Polymerisation of pentadienyl compounds in the presence of transition-metal compounds: the polymorphic compound deca-1,3,7,9-tetraenediiron hexacarbonyl

The reaction between Fe(CO)₅ and penta-1,4-dien-3-ol gives two forms of di(pentadienyliron tricarbonyl).     

Systematic selection of ancestry informative SNPs for differentiating Han,Japanese, Dai,and Kinh populations

Biogeographical origin inferences of different populations can provide valuable clues in the forensic investigation by narrowing down the detection scope. However, much research mainly focuses on forensic ancestral origin analyses of major continental populations, which may provide limited information in forensic practice. To improve the ancestral resolution of East Asian populations, we systematically selected ancestry informative single-nucleotide polymorphisms (AISNPs) for differentiating Han, Dai, Japanese, and Kinh populations. In addition, we evaluated the performance of the selected AISNPs to differentiate these populations via multiple methods. Totally 116 AISNPs were selected from the genome-wide data to infer the population origins of these four populations. Results of principle component analysis and population genetic structure of these populations indicated that the selected 116 AISNPs could achieve ancestral resolution of most individuals. Furthermore, the machine learning model built by 116 AISNPs unveiled that most individuals from these four populations could be assigned to correct population origins. To sum up, the selected 116 SNPs could be available for ancestral origin predictions of Han, Dai, Japanese, and Kinh populations, which could provide valuable information for forensic research and genome-wide association study in East Asian populations to some extent.     

Oscillation criteria for second-order Emden–Fowler delay differential equations with a sublinear neutral term

New oscillation criteria for the second-order Emden–Fowler delay differential equation with a sublinear neutral term are presented. An essential feature of our results is that oscillation of the studied equation is ensured via only one condition. Furthermore, as opposed to the results by Agarwal et al. (Ann. Mat. Pura Appl. (4) 193 (2014), no. 6, 1861–1875), Li and Rogovchenko (Math. Nachr. 288 (2015), no. 10, 1150–1162; Monatsh. Math. 184 (2017), no. 3, 489–500), and Xu (Monatsh. Math. 150 (2007), no. 2, 157–171), new criteria can be applied to Emden–Fowler delay differential equations with noncanonical operators and a sublinear neutral term. Our results essentially improve, extend, and simplify some known ones reported in the literature. The results are illustrated with examples.     

基于GOCI提取东海近几年赤潮信息及时序分析

赤潮已经成为我国东海最普遍的海洋灾害之一.利用卫星手段监测赤潮也由来已久.采用Geostationary Ocean Color Imager(GOCI)静止卫星对东海近几年的赤潮进行了监测和分析.研究表明:1)利用Quick Atmospheric Correction(QUAC)获取GOCI的归一化离水辐射率,其中nLw(555nm)作为赤潮事件的特征波段来监测赤潮是有效的;2)以nLw(555nm)为峰值且通过小于1.5mW·cm~(-2)·sr~(-1)·μm~(-1)这一阀值信息来监测中国东海3次不同时间和区域的赤潮事件.3次事件分别为2011年5月东海原甲藻事件、2011年7月中肋骨条藻事件和2014年5月东海原甲藻事件;3)赤潮面积的日变化主要受有效光合辐射和潮位的影响.通过QUAC获取归一化离水辐射率GOCI-nLw(550nm),将nLw(555nm)作为特征波段来获取赤潮信息,并结合光照强度、潮位、温度等参数,分析了赤潮面积日变化的可能原因.     

投资者情绪影响下资本资产定价的区制性研究——基于股票论坛发帖的情感分析

本文首先建立一个考虑投资者情绪的资本资产定价模型,研究发现,投资者情绪是资产定价的系统性因子且对其影响具有区制性(存在三个区制)。在此基础上通过仿真揭示投资者情绪对资产定价影响存在区制性的原因在于当投资者情绪增加时,最优组合超额收益受组合效应与情绪效应的综合影响。最后基于股票论坛发帖的情感分析构建投资者情绪指标,实证检验了本文的理论模型,并发现基于普通的线性回归模型得到的投资者情绪对股指超额收益影响,一方面会在投资者情绪处于第二区制内时将其对股指超额收益影响方向弄反,另一方面会在投资者情绪处于第三区制内时低估其增加导致的股指超额收益平均增加程度。     

东海硅藻赤潮后海水溶解有机物的荧光特征

利用激发-发射矩阵光谱法(EEMs),测定了2007年4月下旬东海硅藻赤潮消亡后海水溶解有机物的三维荧光,并对荧光特征及其强度与盐度、叶绿素a和碳水化合物的关系进行了分析和讨论。结果显示东海硅藻赤潮后海水中有较强的类蛋白荧光,主要荧光峰有Ex_max/Em_max为270～280/290～315 nm(B峰)和220～230/290～305 nm(D峰)的类酪氨酸荧光峰,230～240/335～350 nm(S峰)和280/320 nm(T峰)的类色氨酸荧光峰,其中B峰强度最大,个别站点荧光强度高达3 955。赤潮消亡主要海区的FI_B/FI_S较大,表明类蛋白溶解有机物主要是由赤潮藻破碎分解产生的类酪氨酸。在255～270/435～480 nm(A峰)和330～350/420～480 nm(C峰)还观察到两种类腐殖质荧光峰,它们的强度低于类蛋白荧光。S峰、A峰和C峰三者之间互相呈较好的正相关,且三者荧光强度与盐度都有显著的线性负相关,其分布均呈现出近岸高远岸低的特点,表明江浙沿岸水的输入是其共同的重要来源。各类荧光峰的强度与叶绿素a的相关性不显著,现存的浮游植物不是赤潮消亡水体中荧光溶解有机物的主要直接来源。     

三维荧光结合平行因子分析在东海溶解有机物研究中的应用

利用三维荧光光谱（EEMs）结合平行因子分析（PARAFAC）,研究了东海夏、秋两季溶解有机物（DOM）的荧光组分特征,并对其种类、分布和来源进行了分析和讨论。共识别出三个荧光组分,分别为类蛋白荧光组分C1（235, 280/330）、陆源或海源类腐殖质组分C2(255, 330/400)以及陆源类腐殖质组分C3（275, 360/480）。两个类腐殖质组分C2和C3之间呈显著正相关,表明他们有相同的来源或在结构上存在某种联系。三组分在两个季节不同水层的分布总体呈现近岸高,远海低的特点。各组分与叶绿素a和盐度的关系表明调查海域的DOM受现存浮游植物的直接影响很小,夏季长江输入是长江口三组分的重要来源,而秋季受长江输入的影响减弱。本研究显示了三维荧光与平行因子分析相结合在海洋溶解有机物的研究中具有很好的应用前景。     

The vibrational spectra and structure of sodium bromoacetate and sodium bromoacetate-d2

The complete vibrational spectra of crystalline sodium bromoacetate and sodium bromoacetate-d₂ have been recorded and a vibrational assignmem proposed. The intermolecular coupling of these compounds is quite strong and the data are consistent with a centrosymmetric unit cell containing at least four molecules.The product rule calculations support a structure m which the bromine atom is rotated out of the plane of the remaining heavy atoms, but the frequency of the carbon-bromine stretching mode indicates that the degree of rotation is not large.