全文获取类型
收费全文 | 45757篇 |
免费 | 3915篇 |
国内免费 | 6394篇 |
专业分类
化学 | 31520篇 |
晶体学 | 1406篇 |
力学 | 1055篇 |
综合类 | 273篇 |
数学 | 8681篇 |
物理学 | 13131篇 |
出版年
2024年 | 86篇 |
2023年 | 474篇 |
2022年 | 1091篇 |
2021年 | 1040篇 |
2020年 | 1355篇 |
2019年 | 1406篇 |
2018年 | 1190篇 |
2017年 | 1443篇 |
2016年 | 1486篇 |
2015年 | 1410篇 |
2014年 | 2042篇 |
2013年 | 3447篇 |
2012年 | 2274篇 |
2011年 | 3508篇 |
2010年 | 2741篇 |
2009年 | 3142篇 |
2008年 | 3318篇 |
2007年 | 3167篇 |
2006年 | 2817篇 |
2005年 | 2622篇 |
2004年 | 2276篇 |
2003年 | 1853篇 |
2002年 | 1685篇 |
2001年 | 1271篇 |
2000年 | 1225篇 |
1999年 | 1046篇 |
1998年 | 855篇 |
1997年 | 769篇 |
1996年 | 686篇 |
1995年 | 681篇 |
1994年 | 633篇 |
1993年 | 553篇 |
1992年 | 446篇 |
1991年 | 323篇 |
1990年 | 224篇 |
1989年 | 216篇 |
1988年 | 172篇 |
1987年 | 128篇 |
1986年 | 127篇 |
1985年 | 134篇 |
1984年 | 109篇 |
1983年 | 71篇 |
1982年 | 95篇 |
1981年 | 83篇 |
1980年 | 89篇 |
1979年 | 63篇 |
1978年 | 62篇 |
1977年 | 45篇 |
1976年 | 31篇 |
1973年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
51.
Q. Gong R. N tzel P.J. van Veldhoven T.J. Eijkemans J.H. Wolter 《Journal of Crystal Growth》2005,280(3-4):413-418
We report on the shape transition from InAs quantum dashes to quantum dots (QDs) on lattice-matched GaInAsP on InP(3 1 1)A substrates. InAs quantum dashes develop during chemical-beam epitaxy of 3.2 monolayers InAs, which transform into round InAs QDs by introducing a growth interruption without arsenic flux after InAs deposition. The shape transition is solely attributed to surface properties, i.e., increase of the surface energy and symmetry under arsenic deficient conditions. The round QD shape is maintained during subsequent GaInAsP overgrowth because the reversed shape transition from dot to dash is kinetically hindered by the decreased ad-atom diffusion under arsenic flux. 相似文献
52.
Nanocomposites (NC) were formed using cationic poly(L ‐lysine) (PLL), a semicrystalline polypeptide, that was reinforced by sodium montmorillonite (MMT) clay via solution intercalation technique. By varying solution conditions such as pH, temperature, and polypeptide concentration in the presence of clay platelets, the secondary structure of PLL was controllably altered into α‐helical, β‐sheet, and random coil. The high molecular weight polypeptide shows a strong propensity to fold into the β‐sheet structure when cast as films, irrespective of the initial secondary structure in solution. Nanocomposite local morphology confirms intercalated MMT platelets with PLL over a wide range of compositions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 239–252, 2007. 相似文献
53.
Adam Kiersnowski Jochen S. Gutmann Jacek Pigłowski 《Journal of Polymer Science.Polymer Physics》2007,45(17):2350-2367
ε‐caprolactone was polymerized in the presence of neat montmorillonite or organomontmorillonites to obtain a variety of poly(ε‐caprolactone) (PCL)‐based systems loaded with 10 wt % of the silicates. The materials were thoroughly investigated by different X‐ray scattering techniques to determine factors affecting structure of the systems. For one of the nanocomposites it was found that varying the temperature in the range corresponding to crystallization of PCL causes reversible changes in the interlayer distance of the organoclay. Extensive experimental and literature studies on this phenomenon provided clues indicating that this effect might be a result of two‐dimensional ordering of PCL chains inside the galleries of the silicate. Small angle X‐ray scattering and wide angle X‐ray scattering investigation of filaments oriented above melting point of PCL revealed that polymer lamellae were oriented perpendicularly to particles of unmodified silicate, while in PCL/organoclay systems they were found parallel to clay tactoids. Calorimetric and microscopic studies shown that clay particles are effective nucleating agents. In the nanocomposites, PCL crystallized 20‐fold faster than in the neat polymer. The crystallization rate in nanocomposites was also significantly higher than in microcomposite. Further research provided an insight how the presence of the filler affects crystalline fraction and spherulitic structure of the polymer matrix in the investigated systems. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2350–2367, 2007 相似文献
54.
Igor Chueshov 《Journal of Differential Equations》2007,233(1):42-86
We study von Karman evolution equations with non-linear dissipation and with partially clamped and partially free boundary conditions. Two distinctive mechanisms of dissipation are considered: (i) internal dissipation generated by non-linear operator, and (ii) boundary dissipation generated by shear forces friction acting on a free part of the boundary. The main emphasis is given to the effects of boundary dissipation. Under suitable hypotheses we prove existence of a compact global attractor and finiteness of its fractal dimension. We also show that any solution is stabilized to an equilibrium and estimate the rate of the convergence which, in turn, depends on the behaviour at the origin of the functions describing the dissipation. 相似文献
55.
The authors give a consistent affirmative response to a question of Juhász, Soukup and Szentmiklóssy: If GCH fails, there are (many) extraresolvable, not maximally resolvable Tychonoff spaces. They show also in ZFC that for ω<λ?κ, no maximal λ-independent family of λ-partitions of κ is ω-resolvable. In topological language, that theorem translates to this: A dense, ω-resolvable subset of a space of the form (DI(λ)) is λ-resolvable. 相似文献
56.
57.
J.T. Devaraju B.H. Sharmila S. Asokan K.V. Acharya 《Applied Physics A: Materials Science & Processing》2002,75(4):515-518
The electrical switching behaviour of As45Te55-xInx (5≤x≤15) and As50Te50-xInx (2.5≤x≤11.5) has been studied over a wide range of compositions. These glasses are found to exhibit threshold switching.
The composition dependence of switching voltage (Vt) has been found to exhibit a change in slope and a local minimum at compositions x=10 and 12.5 for As45Te55-xInx and x=7.5 and 10.8 for As50Te50-xInx, respectively. The slope change in Vt verses x and the local minimum have been identified using two network topological effects, namely the rigidity percolation
threshold and the chemical threshold.
Received: 23 August 2001 / Accepted: 27 August 2001 / Published online: 11 February 2002 相似文献
58.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
59.
In this paper, we report that the phase transformation of Ni-B, Ni-P diffusion barriers deposited electrolessly on Cu, for the reason that the Ni-P layer is a more effective diffusion barrier than the Ni-B layer. The Ni3B crystallized was decomposed to Ni and B2O3 above 400 °C and the Ni3P crystallized was decomposed to Ni and P2O5 above 600 °C respectively in Ar atmosphere. Also, the Ni3B was decomposed to Ni and free B above 400 °C and the Ni3P was decomposed to Ni and free P above 600 °C respectively in H2 atmosphere. The decomposed Ni formed a solid solution with Cu. The Cu diffusion occurred above 400 °C for Ni-B layer and above 600 °C for Ni-P layer, respectively. Because the decomposition temperature of Ni-P layer is about 200 °C higher than that of Ni-B layer, the Ni-P layer is a more effective barrier for Cu than the Ni-B layer. 相似文献
60.
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1?y Fe y )Sb solid solution have been studied by the Mössbauer effect method at 57Fe and 119Sn. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of 119Sn. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of 119 Sn in 3d-metal antimonides in the 0 ≤ x ≤ 0.1 concentration range can be used to determine x – the concentration of transition metal excess relative to the stoichiometric composition. 相似文献