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排序方式: 共有1245条查询结果,搜索用时 321 毫秒
41.
《化学:亚洲杂志》2017,12(20):2684-2693
Electrostatic interactions are characteristic of ionic liquids (ILs) and play a pivotal role in determining the formation of species when solutes are dissolved in them. The formation of new species/complexes has been investigated for certain ILs. However, such investigations have not yet focused on eutectic liquids, which are a promising class of ILs. These liquids (or liquid coordination complexes, LCCs) are rather new and are composed of cationic and anionic chloro complexes of metals. To date, these liquids have been employed as electrolytes to deposit metals and as solvents for catalysis. The present study deals with a liquid that is prepared by mixing a 1.2:1 mol ratio of AlCl3 and 1‐butylpyrrolidine. An attempt has been made to understand the interactions of FeCl2 with the organic molecule using spectroscopy. It was found that dissolved Fe(II) species interact mainly with the IL anion and such interactions can lead to changes in the cation of the electrolyte. Furthermore, the viability of depositing thick magnetic films of Fe and Fe–Al has been explored. 相似文献
42.
《Electroanalysis》2017,29(3):806-813
An electrochemical quartz crystal microbalance (EQCM) is described, which measures the shifts of frequency and bandwidth on multiple harmonics with a time‐resolution of 10 milliseconds. The technique requires the process under study to be repetitive. Examples are square wave amperometry and cyclovoltammetry. Data acquisition is fast because the raw data consist of traces of the electrical admittance at fixed frequencies . A few (∼10) such time traces are acquired sequentially at a set of frequencies evenly spaced around the crystal's resonance. Since all time‐traces are triggered by the same repetitive process, plots of the conductance G (ωi , t ) and the susceptance B (ωi , t ) from constant time delays, t , versus frequency can be produced a posteriori. The shifts, ΔG (ωi ) and ΔB (ωi ) quantify a difference between two resonance curves, pertaining to the sample's reference state and the state at time t . Fitting a difference of two resonance curves to these data, one obtains shifts of frequency, Δf (t ) and shifts of bandwidth, ΔΓ(t ), versus time. This procedure is repeated for the different overtones. Given the repetitive nature of the process, one may accumulate and average, which lowers the noise down to a few tens of mHz. The capabilities of this instrument are demonstrated with two examples, which are copper deposition/dissolution and electro‐responsivity of a polymer film containing weakly acidic side groups. 相似文献
43.
Konstantin Pliuta Alexander Chebotarev Anastasia Pliuta Denys Snigur 《Electroanalysis》2021,33(4):987-992
In current study the carbon-paste electrode modified by silica with embedded cetylpyridinium chloride for determination of Allura Red AC have been developed. The optimal conditions were determined to be for the square-wave voltammetric quantification: pH=2, Eads=300 mV, tads=300 s, amplitude – 40 mV, frequency – 25 Hz and potential scan rate is 250 mV sec−1. The calibration plot has linearity in the concentration ranges 0.04–0.2 μM and 0.2–1.00 μM. The LOD and LOQ are equal to 0.005 μM and 0.015 μM respectively. The crafted sensor has been applied successfully to model solutions and in jelly candies analysis with RSD no more than 10 %. 相似文献
44.
Bisphenol-A polycarbonate films were irradiated with 86 MeV swift heavy nickel ions at varying fluences, ranging from 1 × 1011 to 1 × 1013 ions cm?2, under vacuum at room temperature, to analyze the induced electrical and thermal modifications. AC conductivity measurements and UV-visible spectroscopy, Fourier transform infra-red (FTIR) spectroscopy, thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC), and X-ray diffraction (XRD) techniques were applied to analyze the changes. A significant, exponential increase in conductivity at higher frequency was observed with the increase of nickel ion fluence. UV-visible analysis corroborated the results of the AC conductivity measurement, revealing the increase in size of the carbon clusters embedded in the polymer network, with the increase of heavy ion fluence. FTIR analysis revealed the formation of alkene and alkyne end groups at higher doses, which further supported the suggestion that the variation in electrical properties induced by the ion irradiation of the polymer was due to development of a carbonaceous phase inside the polymer due to the irradiation. Thermal analysis, i.e., TGA and DSC patterns, showed that chain-scission was the leading phenomena in the heavy ion-irradiated polycarbonate samples, resulting in degradation of their thermal stability. 相似文献
45.
Dr. Christian Kulp Konrad Gillmeister Prof. Dr. Wolf Widdra Prof. Michael Bron 《Chemphyschem》2013,14(6):1205-1210
The synthesis of Cu(core)Pt(shell) model catalysts by the direct electrochemical deposition of Pt on Cu particles is presented. Cu particles with an average diameter of 200 nm have been deposited on glassy‐carbon electrodes by double pulse electrodeposition from a copper sulfate solution. Subsequent deposition from a platinum nitrate solution under potential control allows for a high selectivity of the Pt deposition towards Cu. Using a combination of cyclic voltammetry, XPS and sputtering, the structure of the generated particles has been analyzed and their core–shell configuration proven. It is shown that the electrocatalytic activity for the oxygen reduction is similar to that of other PtCu catalyst systems. The synthesized structures could allow for the analysis of structure–activity relations of core–shell catalysts on the way to the simple and controlled synthesis of supported Cu(core)Pt(shell) nanoparticles as oxygen reduction catalysts. 相似文献
46.
采用循环伏安法(CV)对离子液体Reline中三元CuCl2+InCl3+SeCl4体系和四元CuCl2+InCl3+GaCl3+SeCl4体系的电化学行为进行了研究。研究表明,In3+并入三元CIS(Cu-In-Se)薄膜体系和Ga3+并入四元CIGS(Cu-In-Ga-Se)薄膜体系均有两种途径:一是发生共沉积,二是直接还原。利用电感耦合等离子体发射光谱(ICP)和扫描电镜(SEM)对沉积电势、镀液温度和主盐浓度对CIGS薄膜组成、镀层表面形貌的影响进行了测试,结果表明通过工艺参数的选择可以控制Ga/(Ga+In)和CIGS薄膜组成并得到化学计量比为Cu1.00In0.78Ga0.27Se2.13的薄膜。 相似文献
47.
Yuanyuan Guo Limin Chen Ding Ma Daiqi Ye Bichun Huang 《Journal of Energy Chemistry》2013,22(4):591-598
Activated carbon (AC) supported silver catalysts were prepared by incipient wetness impregnation method and their catalytic performance for CO preferential oxidation (PROX) in excess H2 was evaluated. Ag/AC catalysts, after reduction in H2 at low temperatures (≤200 °C) following heat treatment in He at 200 °C (He200H200), exhibited the best catalytic properties. Temperature-programmed desorption (TPD), X-ray diffraction (XRD) and temperature-programmed reduction (TPR) results indicated that silver oxides were produced during heat treatment in He at 200 °C which were reduced to metal silver nanoparticles in H2 at low temperatures (≤200 °C), simultaneously generating the adsorbed water/OH. CO conversion was enhanced 40% after water treatment following heat treatment in He at 600 °C. These results imply that the metal silver nanoparticles are the active species and the adsorbed water/OH has noticeable promotion effects on CO oxidation. However, the promotion effect is still limited compared to gold catalysts under the similar conditions, which may be the reason of low selectivity to CO oxidation in PROX over silver catalysts. The reported Ag/AC-S-He catalyst after He200H200 treatment displayed similar PROX of CO reaction properties to Ag/SiO2. This means that Ag/AC catalyst is also an efficient low-temperature CO oxidation catalyst. 相似文献
48.
Ternary Ni–Mo–P thin films have been electrodeposited from citrate‐based electrolyte onto graphite substrates for application as anode catalysts for ethanol electrooxidation. The operating deposition parameters were optimized to produce Ni–Mo–P alloy films of outstanding catalytic activity. The phase structure of the deposits was evaluated employing X‐ray diffraction technique. Morphology and chemical composition of the deposited alloy films were studied using scanning electron microscopy and energy‐dispersive X‐ray analysis, respectively. The results demonstrated that the rate of Ni–Mo–P deposition increases with increasing the ammonium molybdate concentration in the plating electrolyte up to 10 g l?1. Also, the amount of Mo in the deposits increases with increasing the ammonium molybdate concentration up to 7.5 g l?1, and the maximum Mo content in the film was 9.1 at.%. The catalytic activity of Ni–Mo–P/C alloy films has been evaluated towards electrooxidation of ethanol in 1.0 M NaOH solution by using cyclic voltammetry and chronoamperometry. The catalytic performance of the prepared anodes as a function of the amount of Mo was studied. The results showed an increase in the oxidation peak current density of ethanol with increasing the Mo at.% in the deposited alloy films. Additionally, Ni–Mo–P/C electrodes displayed significantly improved catalytic activity and stability towards electrooxidation of ethanol compared with that of Ni–P/C electrode. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
49.
Lenka Škantárová Andrej Oriňák Renáta Oriňáková Monika Jerigová Monika Stupavská Dušan Velič 《Surface and interface analysis : SIA》2013,45(8):1266-1272
Present article deals with functionality of silver nanostructured surfaces prepared by potentiostatic electrochemical deposition on the paraffin impregnated graphite electrode as template‐free substrates. The effect of the electrodeposition conditions on two silver surface functions: analytical signal enhancement in Surface‐enhanced Raman spectroscopy and pre‐ionization function, applied in secondary ion mass spectrometry (SIMS) is reported. Functional silver nanostructured substrate was prepared at a potential ?850 mV with a deposition duration of 20 min. Analytical signal enhancement factors of 3.2 ×105 for Raman peak at 649 cm?1, 3.0×105 for peak at 810 cm?1 and 2.7×105 for peak at 1539 cm?1 were determined for Rhodamine 6G at deposited surface. Slight pre‐ionization effect has been observed in SIMS, and 1.2×105 fold signal enhancement was established for fragment of Rhodamine 6G with m/z 429 (M‐CH3‐Cl). Electrochemical preparation of nanostructures represents a step towards surface integration directly into miniaturized systems and sensors. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
50.
Palladium(II)and chloride ions tend to form complexes in aqueous solution.Both theoretical and experimental(by UV spectrum)results indicate that there are four complexes formed in aqueous solution containing 3 mol/L hydrochloric acid and 20mmol/L PdCl2.This work evaluates the kinetics of electrochemical deposition of palladium on a Platinum electrode.For this purpose,palladium electrodeposition was investigated by means of cyclic voltammetry(CV),potentiostatic current-time transients(CTTs)and Tafel curve.By CTTs curves,the regions corresponding to the charge transfer control,mixed control and diffusion control were identified.In the diffusion control region,palladium electrodeposition mechanism was characterized as progressive nucleation with three-dimensional(3D)growth under diffusion control;as for the mixed control region,an adsorption(IAds),ion transfer(IIT),and nucleation and growth(ING)model were proposed to analyze the current-time transients quantitatively,which could separate the IAds,IIT and ING perfectly. 相似文献