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151.
Transparent plastics are not scratch resistant. The damage leads to a loss of optical properties. Coatings prepared using either tetraethoxysilane or colloidal silica particles embedded in glymo is a way to avoid these disadvantages. Tribological experiments are carried out to better understand the surface modification due to a sliding friction. It is shown that the wear track is not directly related to usual mechanical properties such as Young's modulus and the hardness of the coating. The different stages leading to material loss are discussed in term of particle removal and debris circulation (accumulation or elimination) through the friction track. The mechanical properties of the film combined with the film to substrate adhesion are expected to play an important role as it can be deduced from results obtained as a function of the coating composition.  相似文献   
152.
利用磁场诱导的微粒运动即磁泳对磁响应性粒子进行精细分离,是近年来发展起来的选择性分离细胞和高分子量核酸的有效技术。本文在阐明磁泳分离原理的基础上,介绍了磁泳分离的分流薄层分级技术、四极磁场流动分离技术和微芯片上的自由流磁泳分离技术的装置构造、工作原理及其在生物分离分析中的应用。  相似文献   
153.
An ultrathin composite film containing anionic Ag-His complexes (His: L-Histidine) and oppositely charged BH-PPV was fabricated by means of the electrostatic layer-by-layer self-assembly technique. UV/Vis spectra showed a continuous deposition process of Ag-His complexes and BH-PPV. The film structure was characterized by using small-angle X-ray diffraction, AFM, and SEM. The nonlinear optical properties of the ultrathin film were studied by using the Z-scan technique with a laser duration of 8 ns at a wavelength of 532 nm. The film sample exhibited a strong nonlinear saturated absorption, with an alpha2 value of -3.9 x 10(-5) mW(-1) and a self-defocusing effect with an n2 value of -4.78 x 10 (-12) m2W(-1).  相似文献   
154.
通过BPO引发的溶液聚合 ,合成了水溶性的星状C6 0 苯乙烯 苯乙烯磺酸钠的三元共聚物 [Star shapedC6 0 poly(St SS) ],运用自组装技术 ,在水溶液中 ,含C6 0 的三元共聚物与重氮树脂 (Diazoresin)通过正负离子间的吸附力在云母基片上交替一层一层有序地组装成固体膜 .自组装膜经紫外光幅照反应 ,通过重氮基的分解 ,层间连接的离子键转变成共价键 ,从而增加薄膜的稳定性和堆砌密度 .用原子力显微镜 摩擦力显微镜(AFM FFM)考察了C6 0 在膜中的承载作用及比较不同链结构、不同链长、不同层数自组装膜的表面形貌和微摩擦性能 .初步的研究结果显示了聚合物薄膜的微摩擦性能与聚合物的化学结构、链长和膜的层数有密切关系  相似文献   
155.
PbZrO3 (PZ) thin films have been prepared by 2-methoxyethanol route from lead oxide or lead acetate and zirconium n-butoxide. The use of lead oxide as lead source and the seeding layer of TiO2 on Pt/TiO2/SiO2/Si substrate facilitate the formation of the perovskite phase.  相似文献   
156.
为了获得表面平整的定向纳米碳管,通过化学及物理的方法将纳米碳管膜进行反转,使其原来的AAO模板底面成为新的表面,用溶液逐步去除表面的铝和氧化铝后,获得了平整的定向纳米碳管膜表面,从而可将其作为工作面使用. 还比较了5%NaOH和6%H3PO4+1.8%H2CrO4溶液去除氧化铝的效果.  相似文献   
157.
《Electroanalysis》2004,16(12):994-1001
The interfacial behavior of electrodes fabricated from carbon film resistors of 2 and 20 Ω in supporting electrolyte solutions of varying pH used in electroanalytical experiments has been characterized by electrochemical impedance spectroscopy with complementary cyclic voltammetric experiments. Equivalent circuits are proposed to fit the experimental data and the influence of electrode pretreatment has also been investigated.  相似文献   
158.
X‐ray reflectivity has been used to determine the mass uptake of probe molecules in porous thin films supported on thick silicon wafers. The adsorption occurs by capillary condensation when the films are exposed to probe vapor at controlled partial vapor pressures. The probe solvent partial pressure was varied by mixing saturated air and dry air at constant temperature or by changing sample temperature at a constant vapor concentration. Pore size distribution in the films can be calculated from the probe uptake with typical porosimetric approaches such as the application of the Kelvin equation to convert partial pressure into pore size. For illustration, the pore size distribution of three different nanoporous thin films, the primary candidate of ultra‐low‐k interlevel dielectrics in the next generation of integrated circuit chips, was determined with this technique. These samples represent different generations of low‐k dielectrics developed by industry. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2170–2177, 2002  相似文献   
159.
乙二胺铜-铁氰复合修饰电极薄膜的电沉积和结构表征及电化学性质陈昌国,李海梅,黄宗卿(重庆大学化工学院重庆630044)关键词:铜、乙二胺,铁氰,修饰电极,光谱普鲁士兰(PB)修饰电极因其独特的电致变色现象而倍受关注。在1978年以来的十余年间里已相继...  相似文献   
160.
This paper reports a detailed study of how repeated r.f. magnetron sputtering from a hydroxyapatite (HA) powder target affects the nature and reproducibility of a sequential series of thin‐film coatings deposited onto Ti6Al4V substrates. An evaluation of the effective lifespan of the HA sputter targets and the reproducibility of the calcium phosphate (CaP) coatings produced from them has been made from Fourier transform infrared spectroscopy, XPS and, as appropriate, atomic force microscopy and SEM/energy dispersive x‐ray analyses. The annulus region of the target surface, from which sputtering under r.f. magnetron conditions normally occurs, showed severe surface degradation after only one deposition run, as indicated by significant PO43? and OH? depletion. This deterioration continued after each subsequent deposition cycle but to a much lesser extent than that observed in the initial sputtering period. The layers produced from all of the sputter runs contained the expected Ca2+ and PO43? species characteristic of a CaP system but were OH? deficient in the as‐deposited state. However, the chemical and morphological properties of the coatings did not change significantly until after the third consecutive sputter cycle. Hence, these data indicate that, even though a significant level of degradation of the HA target occurs at the outset of the sputtering procedure, the general plasma conditions employed here have a dominant influence on the coating properties until a critical degradation condition is met. As such, the compacted HA powder targets of interest can have a life‐cycle greater than single usage without detriment to the chemistry and morphology of the coatings produced from them. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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