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381.
Summary A numerical scheme to approximate a semilinear PDE involving a (singular) maximal monotone graph is analyzed inL . A preliminary regularization is combined with piecewise linear finite elements defined on a triangulation which is not assumed to be acute; the discrete maximum principle is thus avoided. Sharp pointwise error estimates are derived for both the smoothing and the discretization procedures. An optimal choice of the regularization parameter as a function of the mesh size leads to a sharp global rate of convergence. These error estimates for solutions, in conjunction with nondegeneracy properties of continuous problems, provide sharp interface error estimates. Two model examples are discussed: the obstacle problem and a combustion equation.This work was partially supported by Consiglio Nazionale delle Ricerche of Italy while the author was in residence at the Istituto di Analisi Numerica del C.N.R. di Pavia  相似文献   
382.
Jagers P 《Acta Appl Math》1989,14(1-2):103-114
Some problems concerning the development of general models of population growth are examined, with particular reference to Markovian modelling. The tenet of the paper is that such models can be more realistically attempted by focusing on temporal rather than spatial modifications. Specifically, the time concept considered is linked to the dependent structure inherent in the partial order of descent from mother to child. The author attempts to develop "a general theory of populations of individuals under what might be called free reproduction. Hence, the only dependence assumed between individuals is that from mothers to children." He suggests that the results "can be translated into assertions about evolution in real, physical time and also about the final, stable or balanced, composition of populations, over ages, types, family structure, and many other aspects of populations."  相似文献   
383.
In this article we study symmetric subsets of Rauzy fractals of unimodular irreducible Pisot substitutions. The symmetry considered is reflection through the origin. Given an unimodular irreducible Pisot substitution, we consider the intersection of its Rauzy fractal with the Rauzy fractal of the reverse substitution. This set is symmetric and it is obtained by the balanced pair algorithm associated with both substitutions.  相似文献   
384.
The hydrogen-ion selective glass electrode   总被引:1,自引:0,他引:1  
Johansson G  Karlberg B  Wikby A 《Talanta》1975,22(12):953-966
The properties and mechanism of operation of hydrogen-ion selective glass electrodes are reviewed and a model using information from recent research is presented. In the gel layer of a pH-glass protons or hydronium ions are bound to negative charges in a silicon network cross-linked with bi- or tervalent metal ions. The composition of the gel layer is discussed; it is known that the outer part contains water. The formation of a gel layer and its destruction in alkaline solutions are discussed. Between the gel layer and the dry glass there is a transition layer characterized by a very high resistivity. This forms a barrier to ion transport and prevents rapid corrosion of the glass. The ionic mobilities of various ions change drastically with distance inwards towards the dry glass. The alkaline and acid errors are discussed as well as the asymmetry potential. By etching away the gel layers and the transition layers on both sides of the glass and then starting hydration simultaneously on both sides, two symmetric layers can be produced. This will result in an almost complete cancellation of the asymmetry potential. Some applications to precision measurements and measurement in non-aqueous solvents are discussed.  相似文献   
385.
    
Zusammenfassung Für die objektive Beurteilung und Auswahl von Meßpunkten aus überbestimmten spektrometrischen Vielkomponentensystemen werden als Bewertungskriterien die neuen Begriffe der Distension ¯85vj27l132g70k/xxlarge977.gif" alt="thetav" align="BASELINE" BORDER="0"> und der Systemdistension 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0"> = ¯85vj27l132g70k/xxlarge977.gif" alt="thetav" align="BASELINE" BORDER="0">i eingeführt. Beide geben ein quantitatives Maß der Selektivität einzelner Meßstellen in Relation zu den übrigen bzw. mit ihrem Mittelwert Aussagen über die Distension 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0"> eines Mehrkomponentensystems. Die Distension 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0"> erlaubt die optimale Reduzierung eines mehrfach überbestimmten Systems und somit auch die Auswahl optimaler Meßpunkte eines zunächst kontinuierlich vermessenen Systems. Rechenverfahren zur Bestimmung der Distension und der anschließenden Optimierung überbestimmter Systeme werden angegeben und an Beispielen erläutert.Ergänzt wird die 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0">-Optimierung durch eine 85vj27l132g70k/xxlarge8222.gif" alt="ldquor" align="MIDDLE" BORDER="0">längendiskriminierende85vj27l132g70k/xxlarge8220.gif" alt="ldquo" align="MIDDLE" BORDER="0"> Vorauswahl von geeigneten Meßpunkten aus kontinuierlichen Spektren durch Maximierung der Differenzspektren gegenüber den Summenspektren der übrigen Gemischkomponenten.Der Unterschied der 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0">-Optimierung zur Empfindlichkeitsoptimierung wird diskutiert.
Selection, comparison and valuation of optimum working conditions for quantitative multicomponent analysisII. Selection of optimum measuring points by means of the distension of the calibration matrix
Two new terms for the critical classification and selection of measuring points in spectrochemical multicomponent analysis are introduced: the distension 85vj27l132g70k/xxlarge977.gif" alt="thetav" align="BASELINE" BORDER="0"> and the distension of the system 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0"> = ¯85vj27l132g70k/xxlarge977.gif" alt="thetav" align="BASELINE" BORDER="0">i. Both terms give a quantitative relation of the selectivity of any single point of a spectrum with respect to the others and incorporate a measure of the overall-distension of a system. The distension allows the optimal reduction of a multiple overdetermined system and the optimal selection of the best points to be taken from a continuously measured spectrum. Procedures for the calculation of 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0"> and for the optimization which follows are given and demonstrated.The angle-dependent 85vj27l132g70k/xxlarge920.gif" alt="THgr" align="BASELINE" BORDER="0">-optimization is preceded by an 85vj27l132g70k/xxlarge8220.gif" alt="ldquo" align="MIDDLE" BORDER="0">length-discriminating85vj27l132g70k/xxlarge8221.gif" alt="rdquo" align="MIDDLE" BORDER="0"> preselection of points of a continuously measured spectrum; this is done by comparing the difference spectra of all compounds with respect to the sum spectra.
  相似文献   
386.
The electrical properties ofn +-window layers inp-i-n a-Si:H solar cells were characterised as a function ofn +-layer thickness, , by measuring firstly the activation energyE a of the dark conductivity and secondly the built-in potentialV bi of the cells.E a was found to increase with decreasing attaining values as high as 0.8 eV for 5nm; bulk values, e.g.E a . 2eV in the amorphous andE a<0.01 eV in the microcrystalline case, were only observed for >20nm and for >200nm, respectively. In contrast,V bi did not depend on at all and was further found to be consistent with expectations based on the Fermi level positions in bulkn + andp +-material. As a consequenceE a in very thin films can no longer be considered as a measure of (E C –E F), the distance of the Fermi level from the conduction band edge. The apparent inconsistency inherent to theE a and theV bi results can be resolved by assuming that the deposition of then +-material proceeds via the growth and coalescence of small islands.  相似文献   
387.
Solid solution phases of a formula Fe8V10W16–xMoxO85 where 0≤x≤4, have been obtained, possessing a structure of the compound Fe8V10W16O85. It was found on the base of XRD and DTA investigations that these solution phases melted incongruently, with increasing the value of x, in the temperature range from 1108 (x=0) to 1083 K (x=4) depositing Fe2WO6 and WO3. The increase of the Mo6+ ions content in the crystal lattice of Fe8V10W16O85 causes the lattice parameters a=b contraction with cbeing almost constant. IR spectra of the Fe8V10W16–xMoxO85 solid solution phases have been recorded.  相似文献   
388.
The standard problem of radiation transfer in a bounded regionG 8543g13263t32/xxlarge8834.gif" alt="sub" align="MIDDLE" BORDER="0"> 8543g13263t32/xxlarge8477.gif" alt="Ropf" align="BASELINE" BORDER="0"> n can be reformulated as a weakly singular integral equation with an unknown functionu: G8543g13263t32/xxlarge8594.gif" alt="rarr" align="BASELINE" BORDER="0">C(S n–1) and a kernelK: ((G × G 8543g13263t32/xxlarge8726.gif" alt="setmn" align="MIDDLE" BORDER="0"> }x=y}, which is continuously differentiable with respect to the operator strong convergence topology. We take these observations into the basis of an abstract treatment of weakly singular integral equations with 8543g13263t32/xxlarge8466.gif" alt="Lscr" align="MIDDLE" BORDER="0">(E)-valued kernels, whereE is a Banach space. Our purpose is to characterize the smoothness of the solution by proving that it belongs to special weighted spaces of smooth functions. On the way, realizing the proof techniques, we establish the compactness of the integral operator or its square inL p (G,E),BC(G,E), and other spaces of interest in numerical analysis as well as in weighted spaces of smooth functions. The smoothness results are specified for the standard problem of radiation transfer as well as for the corresponding eigenvalue problem.  相似文献   
389.
Summary The model of the potential turbulence described by the 3-dimensional Burgers' equation with random initial data was developped by Zeldovich and Shandarin, in order to explain the existing Large Scale Structure of the Universe. Most of the recent probabilistic investigations of large time asymptotics of the solution deal with the central limit type results (the Gaussian scenario), under suitable moment assumptions on the initial velocity field. These results and some open questions are discussed in Sect. 2, where we concentrate on the Gaussian model and the shot-noise model. In Sect. 3 we construct a probabilistic model of strong initial fluctuations (a zero-range shot-noise field with high amplitudes) which reveals an intermittent large time behaviour, with the velocity determined by the position of the largest initial fluctuation (discounted by the heat kernelg(t,x·)) in a neighborhood ofx. The asymptoties of such local maximum ast8594.gif" alt="rarr" align="BASELINE" BORDER="0"> can be analyzed with the help of the theory of records (Sect. 4). Finally, in Sect. 5 we introduce a global definition of a point process oft-local maxima, and show the weak convergence of the suitably rescaled process to a non-trivial limit ast8594.gif" alt="rarr" align="BASELINE" BORDER="0">.  相似文献   
390.
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