a satisfactory agreement between calculated and observed line positions (dimensionless standard deviation is χ=1.44). The set of 2580 line intensities of 7 rovibrational bands has been measured and fitted with a r.m.s.=6.9% (χ=1.2), leading to the determination of transition moment parameters for these bands. Using these parameters we have obtained more precise estimation for the integrated band intensities S(3ν3)=1.41×10−19, S(ν1+2ν3)=1.28×10−20, S(2ν1+ν3)=7.91×10−21, S(3ν1)=4.72×10−22 cm−1/mol cm−2 at 296 K, with a cutoff 2×10−26 cm−1/mol cm−2. The interactions of the tetrad (003)/(102)/(201)/(300) with the (130) state and the tetrad (040)/(012)/(111)/(210) are studied. 相似文献
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243.
Influence of ion-molecular reactions on μ-capture in hydrogen and on fusion in 3Hedμ muonic molecule
The de-excitation processes (J=1)→ (J=0) in muonic molecular ions (ppμ)+ and (3Hedμ)+ are studied. It is shown that the rate of such transitions substantially depends on the chain of ion-molecular reactions
initiated by positively charged muonic ions.
The probabilities of ortho-para transition in the [(ppμ)+H2] and [(ppμ)+e] complexes formed as a result of chemical reactions in the pure hydrogen were estimated.
Taking into account the ion-molecular processes in D2 + He mixtures, the evaluation of the observed rate λf of nuclear fusion in the 3Hedμ muonic molecules was performed. The expected yield of fusion reactions per muon at the mixture density φ=0.1 and concentration
C
He
=0.05 was obtained to be equal to
.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
244.
本文提出了分子单中心模型,并通过对构型的平均,两个定理的提出与证明,色散能修正的证明,从数学上论证了这个模型的合理性。由此模型可以直接求出两个氢分子间的平均相互作用势,从而改变了长期以来,总是先算有限几种构型然后再作平均的传统作法。通过数字计算,得到了迄今为止最好的全程平均相互作用势曲线。势阱深度及平衡分子间距分别为-2.91meV和3.44(实验值:-2.85~-3.00meV,3.43~3.49)。 相似文献
245.
文中用R矩阵传播子方法计算了He-HCN超精细碰撞跃迁截面和速率常数,给出了新的理论计算结果,并讨论了势函数长程部分对结果的影响 相似文献
246.
本文利用液体的绝对速度理论得到液体的粘滞系数随温度变化的关系式,在不同的温度下测得液体的粘滞系数,找出液体的粘滞系数随温度变化的数学表达式。 相似文献
247.
N. A. Borisevich T. F. Raichyonok A. A. Sukhodola G. B. Tolstorozhev V. A. Shashilov 《Journal of Applied Spectroscopy》2005,72(1):49-58
Extensive studies of the spectral-luminescent characteristics of four 8-azasteroids and a model compound 2-(3,3-dimethyl-1,2,3,4-tetrahydro-1-isoquinolidene)-5,5-dimethyl-1,3-cyclohexanedion in the gas phase have been made. From the analysis of the dependences of the absorption spectra on the vapor pressure (Tlow) and the fluorescence spectra on Tlow and the exciting radiation wavelength (exc) a conclusion on the presence in the vapors of the investigated 8-azasteroids of three absorption and fluorescence centers (S-, M-, and L-centers) has been drawn. The absorption spectra of these centers strongly overlap. Their long-wave absorption boundaries have been determined. The dependence of the fluorescence spectra of all three centers on exc, which is inherent in rarefied gases of individual organic molecules, is observed. The S-centers are the molecules of the initial steroids, and the M- and L-centers are the molecules of thermo- and phototransformations of the initial steroids. The model compound in the gas phase is characterized by the same dependences of the fluorescence spectra on Tlow and exc as those inherent in 8-azasteroids. Taking into account the additional data obtained as a result of investigation of the absorption and fluorescence spectra of solutions of the substances extracted from vacuum cells after the investigation of 8-azasteroids and the model compound in the gas phase, conclusions on the nature of the M- and L-centers have been drawn.__________Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 1, pp. 48–57, January–February, 2005. 相似文献
248.
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