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51.
Padmavathi P Mathana Gopal A Irudaya Sahaya Lancy A Krishna Kumar Pandey Poongodi J Jessie Fernando 《Macromolecular Symposia》2023,407(1):2200006
In this present work, the molecular interaction of the binary liquid mixture has been elucidated using ultrasonic technique. The recorded values of ultrasonic velocity (u), density (ρ), viscosity (η), and refractive index (n) for the experimented binary liquid mixtures of Ethanol with Benzene at 303 K are used to calculate the derived parameters such as adiabatic compressibility (βa), free length (Lf), acoustic impedance (Z), free volume (Vf), molar volume (Vm), internal pressure (πi), relaxation time (τ), Enthalpy (H), Electronic polarization (ε), Molar refraction (Rm), and the experimentally determined ultrasonic velocity have been compared with the with the computed values using different analytical models and empirical relations such as Nomoto's Theory (NOM), Free Length Theory (FLT), and Van Dael-Vangeal theory (VDV). The results are interpreted and reported to explain the behavior of benzene with ethanol. 相似文献
52.
Eurydice Arroyo Diana Tentori Alfonso Garcia Ricardo Valdez Miguel A. Armenta Osvaldo J. Nava Roberto Machorro Amelia Olivas 《Particle & Particle Systems Characterization》2023,40(6):2200200
Carbon quantum dots (CQD) have received significant attention in recent years due to their potential applications in optics and sensing. In this study, the authors report on the first characterization of the optical activity and broad absorption spectrum covering from short-wave ultraviolet, at 200 nm, to mid-infrared, at 1600 nm, of CQD synthesized using the “low-molecular-weight alcohols electrochemical carbonization” method. The CQD are analyzed using spectroscopic techniques, optical activity in the infrared, and high-resolution transmission electron microscopy. Results show a CQD size distribution of 5±3 nm and spherical morphology. The absorption spectra show increased absorption at both, high and low frequency. Additionally, the specific rotation of the CQD solution is significantly higher than that of pure ethanol, by three orders of magnitude. These findings suggest that CQD may have potential applications in polarized infrared filters and/or sensors due to their ability to rotate the polarization state of light at 1550 nm. The results of this study provide valuable insights into the optical properties of CQD and their potential for infiltration into hollow core photonic crystal fibers, making them a promising material for future research and development in the field of optics and sensing. 相似文献
53.
《Advanced Optical Materials》2018,6(1)
Although recent progress in metasurfaces has shown great promise for applications, optical properties in metasurfaces are typically fixed by their structural geometry and dimensions. Here, an electrically controllable amplitude of anomalously‐refracted waves in a hybrid graphene/metasurface system are experimentally demonstrated, which consists of an artificially constructed two‐dimensional metallic apertures array and naturally occurring two‐dimensional carbon atoms (graphene) in the subwavelength‐scale (< λ/10). Based on Pancharatnam–Berry phase and by careful design of a spatially linear phase profile, it is shown that the amplitude of anomalously refracted circularly cross‐polarized terahertz waves can be effectively modulated by an applied gate voltage. The developed electrically tunable graphene metasurfaces may lead to various advanced applications that require dynamical control over electromagnetic waves, such as amplitude tunable active focusing lenses, vortex phase plates and dynamic holography. 相似文献
54.
55.
Based on electro-optic switch effect in crystal, a novel laser ranging method is proposed. CW-laser emitted by laser transmitter propagates forward to the measured target, after being reflected by the target, and then goes back to the transmitter. Close to the transmitter, a special mono-block LiNbO3 crystal is added into the round-trip light beams. High-voltage pulses with the sharp enough changes in rising edges are loaded on the crystal. Based on electro-optic effect, double refraction and internal double reflection effect in crystal, the crystal cuts off the round-trip light beams, and reflects a light pulse cut out by the crystal to a detector aside from the original beam path. The pulse width T is the period that laser propagates forward and back between the crystal and the target. The feasibility of the new idea is proved by our experiments and a brand-new way for the laser ranging is provided. 相似文献
56.
《Comptes Rendus Physique》2016,17(5):533-542
The negative refraction behavior and imaging effect for acoustic waves in a kind of two-dimensional square chiral lattice structure are studied in this paper. The unit cell of the proposed structure consists of four zigzag arms connected through a thin circular ring at the central part. The relation of the symmetry of the unit cell and the negative refraction phenomenon is investigated. Using the finite element method, we calculate the band structures and the equi-frequency surfaces of the system, and confirm the frequency range where the negative refraction is present. Due to the rotational symmetry of the unit cell, a phase difference is induced to the waves propagating from a point source through the structure to the other side. The phase difference is related to the width of the structure and the frequency of the source, so we can get a tunable deviated imaging. This kind of phenomenon is also demonstrated by the numerical simulation of two Gaussian beams that are symmetrical about the interface normal with the same incident angle, and the different negative refractive indexes are presented. Based on this special performance, a double-functional mirror-symmetrical slab is proposed for realizing acoustic focusing and beam separation. 相似文献
57.
就介质折射率的物理意义首先从理论上作了说明,然后从经典概念出发对介质折射率的表达式作了推导,指出了决定介质折射率的因素,即组成介质的原子结构、原子种类、每一个原子周围电子分布的情况及辐射的频率。通过理论计算和实验数值的对比表明,所推导出的结论及相关的计算方式是正确的,对介质折射率的研究和在特殊领域对折射率有一定要求的材料的制备具有一定的指导意义。 相似文献
58.
用衍射光栅和CCD测量透明材料折射率 总被引:11,自引:5,他引:11
介绍了一种基于衍射光栅干涉和CCD图像测量的测量透明材料折射率的方法。这种方法使用的仪器少,操作简单,配合CCD与图像处理的运用,尝试的两种测量方案都使精度能够达到10^-4。两种测量方案对同一玻璃基片的测量结果基本吻合,而第二种测量方案的测量精度要优于第一种,这是因为就我们目前的实验条件而言,CCD判别条纹移动的精度对折射率测量的影响要小于角度测量精度对之的影响。该方法还可以测量各向同性透明薄膜样品的折射率,为探索新型有机薄膜的折射率及其有关特性提供便利的手段。讨论了测量的基本原理和样品的测量结果,并对实验方法误差进行了分析。 相似文献
59.
设计了一种以聚合物作为材料的低损耗、宽带宽的Mach—Zehnder光波导调制器。分析了调制器的脊波导的模式特性,设计了脊波导的结构,并使用BPM软件模拟了脊形波导的光场分布;通过对光场分布的分析,优化了脊形波导的宽度Wg,脊高6,芯层高度H。同时对聚合物调制器的电极进行了优化,包括电极宽度W和电极间距D,使得调制器有较小的导体损耗以及较好的阻抗匹配。并结合了脊波导的结构参数和电极的优化参数,给出了优化结果,它能够使微波的有效折射率与光波的有效折射率达到匹配,从而使带宽达到177GHz,导体损耗为0.2569dB/cm·GHz1/2。 相似文献
60.
Qinqin Liu Juan YangXiaonong Cheng Xiujuan SunChuanliang Zang 《Physica B: Condensed Matter》2011,406(18):3458-3464
ZrW2O8 displays the unusual property of an isotropic bulk contraction in volume as a function of temperature. We report here on the positive thermal expansion (PTE) property caused by substituting Mo for W sites in ZrW2O8 at room temperature. The room temperature crystal structure of ZrW2−xMoxO8 compounds, which were synthesized using a low temperature route, could be divided into ordered phase with α-ZrW2O8 structure (0≤x≤0.5) and disordered phase with β-ZrW2O8 (0.5<x≤1.5) and c-ZrMo2O8 structure (1.5<x≤2). ZrW2−xMoxO8 adopting β-ZrW2O8 structure shows abnormal PTE property at room temperature due to the existence of water molecules, while ZrW2−xMoxO8 adopting the other two structures (α-ZrW2O8 and c-ZrMo2O8) shows negative thermal expansion (NTE) property from room temperature until decomposition for α-ZrW2O8 structure or trigonal phase transition for c-ZrMo2O8 structure. The reason lies in the fact that the oxygen migration caused by the Mo substitution leads to the re-arrangement of W(Mo)O4 tetrahedra lying along the 3-fold axis, only particular W/Mo ratio (0.5<x≤1.5) produces a special crystal structure, which allows the entrance of water molecules. 相似文献